303 research outputs found

    Use of eco-friendly epoxy resins from renewable resources as potential substitutes of petrochemical epoxy resins for ambient cured composites with flax reinforcements

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    [EN] In the last years, some high renewable content epoxy resins, derived from vegetable oils, have been developed at industrial level and are now commercially available; these can compete with petroleum-based resins as thermoset matrices for composite materials. Nevertheless, due to the relatively high cost in comparison to petroleum-based resins, their use is still restricted to applications with relatively low volume consumption such as model making, tuning components, nautical parts, special effects, outdoor sculptures, etc. in which, the use of composite laminates with carbon, aramid and, mainly, glass fibers is generalized by using hand layup and vacuum assisted resin transfer molding (VARTM) techniques due to low manufacturing costs and easy implementation. In this work, we study the behavior of two high renewable content epoxy resins derived from vegetable oils as potential substitutes of petroleum-based epoxies in composite laminates with flax reinforcements by using the VARTM technique. The curing behavior of the different epoxy resins is compared in terms of the gel point and exothermicity profile by differential scanning calorimetry (DSC). In addition, overall performance of flax-epoxy composites is compared with standardized mechanical (tensile, flexural and impact) and thermal (Vicat softening temperature, heat deflection temperature, thermo-mechanical analysis) tests. The curing DSC profiles of the two eco-friendly epoxy resins are similar to a conventional epoxy resin. They can be easily handled and processed by conventional VARTM process thus leading to composite laminates with flax with balanced mechanical and thermal properties, similar or even higher to a multipurpose epoxy resin. © 2012 Society of Plastics Engineers.This work is part of the project IPT-310000-2010-037, "ECOTEXCOMP: Research and development of textile structures useful as reinforcement of composite materials with marked ecological character" funded by the "Ministerio de Ciencia e Innovacion", with an aid of 189540.20 euros, within the "Plan Nacional de Investigacion Cientifica, Desarrollo e InnovacionTecnologica 2008-2011" and funded by the European Union through FEDER funds, Technology Fund 2007-2013, Operational Programme on R+D+i for and on behalf of the companies."Bertomeu PerellĂł, D.; GarcĂ­a Sanoguera, D.; Fenollar Gimeno, OÁ.; Boronat Vitoria, T.; Balart Gimeno, RA. (2012). Use of eco-friendly epoxy resins from renewable resources as potential substitutes of petrochemical epoxy resins for ambient cured composites with flax reinforcements. Polymer Composites. 33(5):683-692. https://doi.org/10.1002/pc.22192S683692335Alves, C., FerrĂŁo, P. M. C., Silva, A. J., Reis, L. G., Freitas, M., Rodrigues, L. B., & Alves, D. E. (2010). Ecodesign of automotive components making use of natural jute fiber composites. Journal of Cleaner Production, 18(4), 313-327. doi:10.1016/j.jclepro.2009.10.022JOHN, M., & THOMAS, S. (2008). Biofibres and biocomposites. Carbohydrate Polymers, 71(3), 343-364. doi:10.1016/j.carbpol.2007.05.040Mohanty, A. K., Misra, M., & Drzal, L. T. (2002). Journal of Polymers and the Environment, 10(1/2), 19-26. doi:10.1023/a:1021013921916Pillin, I., Kervoelen, A., Bourmaud, A., Goimard, J., Montrelay, N., & Baley, C. (2011). Could oleaginous flax fibers be used as reinforcement for polymers? Industrial Crops and Products, 34(3), 1556-1563. doi:10.1016/j.indcrop.2011.05.016Summerscales, J., Dissanayake, N. P. J., Virk, A. S., & Hall, W. (2010). A review of bast fibres and their composites. Part 1 – Fibres as reinforcements. Composites Part A: Applied Science and Manufacturing, 41(10), 1329-1335. doi:10.1016/j.compositesa.2010.06.001Sreekumar, P. A., Saiah, R., Saiter, J. M., Leblanc, N., Joseph, K., Unnikrishnan, G., & Thomas, S. (2009). Dynamic