Instanton Dynamics in the Broken Phase of the Topological Sigma Model

The topological $\sigma$ model with the black hole metric of the target space is considered. It has been shown before that this model is in the phase with BRST-symmetry broken. In particular, vacuum energy is non-\-zero and correlation functions of observables show the coordinate dependence. However these quantities turned out to be infrared (IR) divergent. It is shown here that IR divergences disappear after the sum over an arbitrary number of additional instanton-\-anti-\-instanton pairs is performed. The model appears to be equivalent to Coulomb gas/Sine Gordon system.Comment: some references added

Chemical kinetics and modeling of planetary atmospheres

A unified overview is presented for chemical kinetics and chemical modeling in planetary atmospheres. The recent major advances in the understanding of the chemistry of the terrestrial atmosphere make the study of planets more interesting and relevant. A deeper understanding suggests that the important chemical cycles have a universal character that connects the different planets and ultimately link together the origin and evolution of the solar system. The completeness (or incompleteness) of the data base for chemical kinetics in planetary atmospheres will always be judged by comparison with that for the terrestrial atmosphere. In the latter case, the chemistry of H, O, N, and Cl species is well understood. S chemistry is poorly understood. In the atmospheres of Jovian planets and Titan, the C-H chemistry of simple species (containing 2 or less C atoms) is fairly well understood. The chemistry of higher hydrocarbons and the C-N, P-N chemistry is much less understood. In the atmosphere of Venus, the dominant chemistry is that of chlorine and sulfur, and very little is known about C1-S coupled chemistry. A new frontier for chemical kinetics both in the Earth and planetary atmospheres is the study of heterogeneous reactions. The formation of the ozone hole on Earth, the ubiquitous photochemical haze on Venus and in the Jovian planets and Titan all testify to the importance of heterogeneous reactions. It remains a challenge to connect the gas phase chemistry to the production of aerosols