An Effective Electrodeposition Mode for Porous MnO2/Ni Foam Composite for Asymmetric Supercapacitors

Three kinds of MnO2/Ni foam composite electrode with hierarchical meso-macroporous structures were prepared using potentiodynamic (PD), potentiostatic (PS), and a combination of PS and PD(PS + PD) modes of electrodeposition. The electrodeposition mode markedly influenced the surface morphological, textural, and supercapacitive properties of the MnO2/Ni electrodes. The supercapacitive performance of the MnO2/Ni electrode obtained via PS + PD(PS + PD(MnO2/Ni)) was found to be superior to those of MnO2/Ni electrodes obtained via PD and PS, respectively. Moreover, an asymmetric supercapacitor device, activated carbon (AC)/PS + PD(MnO2/Ni), utilizing PS + PD(MnO2/Ni) as a positive electrode and AC as a negative electrode, was fabricated. The device exhibited an energy density of 7.7 Wh·kg−1 at a power density of 600 W·kg−1 and superior cycling stability, retaining 98% of its initial capacity after 10,000 cycles. The good supercapacitive performance and excellent stability of the AC/PS + PD(MnO2/Ni) device can be ascribed to its high surface area, hierarchical structure, and interconnected three-dimensional reticular configuration of the nickel metal support, which facilitates electrolyte ion intercalation and deintercalation at the electrode/electrolyte interface and mitigates volume change during repeated charge/discharge cycling. These results demonstrate the great potential of the combination of PS and PD modes for MnO2 electrodeposition for the development of high-performance electrodes for supercapacitors

Chapter Six - Molecular signaling in bone cells: Regulation of cell differentiation and survival

The achievement of proper bone mass and architecture, and their maintenance throughout life requires the concerted actions of osteoblasts, the bone forming cells, and osteoclasts, the bone resorbing cells. The differentiation and activity of osteoblasts and osteoclasts are regulated by molecules produced by matrix-embedded osteocytes, as well as by cross-talk between osteoblasts and osteoclasts through secreted factors. In addition, it is likely that direct contact between osteoblast and osteoclast precursors, and the contact of these cells with osteocytes and cells in the bone marrow, also modulate bone cell differentiation and function. With the advancement of molecular and genetic tools, our comprehension of the intracellular signals activated in bone cells has evolved significantly, from early suggestions that osteoblasts and osteoclasts have common precursors and that osteocytes are inert cells in the bone matrix, to the very sophisticated understanding of a network of receptors, ligands, intracellular kinases/phosphatases, transcription factors, and cell-specific genes that are known today. These advances have allowed the design and FDA-approval of new therapies to preserve and increase bone mass and strength in a wide variety of pathological conditions, improving bone health from early childhood to the elderly. We have summarized here the current knowledge on selected intracellular signal pathways activated in osteoblasts, osteocytes, and osteoclasts

Economie sociale et solidaire et territoires : un couple allant de soi ?

L’ancrage territorial constitue, avec le fonctionnement démocratique et la solidarité économique, l’une des caractéristiques majeures de l’économie sociale et solidaire (ESS). Loin de postuler une territorialité spontanée de l’ESS, nous proposons de réintégrer l’observation des dynamiques d’ESS dans les jeux de complémentarité, coopération ou concurrence propres aux processus de constructions territoriales. Le statut de l’ESS dans les transformations globales des modes de coordination des systèmes productifs territoriaux est d’abord analysé. Deux pistes de recherche concernant l’ESS et la gouvernance territoriale sont ensuite déclinées. La première concerne l’institutionnalisation de l’ESS en tant que secteur de l’action publique territoriale. La deuxième interroge le postulat d’une congruence parfaite entre le tournant horizontal et territorial de l’action publique et les objectifs affichés de l’ESS.Like democratic management and economic solidarity, local embeddedness is one of the main features of the social and solidarity economy. Far from arguing that the social and solidarity economy is naturally embedded in the community, we propose to bring the observed dynamics of the social and solidarity economy back into the complementarity, cooperation or competition specific to the processes of territorial constructions. The role of the social and solidarity economy in the global transformation of the coordination of territorial productive systems is then examined. Two lines of research concerning the social and solidarity economy and territorial governance are presented. The first concerns the institutionalisation of the social and solidarity economy as a sector of local community action. The second questions the premise that the horizontal and territorial transformation of local community action and the declared objectives of the social and solidarity economy are perfectly compatible

Search for third-generation scalar leptoquarks and heavy right-handed neutrinos in final states with two tau leptons and two jets in proton-proton collisions at sqrt(s)=13 TeV

A search is performed for third-generation scalar leptoquarks and heavy right-handed neutrinos in events containing one electron or muon, one hadronically decaying τ lepton, and at least two jets, using a s=13 TeV pp collision data sample corresponding to an integrated luminosity of 12.9 fb-1collected with the CMS detector at the LHC in 2016. The number of observed events is found to be in agreement with the standard model prediction. A limit is set at 95% confidence level on the product of the leptoquark pair production cross section and β2, where β is the branching fraction of leptoquark decay to a τ lepton and a bottom quark. Assuming β = 1, third-generation leptoquarks with masses below 850 GeV are excluded at 95% confidence level. An additional search based on the same event topology involves heavy right-handed neutrinos, NR, and right-handed W bosons, WR, arising in a left-right symmetric extension of the standard model. In this search, WRbosons are assumed to decay to a tau lepton and NRfollowed by the decay of the NRto a tau lepton and an off-shell WRboson. Assuming the mass of the right-handed neutrino to be half of the mass of the right-handed W boson, WRboson masses below 2.9 TeV are excluded at 95% confidence level. These results improve on the limits from previous searches for third-generation leptoquarks and heavy right-handed neutrinos with τ leptons in the final state.[Figure not available: see fulltext.]