Controlling exchange bias in Fe3O4/FeO composite particles prepared by pulsed laser irradiation

Spherical iron oxide nanocomposite particles composed of magnetite and wustite have been successfully synthesized using a novel method of pulsed laser irradiation in ethyl acetate. Both the size and the composition of nanocomposite particles are controlled by laser irradiation condition. Through tuning the laser fluence, the Fe3O4/FeO phase ratio can be precisely controlled, and the magnetic properties of final products can also be regulated. This work presents a successful example of the fabrication of ferro (ferri) (FM)/antiferromagnetic (AFM) systems with high chemical stability. The results show this novel simple method as widely extendable to various FM/AFM nanocomposite systems

Theoretical and experimental investigation of the magnetic properties of polyvinylidene fluoride and magnetite nanoparticles-based nanocomposites

Abstract In the present study, the effect of size distribution of magnetite nanoparticles in a PVDF matrix on the magnetic properties of PVDF + Fe3O4 nanocomposites was experimentally and theoretically investigated. The size distribution of nanoparticles in polymer matrix and morphology of the nanocomposites were studied by the means of scanning electron microscopy and atomic force microscopy. It was found that when the Fe3O4 nanoparticles are introduced into the polymer matrix, their coagulation takes place. The increase in the size of the particles depends on their concentration in the polymer matrix, the type of polymer (polar, non-polar, its viscosity, etc.), reaction temperatures, etc. In addition, when Fe3O4 nanoparticles are introduced into the polymer network, the oxidation of the surface layer of particles occurs and the magnetic size decreases. Consequently, the reduced magnetic properties may also be observed. The hysteresis loops have been recorded in small magnetic field range. It was found that the magnetic hysteresis parameters depend on the size and concentration of Fe3O4 nanoparticles. Theoretical calculations were compared with experimental results obtained from M(H) measurements. The reasons of differences between theoretical and experimental results have been explained

Phytoremediation of soils contaminated with heavy metals: techniques and strategies

Environmental pollution by heavy metals and metalloids has become a severe problem worldwide, as soils became increasingly contaminated, posing a threat to ecosystems and ultimately to human health. The decision to remediate a soil depends on the present and future value of the soil, the cost of remediation, the risk posed by the soil, and the perception of that risk by the population and decision-makers. Traditional technologies to remediate soils usually rely on excavation of the contaminated soil, often disposed of as a hazardous waste with or without a previous treatment. The use of plants to remove or immobilize toxic elements has arisen as a very promising alternative to conventional technologies. The use of plants to remediate soils derived from the observation of wild species found in specific environments, evolved to the use of fast growing crops, and later on led to the development of genetically-modified plants. Phytotechnologies include a wide range of technologies that can be applied to remediate soils through stabilization, volatilization, accumulation and sequestration of toxic metals. In this chapter we describe the impacts of heavy metals in plants and the most important phytotechnologies available to remediate soil and substrates