Performance de la nanofiltration pour l'élimination de la matière organique naturelle: essais sur l'usine de Méry/Oise

L'intérêt croissant que les traiteurs d'eaux portent à l'élimination de la matière organique naturelle (MON) a abouti au développement de nouvelles technologies de traitement. Dans ce but, un prototype de nanofiltration à l'échelle industrielle (2 x 1400 m 3 j-¹) est installé à l'usine de Méry sur Oise depuis juillet 1992. Utilisé en traitement de finition après clarification et filtration sur sable, il alimente depuis février 1993 un réseau test de la commune d'Auvers sur Oise (6 000 hbts) en région parisienne.L'objectif de cette publication est de présenter quelques uns des résultats de caractérisation de la MON obtenus pendant 9 mois d'expérimentation (octobre 1992 à juillet 1993), et en particulier ceux concernant les rendements d'élimination de la matière organique naturelle et par voie de conséquence de la demande en chlore.Ces rendements sont généralement supérieurs à 90 % en termes de COD,CODB et d'absorbance UV à 254 et 270 nm éliminés. L'analyse des potentiels de réactivité avec le chlore (taux de chloration: 2,5 mg Cl2/mg C, temps de réaction: 72 heures, pH = 7,5, 20 °C) montre que le perméat est peu consommateur de chlore (demande en chlore < 0,2 mg l-¹ Cl2) et peu précurseur de chloroforme et de trihalométhanes (PFCHC13 < 3 µg l-¹, PFTHM < 11 µg l-¹). Les rendements d'élimination des PFTHM et PFTOX sont généralement supérieurs à 90 %.L'analyse spécifique des constituants majoritaires du perméat montre que les acides aminés totaux (hydrolyse acide puis dérivation à l'OPA/HPLC) constituent une proportion importante du COD (25 à 60 % selon les saisons). Ces composés représentent la quasi totalité de la demande en chlore du perméat si l'on se réfère aux données bibliographiques.Compte tenu de ces résultats, la nanofiltration apparaît comme un excellent procédé de traitement de finition des eaux à potabiliser. En effet, bien qu'elle constitue une barrière de sécurité contre les germes pathogènes, la très faible charge organique du perméat obtenu par nanofiltration (COD~0,15 à 0,3 mg l-¹ C, CODB<0,1 mg l-¹ C) rend plus aisée la maîtrise du résiduel de chlore (lorsqu'une chloration est nécessaire pour maintenir la qualité de l'eau dans les réseaux) et constitue une limitation importante de la formation des sous-produits de chloration.Increasing interest in removing natural organic matter (NOM) has lead to the development of new drinking water treatment technologies. Since July 1992, a nanofiltration demonstration plant (2 x 1400 m3 d-1) has been used to treat sandfiltered water from the Oise river. The permeate has been distributed since February 1993 to the 6000 inhabitants of Auvers/Oise in the Paris suburb. The purpose of this paper is to present and discuss some ofthe results obtained over nine months of operation of this full scale plant, particularly yields of NOM removal and consequently the decreasing of chlorine reactivity (chlorine demand, TTIM and TOX formation potentials).Dissolved organic carbon (DOC) and UV-absorbance were determined using DOC analyser and a spectrophotometer. Biodegradable dissolved organic carbon (BDOC), which represents the biologically assimilable portion of DOC, was determined using the method of JORET et LEVI (1986). Chlorine demand, trihalomethane and total organohalide formation potentials (THMFP and TOXFP) were carried out under the following experimental conditions: applied chlorine dose of 2.5 mg Cl2/mg DOC, pH = 7,5 72 h-contact time and 20°C. Ultrafiltration experiments involved the use ofa laboratory ultrafiltration cell, Total amino-acids were analysed by HPLC after hydrolysis and orthophtaldialdehyde (OPA) derivatization. Aldehyde and ketone determination was based on the method developedby GLAZE et al. (1989) involving pentafluorobenzyl hydroxyl amine (PFBHA) derivatization.Characterization of sand-filtered water (SFW): The sand-frltered water (SFW) upstream of the nanofiItraton membranes has a DOC between 2.4 and 4.l mg l-1, depending on the season (table 1). Its BDOC ranges from 0.7 to l.l mg l-1 C. In fact, a BDOC value higher than 0.3 mg l-1 C has been mentioned by several authors as the limit above which possible bacterial regrowth can take place in the distribution network.The chlorine consumption curves, shown in figure 2 for five sampling campaigns, indicate that the chlorine demand of the SFW can reach 3.4 to 5.2 mg l-1 depending on the season (table 2). The THMFP and the TOXFP are 108-149 ug l-1 and 344-446 ug l-1 Cl- respectively. Note that the ratio of chlorine demand over DOC varies from 1.0 to 1.7 mg Cl2/mg DOC while the THMFP/DOC and TOXFP/DOC ratios present average values of 47.5 ug/mg DOC and 160 ugCl-/mg DOC respectively.The distribution of the SFW (table 3) indicates that the fraction with apparent mo lecular weight Iess than 3 kilodatons contains the major compounds at this stage of the water treatment. This fraction presents the highest chlorine consumption. Specific total amino acids (TAA) analyses demonstrate that TAA represent 3 to 8% of the DOC of the sand-filtered water. The most abundant arnino acids are glycine, aspartic acid, glutamic acid, serine and alanine. The chlorine consumption attributed to these amino acids is evaluated as 1 mg l-1 Cl2, that is to say 1/5 to 1/3 of the SFW chlorine demand. Formaldehyde and acetaldehyde seem to be the major aldehydes present in the SFW with a level of 7 ug l-1 and 20 ug l-1 of formaldehyde and acetaldehyde respectively. They represent only about 0.5 to 0.6 % of the SFW DOC.Characterization of the permeate: The nanofiltration permeate presents a very low NOM level in terms of DOC, BDOC and UV absorbance at 270 nm, that is to say 0.14 to 0.34 mg l-1 C, < 0.1 mg l-1 C and < 0.006 cm-1-l respectively (table 6).The chlorine consumption curves, showt in figure 4 for five sampling campaigns, demonstrate the low permeate reactivity with chlorine. The chlorine demands (table 7) after 72 hours are between 0.12 and 0.32 mg l-1. Moreover chlorine demand/DOC ratios have a value from 0.46 to 0.93 mg Cl2/mg DOC, i.e. half the values measured for SFW. The THMFP and TOXFP (72hours) range from 7 to 11 ug l-1 and 26 to 31 ug l-1 Cl- respectively.Total amino acid (TAA) analyses showed that TAA represent 35 to 60% of the permeate DOC and can account almost entirely for the chlorine consumption. Formaldehyde and acetaldehyde (the major aldehydes analysed) represent 7 to 8% of the permeate DOC.According to the results presented in this paper, nanofiltration appears to be an excellent technolory as a polishing step in surface water treatment. Whereas the level of sand-fïltered water (SFW) DOC varies from 2.4 to 4.1 mg l-1 C (depending on the season), the permeate DOC is consistently lower than 0.3 mg l-1 C. The efficiency of nanofiltration is about 90% for DOC, BDOC and consequently for chlorine demand, THMFP and TOXFP. The high retention of NOM is probably in relation with the percentage (75%) of compounds with apparent molecular weight above 500 daltons in the SFW. In fact the low values of BDOC and chlorine demand justify the use of nanofiltration for the production of a water which represents a very low risk of bacterial regrowth and a low risk of formation of disinfection by product in the network when distributed with a low concentration of residual chlorine

