Coffee and shade trees show complementary use of soil water in a traditional agroforestry ecosystem

Financial support. This research has been supported by the PAPIIT-UNAM (Mexico) (grant nos. IB100313 and IB100113), the CONACyT (Mexico) (grant no. 187646), the National Science Foundation (US) (grant no. 1313804), and the Scottish Funding Council (UK) (grant no. SF10192). Author contributions. LEMV designed the experiment. LEMV, MSAB and FH collected the field data. MSAB performed all the Bayesian mixing model analysis. JG contributed in the data analysis. LEMV prepared the first draft of the manuscript. FH, MSAB and JG edited and commented on the manuscript several times, and TED carried out the final revision. Later, all the co-authors contributed with revisions. Data can be accessed at https://doi.org/10.5063/F1MS3R3J (Muñoz-Villers et al., 2020).Peer reviewedPublisher PD

Tracers reveal limited influence of plantation forests on surface runoff in a UK natural flood management catchment

Study region United Kingdom (UK). Study focus Natural flood management (NFM) schemes are increasingly prominent in the UK. Studies of NFM have not yet used natural tracers at catchment scale to investigate how interventions influence partitioning during storms between surface rainfall runoff and water already stored in catchments. Here we investigate how catchment properties, particularly plantation forestry, influence surface storm rainfall runoff. We used hydrograph separation based on hydrogen and oxygen isotopes (2H, 18O) and acid neutralising capacity from high flow events to compare three headwater catchments (2.4-3.1 km2) with differences in plantation forest cover (Picea sitchensis: 94%, 41%, 1%) within a major UK NFM pilot, typical of the UK uplands. New hydrological insights Plantation forest cover reduced the total storm rainfall runoff fraction during all events (by up to 11%) when comparing two paired catchments with similar soils, geology and topography but ∼50% difference in forest cover. However, comparison with the third catchment, with negligible forest cover but different characteristics, suggests that soils and geology were dominant controls on storm rainfall runoff fraction. Furthermore, differences between events were greater than differences between catchments. These findings suggest that while plantation forest cover may influence storm rainfall runoff fractions, it is not a dominant control in temperate upland UK catchments, especially for larger events. Soils and geology may exert greater influence, with implications for planning NFM

Illuminating hydrological processes at the soil-vegetation-atmosphere interface with water stable isotopes

Funded by DFG research project “From Catchments as Organised Systems to Models based on Functional Units” (FOR 1Peer reviewedPublisher PDFPublisher PD

Temporal dynamics in dominant runoff sources and flow paths in the Andean Páramo

Funded by Central Research Office of the Universidad de Cuenca (DIUC) Secretaría de Educación Superior, Ciencia, Tecnología e Innovación (SENESCYT 112–2012) . Grant Number: SENESCYT 112-2012 German Research Foundation (DFG) . Grant Number: BR2238/14-1Peer reviewedPublisher PD

Trees, forests and water: Cool insights for a hot world

Forest-driven water and energy cycles are poorly integrated into regional, national, continental and global decision-making on climate change adaptation, mitigation, land use and water management. This constrains humanity’s ability to protect our planet’s climate and life-sustaining functions. The substantial body of research we review reveals that forest, water and energy interactions provide the foundations for carbon storage, for cooling terrestrial surfaces and for distributing water resources. Forests and trees must be recognized as prime regulators within the water, energy and carbon cycles. If these functions are ignored, planners will be unable to assess, adapt to or mitigate the impacts of changing land cover and climate. Our call to action targets a reversal of paradigms, from a carbon-centric model to one that treats the hydrologic and climate-cooling effects of trees and forests as the first order of priority. For reasons of sustainability, carbon storage must remain a secondary, though valuable, by-product. The effects of tree cover on climate at local, regional and continental scales offer benefits that demand wider recognition. The forest- and tree-centered research insights we review and analyze provide a knowledge-base for improving plans, policies and actions. Our understanding of how trees and forests influence water, energy and carbon cycles has important implications, both for the structure of planning, management and governance institutions, as well as for how trees and forests might be used to improve sustainability, adaptation and mitigation efforts

Effects of conversion of native cerrado vegetation to pasture on soil hydro-physical properties, evapotranspiration and streamflow on the Amazonian agricultural frontier

Understanding the impacts of land-use change on landscape-hydrological dynamics is one of the main challenges in the Northern Brazilian Cerrado biome, where the Amazon agricultural frontier is located. Motivated by the gap in literature assessing these impacts, we characterized the soil hydro-physical properties and quantified surface water fluxes from catchments under contrasting land-use in this region. We used data from field measurements in two headwater micro-catchments with similar physical characteristics and different land use, i.e. cerrado sensu stricto vegetation and pasture for extensive cattle ranching. We determined hydraulic and physical properties of the soils, applied ground-based remote sensing techniques to estimate evapotranspiration, and monitored streamflow from October 2012 to September 2014. Our results show significant differences in soil hydro-physical properties between the catchments, with greater bulk density and smaller total porosity in the pasture catchment. We found that evapotranspiration is smaller in the pasture (639 ± 31% mm yr-1) than in the cerrado catchment (1,004 ± 24% mm yr-1), and that streamflow from the pasture catchment is greater with runoff coefficients of 0.40 for the pasture and 0.27 for the cerrado catchment. Overall, our results confirm that conversion of cerrado vegetation to pasture causes soil hydro-physical properties deterioration, reduction in evapotranspiration reduction, and increased streamflow

Copper(I) Thiocyanate (CuSCN) Hole-Transport Layers Processed from Aqueous Precursor Solutions and Their Application in Thin-Film Transistors and Highly Efficient Organic and Organometal Halide Perovskite Solar Cells

This study reports the development of copper(I) thiocyanate (CuSCN) hole-transport layers (HTLs) processed from aqueous ammonia as a novel alternative to conventional n-alkyl sulfide solvents. Wide bandgap (3.4–3.9 eV) and ultrathin (3–5 nm) layers of CuSCN are formed when the aqueous CuSCN–ammine complex solution is spin-cast in air and annealed at 100 °C. X-ray photoelectron spectroscopy confirms the high compositional purity of the formed CuSCN layers, while the high-resolution valence band spectra agree with first-principles calculations. Study of the hole-transport properties using field-effect transistor measurements reveals that the aqueous-processed CuSCN layers exhibit a fivefold higher hole mobility than films processed from diethyl sulfide solutions with the maximum values approaching 0.1 cm2 V−1 s−1. A further interesting characteristic is the low surface roughness of the resulting CuSCN layers, which in the case of solar cells helps to planarize the indium tin oxide anode. Organic bulk heterojunction and planar organometal halide perovskite solar cells based on aqueous-processed CuSCN HTLs yield power conversion efficiency of 10.7% and 17.5%, respectively. Importantly, aqueous-processed CuSCN-based cells consistently outperform devices based on poly(3,4-ethylenedioxythiophene) polystyrene sulfonate HTLs. This is the first report on CuSCN films and devices processed via an aqueous-based synthetic route that is compatible with high-throughput manufacturing and paves the way for further developments