66 research outputs found

    Phase-Modulated Elastic Properties of Two-Dimensional Magnetic FeTe: Hexagonal and Tetragonal Polymorphs

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    Two-dimensional (2D) layered magnets, such as iron chalcogenides, have emerged these years as a new family of unconventional superconductor and provided the key insights to understand the phonon-electron interaction and pairing mechanism. Their mechanical properties are of strategic importance for the potential applications in spintronics and optoelectronics. However, there is still lack of efficient approach to tune the elastic modulus despite the extensive studies. Herein, we report the modulated elastic modulus of 2D magnetic FeTe and its thickness-dependence via phase engineering. The grown 2D FeTe by chemical vapor deposition can present various polymorphs, i.e. tetragonal FeTe (t-FeTe, antiferromagnetic) and hexagonal FeTe (h-FeTe, ferromagnetic). The measured Young's modulus of t-FeTe by nanoindentation method showed an obvious thickness-dependence, from 290.9+-9.2 to 113.0+-8.7 GPa when the thicknesses increased from 13.2 to 42.5 nm, respectively. In comparison, the elastic modulus of h-FeTe remains unchanged. Our results could shed light on the efficient modulation of mechanical properties of 2D magnetic materials and pave the avenues for their practical applications in nanodevices.Comment: 19 pages, 4 figure

    Pressure-Modulated Structural and Magnetic Phase Transitions in Two-Dimensional FeTe: Tetragonal and Hexagonal Polymorphs

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    Two-dimensional (2D) Fe-chalcogenides with rich structures, magnetisms and superconductivities are highly desirable to reveal the torturous transition mechanism and explore their potential applications in spintronics and nanoelectronics. Hydrostatic pressure can effectively stimulate novel phase transitions between various ordered states and to plot the seductive phase diagram. Herein, the structural evolution and transport characteristics of 2D FeTe were systematically investigated under extreme conditions through comparing two distinct symmetries, i.e., tetragonal (t-) and hexagonal (h-) FeTe. We found that 2D t-FeTe presented the pressure-induced transition from antiferromagnetic to ferromagnetic states at ~ 3 GPa, corresponding to the tetragonal collapse of layered structure. Contrarily, ferromagnetic order of 2D h-FeTe was retained up to 15 GPa, evidently confirmed by electrical transport and Raman measurements. Furthermore, the detailed P-T phase diagrams of both 2D t-FeTe and h-FeTe were mapped out with the delicate critical conditions. We believe our results can provide a unique platform to elaborate the extraordinary physical properties of Fe-chalcogenides and further to develop their practical applications.Comment: 22 Pages, 5 Figure

    Large expert-curated database for benchmarking document similarity detection in biomedical literature search

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    Document recommendation systems for locating relevant literature have mostly relied on methods developed a decade ago. This is largely due to the lack of a large offline gold-standard benchmark of relevant documents that cover a variety of research fields such that newly developed literature search techniques can be compared, improved and translated into practice. To overcome this bottleneck, we have established the RElevant LIterature SearcH consortium consisting of more than 1500 scientists from 84 countries, who have collectively annotated the relevance of over 180 000 PubMed-listed articles with regard to their respective seed (input) article/s. The majority of annotations were contributed by highly experienced, original authors of the seed articles. The collected data cover 76% of all unique PubMed Medical Subject Headings descriptors. No systematic biases were observed across different experience levels, research fields or time spent on annotations. More importantly, annotations of the same document pairs contributed by different scientists were highly concordant. We further show that the three representative baseline methods used to generate recommended articles for evaluation (Okapi Best Matching 25, Term Frequency-Inverse Document Frequency and PubMed Related Articles) had similar overall performances. Additionally, we found that these methods each tend to produce distinct collections of recommended articles, suggesting that a hybrid method may be required to completely capture all relevant articles. The established database server located at https://relishdb.ict.griffith.edu.au is freely available for the downloading of annotation data and the blind testing of new methods. We expect that this benchmark will be useful for stimulating the development of new powerful techniques for title and title/abstract-based search engines for relevant articles in biomedical research.Peer reviewe

    Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ido)magnesium

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    The title complex, [Mg(C7H7N4O2)2(H2O)4], lies across an inversion centre and the MgII atom is coordinated in a slightly distorted octahedral environment by four aqua ligands in the equatorial sites and two 1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ide ligands, through imidazole ring N atoms, in the axial sites. An intramolecular O—H...O hydrogen bond forms an S(7) graph-set motif. In the crystal, O—H...O and O—H...N hydrogen bonds link complex molecules forming a three-dimensional network incorporating R42(8) and R22(18) graph-set motifs

    Failure Mechanism and Stability Control Technology of Slope during Open-Pit Combing Underground Extraction: A Case Study from Shanxi Province of China

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    With the development of society, the demand for mineral resources is gradually increasing, and the current situation of decreasing total resources dictates the inevitable interaction between open-pit combing underground extraction (OPUG) in time and space. In this research, we took the Anjialing coal mine in Shanxi Province of China as a case study, and tested the physical and mechanical properties of coal rocks in the laboratory. The similarity criterion was used to build a similar experimental model for the deformation evolution of the slope of the open-pit mine section; the digital scattering method was used to test the influence of the underground mining process parameters on the deformation evolution of the open-pit slope. The results showed that there was an obvious distribution of “three zones” above the mining goaf, namely, a collapse zone, fracture zone, and slow subsidence zone. When the mining face was continuously advanced towards the bottom of the open pit, the supporting stress of the mining face transferred to the side of the open-pit slope. Additionally, large displacement and stress concentration were observed on the slope near the stoping line, which caused the slope body to move along the uppermost part of the slope first, and thereafter along the lower part. Various techniques for slope stability control are discussed, including the optimization of spatial and temporal relationships between open-pit and underground mining, the optimization of mining plans, and the use of monitoring and early warning systems. The results can provide a guide for slope stability control of similar open-pit mines in the process of mining coal resources

    A Modified Micro-Macro Constitutive Model for Porous Rocks with Pressure-Sensitive Matrix by considering a New Hardening Law

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    This paper aims mainly at providing an incremental elastoplastic constitutive model for heterogeneous porous rock-like materials in the frame of micromechanics. The studied material is considered to be made up of randomly distributed spherical pores embedded in a pressure-sensitive solid matrix obeying Drucker–Prager yield function. The effective elastic properties of porous rocks are obtained by the use of Mori and Tanaka homogenization scheme, which are on function of the bulk and shear moduli of the solid matrix and of the value of porosity. For the macroscopic nonlinear phase, a limit analysis-based macroscopic criterion is adopted to derive the basic constitutive rule by considering an associated plastic flow rule. In order to capture the typical hardening effects of rocks, an originally proposed hardening function of the solid matrix is also taken into consideration, which is related on the accumulated equivalent plastic strain. In order to verify its accuracy, the proposed micro-macro constitutive model is implemented by a numerical procedure including elastic predictions and plastic corrections and compared to experimental results of triaxial compression tests of sandstone with different confining pressures. It is observed that the numerical simulation is in accord with the experimental data, indicating that the obtained model is able to predict the main mechanical behaviours of rock-like materials

    A flow-rate-controlled double-nozzles approach for electrochemical additive manufacturing

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    The electrochemical additive manufacturing technique based on the meniscus-confined approach has been proved to be a powerful tool for fabricating nanoscale and microscale metal components. The stability of the meniscus is the key in this meniscus-confined approach to achieve high resolution and reliable product quality. In the present study, a double-nozzles design, which consists of a feed nozzle and a suction nozzle, is proposed for the meniscus confined electrochemical additive manufacturing technique. It was demonstrated that the proposed design possessed robust control of the stability of the meniscus by manipulating the feed and suction rates of the two nozzles in a quite large range. Various sizes of menisci can be easily obtained by utilising nozzles with different sizes. Compared with the pressure-controlled single-nozzle approach, the results showed that dense structures without dendrites can be fabricated by the double-nozzles design with larger current density due to the feed-and-suction process at the tip of the nozzles. The proposed flow-rate-controlled double-nozzles design was finally employed to fabricate some copper circuits and a Cu/CuNi thin film thermocouple to demonstrate its potential in fabricating electronic devices

    Analysis of Metal Work-Function Modulation Effect in Reconfigurable Field-Effect Transistor

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