Development of Vegetation Communities in a Retrogressive Thaw Slump near Mayo, Yukon Territory : A 10-year Assessment

The vegetation in a retrogressive thaw slump, first surveyed and documented in 1987, was revisited 10 years later to investigate its subsequent development and to test a chronosequence-based successional model. The thaw slump stabilized in 1994, when the headwall became covered by organic and mineral debris. As a result, the meltwater supply from headwall ablation ceased. Alteration of environmental conditions due to stabilization of the headwall diverted the vegetation succession from the chronosequence determined in 1987. Areas that were marshy in 1987 dried up, and an area dominated by Polygonum alaskanum appeared close to the headwall. Much of the thaw slump was dominated by Salix spp. in 1997, rather than the Equisteum of 1987. However, the ground more than 200 m from the headwall, over a decade old in 1987, experienced less change in edaphic conditions, and the communities there continued to develop a structure approaching the surrounding undisturbed forest.La végétation située dans un décrochement de fonte régressif, étudiée et documentée pour la première fois en 1987, a fait l'objet d'une autre étude sur place dix ans plus tard pour examiner son évolution et tester un modèle de succession fondé sur la chronoséquence. Le décrochement de fonte s'est stabilisé en 1994, quand le mur de rimaye s'est couvert de débris organiques et minéraux. Il en a résulté que l'alimentation en eau de fonte venant de l'ablation du mur de rimaye a cessé. Le changement dans les conditions environnementales dû à la stabilisation du mur a détourné la succession végétale de la chronoséquence établie en 1987. Des zones qui étaient marécageuses en 1987 se sont asséchées, et une étendue où dominait Polygonum alaskanum apparue près du mur. En 1997, une grande partie de la zone du décrochement de fonte était dominée par des espèces Salix, plutôt qu'Equisteum, comme c'était le cas en 1987. Toutefois, le sol situé à plus de 200 m du mur de rimaye, sol vieux de dix ans en 1987, a subi moins de changement dans les conditions édaphiques, et les communautés y ont continué à évoluer vers une structure qui se rapproche de la forêt non perturbée située à la périphérie

