10,598 research outputs found

    Photochemical Redox Decomposition of Aqueous Azidopentaamminechromium(III)

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    Theoretical study of geometries and 1H-chemical shifts of cycloarenes

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    The geometries of the cycloarenes 1–6 with 9–12 annelated benzene rings are determined by means of a π-SCF force-field approach. 1H-chemical shifts are calculated by taking into account ring current and local anisotropic contributions. The importance of annulenoid resonance structures is discussed

    A new web interface to facilitate access to corpora: development of the ASLLRP data access interface

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    A significant obstacle to broad utilization of corpora is the difficulty in gaining access to the specific subsets of data and annotations that may be relevant for particular types of research. With that in mind, we have developed a web-based Data Access Interface (DAI), to provide access to the expanding datasets of the American Sign Language Linguistic Research Project (ASLLRP). The DAI facilitates browsing the corpora, viewing videos and annotations, searching for phenomena of interest, and downloading selected materials from the website. The web interface, compared to providing videos and annotation files off-line, also greatly increases access by people that have no prior experience in working with linguistic annotation tools, and it opens the door to integrating the data with third-party applications on the desktop and in the mobile space. In this paper we give an overview of the available videos, annotations, and search functionality of the DAI, as well as plans for future enhancements. We also summarize best practices and key lessons learned that are crucial to the success of similar projects

    Pushdown machines for the macro tree transducer

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    The macro tree transducer can be considered as a system of recursive function procedures with parameters, where the recursion is on a tree (e.g., the syntax tree of a program). We investigate characterizations of the class of tree (tree-to-string) translations which is induced by macro tree transducers (macro tree-to-string transducers, respectively). For this purpose we define several pushdown machines of which the control is recursive without parameters, or even iterative, and which work on a generalized pushdown as storage. Because of the relevance for semantics of programming languages, we stress (besides the nondeterministic case) the study of machines for the total deterministic macro tree(-to-string) transducer, which translates every input tree into exactly one output tree (string, respectively). Finally, we characterize the n-fold composition of total deterministic macro tree transducers by recursive pushdown machines with an iterated pushdown as storage, which is a pushdown of pushdowns of … of pushdowns
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