mechanical properties of sisal fiber reinforced polyester composites fabricated by resin transfer molding. Polymer Composites, 30(6), 768-775. doi:10.1002/pc.20611Mu, Q., Wei, C., & Feng, S. (2009). Studies on mechanical properties of sisal fiber/phenol formaldehyde resin in-situ composites. Polymer Composites, 30(2), 131-137. doi:10.1002/pc.20529Sever, K., Sarikanat, M., Seki, Y., Erkan, G., Erdoğan, Ü. H., & Erden, S. (2012). Surface treatments of jute fabric: The influence of surface characteristics on jute fabrics and mechanical properties of jute/polyester composites. Industrial Crops and Products, 35(1), 22-30. doi:10.1016/j.indcrop.2011.05.020Wood, B. M., Coles, S. R., Maggs, S., Meredith, J., & Kirwan, K. (2011). Use of lignin as a compatibiliser in hemp/epoxy composites. Composites Science and Technology, 71(16), 1804-1810. doi:10.1016/j.compscitech.2011.06.005Eichhorn, S. J., Baillie, C. A., Zafeiropoulos, N., Mwaikambo, L. Y., Ansell, M. P., Dufresne, A., 
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Journal of Polymers and the Environment, 18(4), 464-473. doi:10.1007/s10924-010-0165-4De Arcaya, P. A., Retegi, A., Arbelaiz, A., Kenny, J. M., & Mondragon, I. (2009). Mechanical properties of natural fibers/polyamides composites. Polymer Composites, 30(3), 257-264. doi:10.1002/pc.20558Twite-Kabamba, E., Mechraoui, A., & Rodrigue, D. (2009). Rheological properties of polypropylene/hemp fiber composites. Polymer Composites, 30(10), 1401-1407. doi:10.1002/pc.20704De Rosa, I. M., Iannoni, A., Kenny, J. M., Puglia, D., Santulli, C., Sarasini, F., & Terenzi, A. (2011). Poly(lactic acid)/Phormium tenax composites: Morphology and thermo-mechanical behavior. Polymer Composites, 32(9), 1362-1368. doi:10.1002/pc.21159Christian, S. J., & Billington, S. L. (2011). Mechanical response of PHB- and cellulose acetate natural fiber-reinforced composites for construction applications. 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Polymer Composites, 30(11), 1595-1600. doi:10.1002/pc.20732Campaner, P., D’Amico, D., Longo, L., Stifani, C., & Tarzia, A. (2009). Cardanol-based novolac resins as curing agents of epoxy resins. Journal of Applied Polymer Science, 114(6), 3585-3591. doi:10.1002/app.30979Raju, & Kumar, P. (2011). Cathodic electrodeposition of self-curable polyepoxide resins based on cardanol. Journal of Coatings Technology and Research, 8(5), 563-575. doi:10.1007/s11998-011-9337-yRao, B. S., & Palanisamy, A. (2011). Monofunctional benzoxazine from cardanol for bio-composite applications. Reactive and Functional Polymers, 71(2), 148-154. doi:10.1016/j.reactfunctpolym.2010.11.025Chen, L., Zhou, S., Song, S., Zhang, B., & Gu, G. (2010). Preparation and anticorrosive performances of polysiloxane-modified epoxy coatings based on polyaminopropylmethylsiloxane-containing amine curing agent. 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Cure kinetics of an epoxidized hemp oil based bioresin system. Journal of Applied Polymer Science, 122(1), 444-451. doi:10.1002/app.34086Mustata, F., Tudorachi, N., & Rosu, D. (2011). Curing and thermal behavior of resin matrix for composites based on epoxidized soybean oil/diglycidyl ether of bisphenol A. Composites Part B: Engineering, 42(7), 1803-1812. doi:10.1016/j.compositesb.2011.07.003Takahashi, T., Hirayama, K., Teramoto, N., & Shibata, M. (2008). Biocomposites composed of epoxidized soybean oil cured with terpene-based acid anhydride and cellulose fibers. Journal of Applied Polymer Science, 108(3), 1596-1602. doi:10.1002/app.27866Miyagawa, H., Misra, M., Drzal, L. T., & Mohanty, A. K. (2005). Fracture toughness and impact strength of anhydride-cured biobased epoxy. Polymer Engineering & Science, 45(4), 487-495. doi:10.1002/pen.20290J. D. Espinoza PĂ©rez, D. M. Haagenson, S. W. Pryor, C. A. Ulven, & D. P. Wiesenborn. (2009). 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    The performance of the jet trigger for the ATLAS detector during 2011 data taking