Dynamics of quantum Hall stripes in double-quantum-well systems

The collective modes of stripes in double layer quantum Hall systems are computed using the time-dependent Hartree-Fock approximation. It is found that, when the system possesses spontaneous interlayer coherence, there are two gapless modes, one a phonon associated with broken translational invariance, the other a pseudospin-wave associated with a broken U(1) symmetry. For large layer separations the modes disperse weakly for wavevectors perpendicular to the stripe orientation, indicating the system becomes akin to an array of weakly coupled one-dimensional XY systems. At higher wavevectors the collective modes develop a roton minimum associated with a transition out of the coherent state with further increasing layer separation. A spin wave model of the system is developed, and it is shown that the collective modes may be described as those of a system with helimagnetic ordering.Comment: 16 pages including 7 postscript figure

Stripes in Quantum Hall Double Layer Systems

We present results of a study of double layer quantum Hall systems in which each layer has a high-index Landau level that is half-filled. Hartree-Fock calculations indicate that, above a critical layer separation, the system becomes unstable to the formation of a unidirectional coherent charge density wave (UCCDW), which is related to stripe states in single layer systems. The UCCDW state supports a quantized Hall effect when there is tunneling between layers, and is {\it always} stable against formation of an isotropic Wigner crystal for Landau indices $N \ge 1$. The state does become unstable to the formation of modulations within the stripes at large enough layer separation. The UCCDW state supports low-energy modes associated with interlayer coherence. The coherence allows the formation of charged soliton excitations, which become gapless in the limit of vanishing tunneling. We argue that this may result in a novel {\it ``critical Hall state''}, characterized by a power law $I-V$ in tunneling experiments.Comment: 10 pages, 8 figures include

ISPIDER Central: an integrated database web-server for proteomics

Despite the growing volumes of proteomic data, integration of the underlying results remains problematic owing to differences in formats, data captured, protein accessions and services available from the individual repositories. To address this, we present the ISPIDER Central Proteomic Database search (http://www.ispider.manchester.ac.uk/cgi-bin/ProteomicSearch.pl), an integration service offering novel search capabilities over leading, mature, proteomic repositories including PRoteomics IDEntifications database (PRIDE), PepSeeker, PeptideAtlas and the Global Proteome Machine. It enables users to search for proteins and peptides that have been characterised in mass spectrometry-based proteomics experiments from different groups, stored in different databases, and view the collated results with specialist viewers/clients. In order to overcome limitations imposed by the great variability in protein accessions used by individual laboratories, the European Bioinformatics Institute's Protein Identifier Cross-Reference (PICR) service is used to resolve accessions from different sequence repositories. Custom-built clients allow users to view peptide/protein identifications in different contexts from multiple experiments and repositories, as well as integration with the Dasty2 client supporting any annotations available from Distributed Annotation System servers. Further information on the protein hits may also be added via external web services able to take a protein as input. This web server offers the first truly integrated access to proteomics repositories and provides a unique service to biologists interested in mass spectrometry-based proteomics

Bias-voltage induced phase-transition in bilayer quantum Hall ferromagnets

We consider bilayer quantum Hall systems at total filling factor $\nu=1$ in presence of a bias voltage $\Delta_v$ which leads to different filling factors in each layer. We use auxiliary field functional integral approach to study mean-field solutions and collective excitations around them. We find that at large layer separation, the collective excitations soften at a finite wave vector leading to the collapse of quasiparticle gap. Our calculations predict that as the bias voltage is increased, bilayer systems undergo a phase transition from a compressible state to a $\nu=1$ phase-coherent state {\it with charge imbalance}. We present simple analytical expressions for bias-dependent renormalized charge imbalance and pseudospin stiffness which are sensitive to the softening of collective modes.Comment: 12 pages, 5 figures. Minor changes, one reference adde

