Assessing the dynamics of organic aerosols over the North Atlantic Ocean

© The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Scientific Reports 7 (2017): 45476, doi:10.1038/srep45476.The influence of aerosols on climate is highly dependent on the particle size distribution, concentration, and composition. In particular, the latter influences their ability to act as cloud condensation nuclei, whereby they impact cloud coverage and precipitation. Here, we simultaneously measured the concentration of aerosols from sea spray over the North Atlantic on board the exhaust-free solar-powered vessel “PlanetSolar”, and the sea surface physico-chemical parameters. We identified organic-bearing particles based on individual particle fluorescence spectra. Organic-bearing aerosols display specific spatio-temporal distributions as compared to total aerosols. We propose an empirical parameterization of the organic-bearing particle concentration, with a dependence on water salinity and sea-surface temperature only. We also show that a very rich mixture of organic aerosols is emitted from the sea surface. Such data will certainly contribute to providing further insight into the influence of aerosols on cloud formation, and be used as input for the improved modeling of aerosols and their role in global climate processes.We gratefully acknowledge the financial support by the H. Dudley Wright and the Henri Moser Foundations, the Rector’s Office and the Institute for Environmental Sciences at the University of Geneva, as well as a generous anonymous donator

Black Sea beaches vulnerability to sea level rise

Integrated Coastal Zone Management (ICZM) aims to promote sustainable management of coastal zones based on ecosystem and holistic management approaches. In this context, policies have to consider the complex interactions that influence the fragile equilibrium of coastal ecosystems. Beaches represent both valuable and vulnerable natural resources because of the various ecosystem services they provide and their sensitivity to climate change and sea level rise. We present the first comprehensive digital record of all Black Sea beaches and provide a rapid assessment of their erosion risk under different scenarios of sea level rise. Through the digitisation of freely available remote-sensed images on the web, we provide broad information on the spatial characteristics and other attributes of all Black Sea beaches (e.g. photo-based visual estimation of the sediment type, presence of coastal defences, urban development). These data have been assembled and stored in full Spatial Data Infrastructure (SDI) – allowing spatial queries, visualisation and data sharing – and are therefore particularly interesting to feed/supply web-GIS portals (coastal atlases) for visualisation purpose, spatial queries or spatial indicators calculations. The resulting Black Sea beaches database contains 1228 beaches, with a total coast-line length of 2042 km with an area of 224 km2. The majority of the Black Sea beaches have been found to have small widths (61% have maximum widths less than 50 m), whereas 47% of all beaches presented coastal defence schemes, suggesting an already serious beach erosion problem. The erosion risk of the Black Sea beaches was assessed through the comparison of their maximum widths with estimations of the sea level rise-induced retreat by an ensemble of six 1-D analytical and numerical morphodynamic models. Following more than 17,000 experiments using different combinations of wave conditions, beach sediment textures and slopes and 11 scenarios of sea level rise (up to 2 m), the means (best fits) of the lowest and highest projections by the model ensemble were estimated; these were then compared to the maximum widths of the Black Sea beaches. The analysis showed that sea level rise will have highly significant impacts on the Black Sea beaches, as for a 0.5 m sea level rise 56% of all beaches are projected to retreat by 50% of their maximum width. For a 0.82 m sea level rise (the high IPCC estimate for the period 2081–2100) about 41% are projected to retreat by their entire maximum width, whereas for 1 m sea level rise about 51% of all Black Sea beaches are projected to retreat by (drowned or shifted landward by) their entire maximum width, if the high mean of the model ensemble projections is used. Results substantiate the risk of beach erosion as a major environmental problem along the Black Sea coast, which therefore needs to be taken into account in any future coastal management plans, as a matter of urgency. As these scenarios consider only sea level rise, they are considered to be conservative. Although the present results cannot replace detailed studies, the database and projections may assist Black Sea coastal managers and policy makers to rapidly identify beaches with increased risk of erosion, valuate accordingly coastal assets and infrastructure, estimate beach capacity for touristic development purposes, and rapidly assess direct and indirect costs and benefits of beach protection options. They also provide the necessary inputs to advance discussions relevant to the Black Sea ICZM

MS/MS-Guided Isolation of Clarinoside, a New Anti-Inflammatory Pentalogin Derivative

Re-investigation of the chemical composition of the annual plant Mitracarpus scaber Zucc. led to the identification of clarinoside, a new pentalogin derivative containing a rare quinovose moiety, and the known compound harounoside. While the planar structure was fully determined using tandem mass spectrometry (MS) and quantum mechanics (QM) calculations, the tridimensional structure was unravelled after isolation and NMR analysis. The absolute configuration was assigned by comparison of experimental and theoretical synchrotron radiation circular dichroism spectra. Both compounds were tested for anti-inflammatory activity, and compound 1 showed the ability to inhibit the production of interleukin-8 (Il-8) with an IC 50 value of 9.17 μ M

Data from: A web platform for landuse, climate, demography, hydrology and beach erosion in the Black Sea catchment

The Black Sea catchment (BSC) is facing important demographic, climatic and landuse changes that may increase pollution, vulnerability and scarcity of water resources, as well as beach erosion through sea level rise. Limited access to reliable time-series monitoring data from environmental, statistical, and socio-economical sources is a major barrier to policy development and decision-making. To address these issues, a web-based platform was developed to enable discovery and access to key environmental information for the region. This platform covers: landuse, climate, and demographic scenarios; hydrology and related water vulnerability and scarcity; as well as beach erosion. Each data set has been obtained with state-of-the-art modelling tools from available monitoring data using appropriate validation methods. These analyses were conducted using global and regional data sets. The data sets are intended for national to regional assessments, for instance for prioritizing environmental protection projects and investments. Together they form a unique set of information, which lay out future plausible change scenarios for the BSC, both for scientific and policy purposes

Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field