29 research outputs found

    Discourse and religion in educational practice

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    Despite the existence of long-held binaries between secular and sacred, private and public spaces, school and religious literacies in many contemporary societies, the significance of religion and its relationship to education and society more broadly has become increasingly topical. Yet, it is only recently that the investigation of the nexus of discourse and religion in educational practice has started to receive some scholarly attention. In this chapter, religion is understood as a cultural practice, historically situated and embedded in specific local and global contexts. This view of religion stresses the social alongside the subjective or experiential dimensions. It explores how through active participation and apprenticeship in culturally appropriate practices and behaviors often mediated intergenerationally and the mobilisation of linguistic and other semiotic resources but also affective, social and material resources, membership in religious communities is constructed and affirmed. The chapter reviews research strands that have explored different aspects of discourse and religion in educational practice as a growing interdisciplinary field. Research strands have examined the place and purpose of religion in general and evangelical Christianity in particular in English Language Teaching (ELT) programmes and the interplay of religion and teaching and learning in a wide range of religious and increasingly secular educational contexts. They provide useful insights for scholars of discourse studies to issues of identity, socialisation, pedagogy and language policy

    Light Lanthanide Metallocenium Cations Exhibiting Weak Equatorial Anion Interactions.

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    As the dysprosocenium complex [Dy(Cpttt )2 ][B(C6 F5 )4 ] (Cpttt =C5 H2 tBu3 -1,2,4, 1-Dy) exhibits magnetic hysteresis at 60 K, similar lanthanide (Ln) complexes have been targeted to provide insights into this remarkable property. We recently reported homologous [Ln(Cpttt )2 ][B(C6 F5 )4 ] (1-Ln) for all the heavier Ln from Gd-Lu; herein, we extend this motif to the early Ln. We find, for the largest LnIII cations, that contact ion pairs [Ln(Cpttt )2 {(C6 F5 -κ1 -F)B(C6 F5 )3 }] (1-Ln; La-Nd) are isolated from reactions of parent [Ln(Cpttt )2 (Cl)] (2-Ln) with [H(SiEt3 )2 ][B(C6 F5 )4 ], where the anion binds weakly to the equatorial sites of [Ln(Cpttt )2 ]+ through a single fluorine atom in the solid state. For smaller SmIII , [Sm(Cpttt )2 ][B(C6 F5 )4 ] (1-Sm) is isolated, which like heavier 1-Ln does not exhibit equatorial anion interactions, but the EuIII analogue 1-Eu could not be synthesised due to the facile reduction of EuIII precursors to EuII products. Thus with the exception of Eu and radioactive Pm this work constitutes a structurally similar family of Ln metallocenium complexes, over 50 years after the [M(Cp)2 ]+ series was isolated for the 3d metals

    Understanding magnetic relaxation in single-ion magnets with high blocking temperature

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    The recent discovery of single-ion magnets with magnetic hysteresis above liquid-nitrogen temperatures placed these compounds among the best candidates to realize high-density storage devices. Starting from a prototypical dysprosocenium molecule, showing hysteresis up to 60 K, we derive here a general recipe to design high-blocking-temperature rare-earth single-ion magnets. The complex magnetic relaxation is unraveled by combining magnetization and nuclear magnetic resonance measurements with inelastic neutron scattering experiments and ab initio calculations, thus disentangling the different mechanisms and identifying the key ingredients behind slow relaxation

    Field- and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet.

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    Understanding quantum tunnelling of the magnetisation (QTM) in single-molecule magnets (SMMs) is crucial for improving performance and achieving molecule-based information storage above liquid nitrogen temperatures. Here, through a field- and temperature-dependent study of the magnetisation dynamics of [Dy(tBuO)Cl(THF)5][BPh4]·2THF, we elucidate the different relaxation processes: field-independent Orbach and Raman mechanisms dominate at high temperatures, a single-phonon direct process dominates at low temperatures and fields >1 kOe, and a field- and temperature-dependent QTM process operates near zero field. Accounting for the exponential temperature dependence of the phonon collision rate in the QTM process, we model the magnetisation dynamics over 11 orders of magnitude and find a QTM tunnelling gap on the order of 10-4 to 10-5 cm-1. We show that removal of Dy nuclear spins does not suppress QTM, and argue that while internal dipolar fields and hyperfine coupling support QTM, it is the dynamic crystal field that drives efficient QTM

    To Brexit or Not to Brexit: The Roles of Islamophobia, Conspiracist Beliefs, and Integrated Threat in Voting Intentions for the United Kingdom European Union Membership Referendum

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    We used an identities approach to examine voting intentions in the June 2016 United Kingdom (UK) referendum on membership of the European Union (EU). In April 2016, 303 British adults (58.7% women, age M = 34.73) indicated their voting intentions for the referendum and completed measures of identification with the national in-group, perceived threat from Muslim immigrants, belief in Islamophobic conspiracy narratives, Islamophobia, general conspiracist beliefs, ambiguity tolerance, and belief in a clash of civilisations. Path and mediation analyses indicated that greater belief in Islamophobic conspiracy theories mediated the link between Islamophobia and intention to vote to leave. Islamophobia and Islamophobic conspiracist beliefs also mediated the effects of perceived threat from Muslims on voting intentions. Other variables acted as antecedents of perceived threat or Islamophobic conspiracy narratives. These findings highlight the role that identity-based cognitions may have played in shaping voting intentions for the UK EU referendum

    Discourse and the Linguistic Landscape

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    Research into the way that linguistic and other semiotic signs are displayed in public space has opened up a productive field for social language analysis over the last few years. Often focused on the policy implications – at both institutional and grass-roots level – of public signage, linguistic landscape research has, from the very beginning, engaged with issues of politics and ideology and thus, indirectly, discourse. In recent years it has also begun to theorise the ways in which semiotic artefacts and practices generate meaning by interacting in explicitly dialogical ways. To date however, theorising that is directed specifically at the relationship between linguistic landscape studies and discourse studies has been slight. This chapter explores the nature of this relationship by focusing on select case studies which exemplify the way that acts of linguistic and semiotic display in the public arena operate as key sites for social organisation and for political regulation and contestation. These short case studies also examine how meaning is generated through complex layering of contexts, the interplay between multiple signs, the narrative potential of landscapes and the dialogic possibilities presented by social media which allow local meanings to be up-scaled and reconfigured, thus pulling site-specific semiotic events into much broader discourses
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