Analytical approach to bit-string models of language evolution

A formulation of bit-string models of language evolution, based on differential equations for the population speaking each language, is introduced and preliminarily studied. Connections with replicator dynamics and diffusion processes are pointed out. The stability of the dominance state, where most of the population speaks a single language, is analyzed within a mean-field-like approximation, while the homogeneous state, where the population is evenly distributed among languages, can be exactly studied. This analysis discloses the existence of a bistability region, where dominance coexists with homogeneity as possible asymptotic states. Numerical resolution of the differential system validates these findings.Comment: To appear in Int. J. Mod. Phys.

Search for direct production of charginos and neutralinos in events with three leptons and missing transverse momentum in √s = 7 TeV pp collisions with the ATLAS detector

A search for the direct production of charginos and neutralinos in final states with three electrons or muons and missing transverse momentum is presented. The analysis is based on 4.7 fb−1 of proton–proton collision data delivered by the Large Hadron Collider and recorded with the ATLAS detector. Observations are consistent with Standard Model expectations in three signal regions that are either depleted or enriched in Z-boson decays. Upper limits at 95% confidence level are set in R-parity conserving phenomenological minimal supersymmetric models and in simplified models, significantly extending previous results

Search for H→γγ produced in association with top quarks and constraints on the Yukawa coupling between the top quark and the Higgs boson using data taken at 7 TeV and 8 TeV with the ATLAS detector

A search is performed for Higgs bosons produced in association with top quarks using the diphoton decay mode of the Higgs boson. Selection requirements are optimized separately for leptonic and fully hadronic final states from the top quark decays. The dataset used corresponds to an integrated luminosity of 4.5 fb−14.5 fb−1 of proton–proton collisions at a center-of-mass energy of 7 TeV and 20.3 fb−1 at 8 TeV recorded by the ATLAS detector at the CERN Large Hadron Collider. No significant excess over the background prediction is observed and upper limits are set on the tt¯H production cross section. The observed exclusion upper limit at 95% confidence level is 6.7 times the predicted Standard Model cross section value. In addition, limits are set on the strength of the Yukawa coupling between the top quark and the Higgs boson, taking into account the dependence of the tt¯H and tH cross sections as well as the H→γγ branching fraction on the Yukawa coupling. Lower and upper limits at 95% confidence level are set at −1.3 and +8.0 times the Yukawa coupling strength in the Standard Model

Measurements of fiducial cross-sections for t\bart production with one or two additional b-jets in pp collisions at √s =8 TeVusing the ATLAS detector

Fiducial cross-sections for $t\bar{t}$ production with one or two additional $b$-jets are reported, using an integrated luminosity of 20.3 fb$^{-1}$ of proton--proton collisions at a centre-of-mass energy of 8 TeV at the Large Hadron Collider, collected with the ATLAS detector. The cross-section times branching ratio for $t\bar{t}$ events with at least one additional $b$-jet is measured to be 950 $\pm$ 70 (stat.) $^{+240}_{-190}$ (syst.) fb in the lepton-plus-jets channel and 50 $\pm$ 10 (stat.) $^{+15}_{-10}$ (syst.) fb in the $e \mu$ channel. The cross-section times branching ratio for events with at least two additional $b$-jets is measured to be 19.3 $\pm$ 3.5 (stat.) $\pm$ 5.7 (syst.) fb in the dilepton channel ($e \mu$,\,$\mu\mu$, and \,$ee$) using a method based on tight selection criteria, and 13.5 $\pm$ 3.3 (stat.) $\pm$ 3.6 (syst.) fb using a looser selection that allows the background normalisation to be extracted from data. The latter method also measures a value of 1.30 $\pm$ 0.33 (stat.) $\pm$ 0.28 (syst.)\% for the ratio of $t\bar{t}$ production with two additional $b$-jets to $t\bar{t}$ production with any two additional jets. All measurements are in good agreement with recent theory predictions.Comment: 41 pages plus author list + cover page (58 total), 9 Figures, 16 tables, submitted to EPJC, all figures including auxiliary figures are available at https://atlas.web.cern.ch/Atlas/GROUPS/PHYSICS/PAPERS/TOPQ-2014-10