4 research outputs found

    Magnetism and magnetocaloric properties of Co1−x_{1-x}Mnx_xCr2_2O4_4

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    Co1−x_{1-x}Mnx_xCr2_2O4_4 crystallizes as a normal spinel in the cubic Fd3‾mFd \overline{3}m space group, and the end members have been reported to display a region of collinear ferrimagnetism as well as a low-temperature spin-spiral state with variable coherence lengths from 3 nm to 10 nm in polycrystalline samples. Here, we present the synthesis of the entire solid solution, and data showing that the ferrimagnetic ordering temperature as well as the spin-spiral lock-in temperature are tunable with the Co/Mn ratio. The peak magnetocaloric entropy change was determined to be ΔSM\Delta S_M = -5.63 J kg−1^{-1} K−1^{-1} in an applied magnetic field change of ΔH\Delta H = 0 T to 5 T for the Mn end-member at the ferrimagnetic ordering temperature. Using density functional theory (DFT), we explore the shortcomings of the magnetic deformation proxy to identify trends in ΔSM\Delta S_M across composition in this spinel system, and explore future extensions of theory to address these discrepancies

    Graphene-Based Smartphone Technologies

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    Graphene is a carbon-based two-dimensional material with a wide range of superlative mechanical, electronic, optical, thermal, and chemical properties. It is currently undergoing research and development for a variety of applications including several technologies used in modern smartphones. In this paper I begin with a general description of graphene’s bonding structure and how this relates to its physical properties. Following this I explain how said properties are harnessed for applications as graphene-based transistors, touchscreens, and rechargeable batteries. Each of these technologies faces fabrication and engineering challenges before commercial viability, but ongoing research is promising for future graphene-based technologie

    The concise guide to PHARMACOLOGY 2013/14:G protein-coupled receptors

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    The Concise Guide to PHARMACOLOGY 2013/14 provides concise overviews of the key properties of over 2000 human drug targets with their pharmacology, plus links to an open access knowledgebase of drug targets and their ligands (www.guidetopharmacology.org), which provides more detailed views of target and ligand properties. The full contents can be found at http://onlinelibrary.wiley.com/doi/10.1111/bph.12444/full. G protein-coupled receptors are one of the seven major pharmacological targets into which the Guide is divided, with the others being G protein-coupled receptors, ligand-gated ion channels, ion channels, catalytic receptors, nuclear hormone receptors, transporters and enzymes. These are presented with nomenclature guidance and summary information on the best available pharmacological tools, alongside key references and suggestions for further reading. A new landscape format has easy to use tables comparing related targets. It is a condensed version of material contemporary to late 2013, which is presented in greater detail and constantly updated on the website www.guidetopharmacology.org, superseding data presented in previous Guides to Receptors and Channels. It is produced in conjunction with NC-IUPHAR and provides the official IUPHAR classification and nomenclature for human drug targets, where appropriate. It consolidates information previously curated and displayed separately in IUPHAR-DB and the Guide to Receptors and Channels, providing a permanent, citable, point-in-time record that will survive database updates

    The Concise Guide to PHARMACOLOGY 2013/14: G Protein-Coupled Receptors

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