Raman microspectroscopy, bitumen reflectance and illite crystallinity scale: comparison of different geothermometry methods on fossiliferous Proterozoic sedimentary basins (DR Congo, Mauritania and Australia)

Sedimentary rocks containing microfossils are crucial archives to reconstitute early life evolution on Earth. However, the preservation of microfossils within rocks depends on several physico-chemical factors. Among these factors, the thermal evolution of the host rocks can be decisive. Here, we investigated carbonaceous shale samples containing exquisitely preserved organic-walled microfossils assemblages from three Proterozoic shallow marine sedimentary sequences: the Mbuji-Mayi Supergroup (Democratic Republic of Congo, Congo Basin), the Atar/El Mreïti Group (Mauritania, Taoudeni Basin) and the Kanpa Formation (Australia, Officer Basin). Thermal maturity of these rock samples is evaluated with Raman geothermometry, Raman reflectance, solid bitumen reflectance, illite crystallinity and Thermal Alteration Index. The comparison of results coming from these different techniques validates the use of Raman reflectance on Proterozoic carbonaceous material and especially for poorly-ordered carbonaceous material. We show that extracted kerogen (microfossils and amorphous organic material) is more accurate to estimate the thermal maturity of low-grade temperature Proterozoic sequences than kerogen in thin section. All techniques provide consistent range of temperatures except for Raman geothermometry, giving slightly higher estimates. Raman reflectance appears to be a fast, robust and non-destructive tool to evaluate the thermal maturity of poorly-organized carbonaceous material from Proterozoic rocks.Early Life Tarces, Evolution and implications for Astrobiolog

Use of different geothermometry methods on fossiliferous Proterozoic sediments to constrain thermal maturity of microfossils and sedimentary basins (DRCongo, Mauritania & Australia)

Evaluate the thermal maturity of old sedimentary basins containing microfossils is crucial to reconstruct early life evolution on Earth. Here, we investigate carbonaceous shale samples containing exquisitely preserved organic-walled microfossil assemblages from three Proterozoic shallow marine sedimentary sequences: the Mbuji-Mayi Supergroup (Democratic Republic of Congo, Congo Basin), the Atar/El Mreïti Group (Mauritania, Taoudeni Basin) and the Kanpa Formation (Australia, Officer Basin). By comparison with Raman geothermometry, solid bitumen reflectance, illite crystallinity and Thermal Alteration Index, we evaluate and validate the use of Raman reflectance on Proterozoic carbonaceous material and especially for poorly-ordered carbonaceous material. We show that extracted kerogen (microfossils and amorphous organic material) is more accurate to estimate the thermal maturity of low-grade temperature Proterozoic sequences than kerogen in thin section. All the techniques provide consistent range of temperatures except for Raman geothermometry, giving slightly higher estimates. Raman reflectance appears to be a fast and robust tool to evaluate the thermal maturity of poorly-organized carbonaceous material from Proterozoic rocks and by extension could be used to assess the thermal evolution of a sedimentary successions. This work was supported by the ERC StG ELITE FP7/308074; BELSPO IAP PLANET TOPERS, and the Marie-Curie Cofund program

Raman reflectance on isolated Proterozoic microfossils: A fast and robust tool to assess thermal maturity of sedimentary basins

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