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    The performance of the jet trigger for the ATLAS detector at the LHC during the 2011 data taking period is described. During 2011 the LHC provided proton–proton collisions with a centre-of-mass energy of 7 TeV and heavy ion collisions with a 2.76 TeV per nucleon–nucleon collision energy. The ATLAS trigger is a three level system designed to reduce the rate of events from the 40 MHz nominal maximum bunch crossing rate to the approximate 400 Hz which can be written to offline storage. The ATLAS jet trigger is the primary means for the online selection of events containing jets. Events are accepted by the trigger if they contain one or more jets above some transverse energy threshold. During 2011 data taking the jet trigger was fully efficient for jets with transverse energy above 25 GeV for triggers seeded randomly at Level 1. For triggers which require a jet to be identified at each of the three trigger levels, full efficiency is reached for offline jets with transverse energy above 60 GeV. Jets reconstructed in the final trigger level and corresponding to offline jets with transverse energy greater than 60 GeV, are reconstructed with a resolution in transverse energy with respect to offline jets, of better than 4 % in the central region and better than 2.5 % in the forward direction

    Measurements of the charge asymmetry in top-quark pair production in the dilepton final state at s √ =8  TeV with the ATLAS detector

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    Measurements of the top-antitop quark pair production charge asymmetry in the dilepton channel, characterized by two high-pT leptons (electrons or muons), are presented using data corresponding to an integrated luminosity of 20.3  fb−1 from pp collisions at a center-of-mass energy s√=8  TeV collected with the ATLAS detector at the Large Hadron Collider at CERN. Inclusive and differential measurements as a function of the invariant mass, transverse momentum, and longitudinal boost of the ttÂŻ system are performed both in the full phase space and in a fiducial phase space closely matching the detector acceptance. Two observables are studied: AℓℓC based on the selected leptons and AttÂŻC based on the reconstructed ttÂŻ final state. The inclusive asymmetries are measured in the full phase space to be AℓℓC=0.008±0.006 and AttÂŻC=0.021±0.016, which are in agreement with the Standard Model predictions of AℓℓC=0.0064±0.0003 and AttÂŻC=0.0111±0.0004

    Global injury morbidity and mortality from 1990 to 2017 : results from the Global Burden of Disease Study 2017

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    Correction:Background Past research in population health trends has shown that injuries form a substantial burden of population health loss. Regular updates to injury burden assessments are critical. We report Global Burden of Disease (GBD) 2017 Study estimates on morbidity and mortality for all injuries. Methods We reviewed results for injuries from the GBD 2017 study. GBD 2017 measured injury-specific mortality and years of life lost (YLLs) using the Cause of Death Ensemble model. To measure non-fatal injuries, GBD 2017 modelled injury-specific incidence and converted this to prevalence and years lived with disability (YLDs). YLLs and YLDs were summed to calculate disability-adjusted life years (DALYs). Findings In 1990, there were 4 260 493 (4 085 700 to 4 396 138) injury deaths, which increased to 4 484 722 (4 332 010 to 4 585 554) deaths in 2017, while age-standardised mortality decreased from 1079 (1073 to 1086) to 738 (730 to 745) per 100 000. In 1990, there were 354 064 302 (95% uncertainty interval: 338 174 876 to 371 610 802) new cases of injury globally, which increased to 520 710 288 (493 430 247 to 547 988 635) new cases in 2017. During this time, age-standardised incidence decreased non-significantly from 6824 (6534 to 7147) to 6763 (6412 to 7118) per 100 000. Between 1990 and 2017, age-standardised DALYs decreased from 4947 (4655 to 5233) per 100 000 to 3267 (3058 to 3505). Interpretation Injuries are an important cause of health loss globally, though mortality has declined between 1990 and 2017. Future research in injury burden should focus on prevention in high-burden populations, improving data collection and ensuring access to medical care.Peer reviewe

    Mortality from gastrointestinal congenital anomalies at 264 hospitals in 74 low-income, middle-income, and high-income countries: a multicentre, international, prospective cohort study

