Enhanced CO2 absorption kinetics in lithium silicate platelets synthesized by a sol–gel approach

Platelet-shaped lithium orthosilicate particles synthesized by a sol–gel approach employing the precursors lithium nitrate and colloidal silica displayed enhanced absorption kinetics for CO2 compared to the powders prepared by a solid-state reaction process involving Li2CO3 and silica. The sol–gel samples showed a CO2 absorption capacity of 350 mg g-1 at an absorption rate of 22.5 mg g-1 min-1, a value 70% higher than the rate of 13.2 mg g-1 min-1 measured with the solid-state samples under similar conditions. The higher sorption kinetics of CO2 by the sol–gel derived lithium orthosilicate could be attributed to the unique platelet morphology of the particles, which have a very small thickness. A porous carbon mesh coated with the sol–gel based particles exhibited CO2 absorption capacity of 150 mg g-1 at an absorption rate of 37.5 mg g-1 min-1. This supported absorbent also showed stable absorption and desorption performance for the 8 cycles examined in this study. The excellent absorption characteristics of the sol–gel prepared powders, more specifically the coated strips, provide a successful pathway for the commercialisation of these materials

ASEAN and the Dynamics of Resistance to Sovereignty Violation:The Case of the Third Indochina War (1978–1991)

This article investigates the history of ASEAN’s relationship to external intervention in regional affairs. It addresses a specific question: What was the basic cause of the success of ASEAN resistance to the Vietnamese challenge to ASEAN’s sovereignty from 1978-1991? ASEAN’s history is understood in terms of a realist theoretical logic, in terms of the relationship between an ASEAN state with the most compelling interests at stake in a given issue, which I call a ‘vanguard state,’ and selected external powers. Using the Third Indochina War (1978–1991) as a case study, this article contends that ASEAN’s ability to resist violations to the sovereignty of Thailand from a Soviet-backed Vietnam is a consequence of high interest convergence between Thailand, and a designated external power, China

Hyponatremia and hospital outcomes among patients with pneumonia: a retrospective cohort study

<p>Abstract</p> <p>Background</p> <p>Community-acquired (CAP) and nosocomial pneumonias contribute substantially to morbidity and hospital resource utilization. Hyponatremia, occurring in >1/4 of patients with CAP, is associated with greater disease severity and worsened outcomes.</p> <p>Methods</p> <p>To explore how hyponatremia is associated with outcomes in hospitalized patients with pneumonia, we analyzed a large administrative database with laboratory component from January 2004 to December 2005. Hyponatremia was defined as at least two [Na⁺] < 135 mEq/L within 24 hours of admission value.</p> <p>Results</p> <p>Of 7,965 patients with pneumonia, 649 (8.1%) with hyponatremia were older (72.4 ± 15.7 vs. 68.0 ± 22.0, p < 0.01), had a higher mean Deyo-Charlson Comorbidity Index Score (1.7 ± 1.7 vs. 1.6 ± 1.6, p = 0.02), and higher rates of ICU (10.0% vs. 6.3%, p < 0.001) and MV (3.9% vs. 2.3%, p = 0.01) in the first 48 hours of hospitalization than patients with normal sodium. Hyponatremia was associated with an increased ICU (6.3 ± 5.6 vs. 5.3 ± 5.1 days, p = 0.07) and hospital lengths of stay (LOS, 7.6 ± 5.3 vs. 7.0 ± 5.2 days, p < 0.001) and a trend toward increased hospital mortality (5.4% vs. 4.0%, p = 0.1). After adjusting for confounders, hyponatremia was associated with an increased risk of ICU (OR 1.58, 95% CI 1.20–2.08), MV (OR 1.75 95% CI 1.13–2.69), and hospital death (OR 1.3, 95% CI 0.90–1.87) and with increases of 0.8 day to ICU and 0.3 day to hospital LOS, and over $1,300 to total hospital costs.</p> <p>Conclusion</p> <p>Hyponatremia is common among hospitalized patients with pneumonia and is associated with worsened clinical and economic outcomes. Studies in this large population are needed to explore whether prompt correction of [Na⁺] may impact these outcomes.</p

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Numerical simulations of the impacts of land-cover change on cold fronts in South-West Western Australia

The south-west of Western Australia has experienced significant land-cover change as well as a decline in rainfall. Given that most precipitation in the region results from frontal passages, the impact of land-cover change on the dynamics of cold fronts is explored using the Regional Atmospheric Modeling System version 6.0. Frontal simulations are evaluated against high resolution atmospheric soundings, station observations, and gridded rainfall analyses and shown to reproduce the qualitative features of cold fronts. Land-cover change results in a decrease in total frontal precipitation through a decrease in boundary-layer turbulent kinetic energy and vertically integrated moisture convergence, and an increase in wind speed within the lower boundary layer. Such processes contribute to reduced convective rainfall under current vegetation cover

Numerical simulations of the impacts of land-cover change on a southern sea breeze in South-West Western Australia

A sea-breeze event in south-west Western Australia is simulated using the Regional Atmospheric Modelling System (RAMS) version 6.0. The model is evaluated against high resolution soundings as well as station observations and is shown to reproduce the qualitative features of the sea breeze well. Sensitivity tests are carried out to investigate the effects of historical land-cover change and changes in soil moisture on the dynamics of the sea breeze. It is found that land-cover change alone, i.e., a change from wooded grasslands to bare soil, with no change in soil moisture initialisation, does not significantly alter the overall structure of the sea breeze but results in higher surface winds due to the reduced vegetation roughness length, which leads to enhanced surface moisture advection inland. On the other hand, land-cover change in conjunction with increased soil moisture results in a considerably weaker, shallower, and less penetrative sea breeze, and delays its onset and duration. A sea-breeze scaling analysis highlights the impact of increasing soil moisture on reducing the sea-breeze volume flux scale

Validation of a Simple Steady-State Forecast of Minimum Nocturnal Temperatures

A two-layer steady-state resistance model is compared with routine meteorological data collected from the Western Australian wheat belt during 2000-06. Major difficulties in implementing such a model are the correct parameterization for the incoming longwave radiation and estimation of daily soil moisture, neither of which are routinely measured. These difficulties are addressed by testing parameterizations for incoming longwave radiation calibrated to local conditions and incorporating a soil-water balance model based on routine weather data. The modified model has RMSE and biases ranging from 2.4° to 3.1°C and -0.2° to 0.8°C, respectively, across the wheat belt when comparing all minimum nocturnal temperatures. The model is shown to predict frost events approximately 55% of the time and illustrates that frost damage to foliage may occur when screen temperatures are < 2°C