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    Background: Congenital anomalies are the fifth leading cause of mortality in children younger than 5 years globally. Many gastrointestinal congenital anomalies are fatal without timely access to neonatal surgical care, but few studies have been done on these conditions in low-income and middle-income countries (LMICs). We compared outcomes of the seven most common gastrointestinal congenital anomalies in low-income, middle-income, and high-income countries globally, and identified factors associated with mortality. // Methods: We did a multicentre, international prospective cohort study of patients younger than 16 years, presenting to hospital for the first time with oesophageal atresia, congenital diaphragmatic hernia, intestinal atresia, gastroschisis, exomphalos, anorectal malformation, and Hirschsprung's disease. Recruitment was of consecutive patients for a minimum of 1 month between October, 2018, and April, 2019. We collected data on patient demographics, clinical status, interventions, and outcomes using the REDCap platform. Patients were followed up for 30 days after primary intervention, or 30 days after admission if they did not receive an intervention. The primary outcome was all-cause, in-hospital mortality for all conditions combined and each condition individually, stratified by country income status. We did a complete case analysis. // Findings: We included 3849 patients with 3975 study conditions (560 with oesophageal atresia, 448 with congenital diaphragmatic hernia, 681 with intestinal atresia, 453 with gastroschisis, 325 with exomphalos, 991 with anorectal malformation, and 517 with Hirschsprung's disease) from 264 hospitals (89 in high-income countries, 166 in middle-income countries, and nine in low-income countries) in 74 countries. Of the 3849 patients, 2231 (58·0%) were male. Median gestational age at birth was 38 weeks (IQR 36–39) and median bodyweight at presentation was 2·8 kg (2·3–3·3). Mortality among all patients was 37 (39·8%) of 93 in low-income countries, 583 (20·4%) of 2860 in middle-income countries, and 50 (5·6%) of 896 in high-income countries (p<0·0001 between all country income groups). Gastroschisis had the greatest difference in mortality between country income strata (nine [90·0%] of ten in low-income countries, 97 [31·9%] of 304 in middle-income countries, and two [1·4%] of 139 in high-income countries; p≀0·0001 between all country income groups). Factors significantly associated with higher mortality for all patients combined included country income status (low-income vs high-income countries, risk ratio 2·78 [95% CI 1·88–4·11], p<0·0001; middle-income vs high-income countries, 2·11 [1·59–2·79], p<0·0001), sepsis at presentation (1·20 [1·04–1·40], p=0·016), higher American Society of Anesthesiologists (ASA) score at primary intervention (ASA 4–5 vs ASA 1–2, 1·82 [1·40–2·35], p<0·0001; ASA 3 vs ASA 1–2, 1·58, [1·30–1·92], p<0·0001]), surgical safety checklist not used (1·39 [1·02–1·90], p=0·035), and ventilation or parenteral nutrition unavailable when needed (ventilation 1·96, [1·41–2·71], p=0·0001; parenteral nutrition 1·35, [1·05–1·74], p=0·018). Administration of parenteral nutrition (0·61, [0·47–0·79], p=0·0002) and use of a peripherally inserted central catheter (0·65 [0·50–0·86], p=0·0024) or percutaneous central line (0·69 [0·48–1·00], p=0·049) were associated with lower mortality. // Interpretation: Unacceptable differences in mortality exist for gastrointestinal congenital anomalies between low-income, middle-income, and high-income countries. Improving access to quality neonatal surgical care in LMICs will be vital to achieve Sustainable Development Goal 3.2 of ending preventable deaths in neonates and children younger than 5 years by 2030

    Performance of the ALICE experiment at the CERN LHC

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    ALICE is the heavy-ion experiment at the CERN Large Hadron Collider. The experiment continuously took data during the first physics campaign of the machine from fall 2009 until early 2013, using proton and lead-ion beams. In this paper we describe the running environment and the data handling procedures, and discuss the performance of the ALICE detectors and analysis methods for various physics observables

    First measurement of the |t|-dependence of coherent J/ψ photonuclear production

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    The first measurement of the cross section for coherent J/ψ photoproduction as a function of |t|, the square of the momentum transferred between the incoming and outgoing target nucleus, is presented. The data were measured with the ALICE detector in ultra-peripheral Pb–Pb collisions at a centre-of-mass energy per nucleon pair sNN=5.02TeV with the J/ψ produced in the central rapidity region |y|<0.8, which corresponds to the small Bjorken-x range (0.3−1.4)×10−3. The measured |t|-dependence is not described by computations based only on the Pb nuclear form factor, while the photonuclear cross section is better reproduced by models including shadowing according to the leading-twist approximation, or gluon-saturation effects from the impact-parameter dependent Balitsky–Kovchegov equation. These new results are therefore a valid tool to constrain the relevant model parameters and to investigate the transverse gluonic structure at very low Bjorken-x.publishedVersio

    First measurement of coherent ρ0 photoproduction in ultra-peripheral Xe–Xe collisions at √sNN = 5.44 TeV

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    The first measurement of the coherent photoproduction of ρ0 vector mesons in ultra-peripheral Xe–Xe collisions at sNN=5.44 TeV is presented. This result, together with previous HERA Îłp data and γ–Pb measurements from ALICE, describes the atomic number (A) dependence of this process, which is particularly sensitive to nuclear shadowing effects and to the approach to the black-disc limit of QCD at a semi-hard scale. The cross section of the Xe+Xe→ρ0+Xe+Xe process, measured at midrapidity through the decay channel ρ0→π+π−, is found to be dσ/dy=131.5±5.6(stat.)−16.9+17.5(syst.) mb. The ratio of the continuum to resonant contributions for the production of pion pairs is also measured. In addition, the fraction of events accompanied by electromagnetic dissociation of either one or both colliding nuclei is reported. The dependence on A of cross section for the coherent ρ0 photoproduction at a centre-of-mass energy per nucleon of the ÎłA system of WÎłA,n=65 GeV is found to be consistent with a power-law behaviour σ(ÎłA→ρ0A)∝Aα with a slope α=0.96±0.02(syst.). This slope signals important shadowing effects, but it is still far from the behaviour expected in the black-disc limit.publishedVersio
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