Evaluation of band gap energy of TiO2 precipitated from titanium sulphate

The determination of the band gap energy () of semiconductors powder materials can be performed from diffuse reflectance spectroscopy (DRS) measurements. For this purpose, the classical theory proposed by Kubelka and Munk (K-M) and the so-called plot Tauc, both discussed here, have been largely employed. We investigate the values of anatase TiO2 particles synthesized by precipitation of titanyl sulphate in the presence of 5% ammonia solution and titanium and iron salts. Based on K-M function and Tauc plot and considering that the TiO2 anatase phase is an indirect band gap semiconductor, our results indicate that the samples subjected to a mechanochemical treatment (mill rotation speed equal to 300 rpm) present substantially lower values compared to those reported by other authors in a recent work(undefined

Applied optics in the development of smart asphalt mixtures

The functionalization of asphalt mixtures is carried out in order to provide new capabilities to the road pavements, with major social, environmental and financial benefits. Optical characterization techniques as well as optical processes like photocatalysis play a major role in the development of new asphalt mixtures with smart functions. These advanced capabilities which are being developed in asphalt mixtures are: photocatalytic, superhydrophobic, self-cleaning, de-icing/anti-ice, self-healing, thermochromic, and latent heat thermal energy storage. The main objective of this research work is to stress the importance of optics and photonics technologies giving an overview of advanced functionalized smart asphalt mixtures.This work was supported by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Funding UIDB/04650/2020. This work was partially financed by FCT - Fundação para a Ciência e a Tecnologia - under the projects of the Strategic Funding UIDB/04650/2020, MicroCoolPav project EXPL/EQU-EQU/1110/2021, and NanoAir project PTDC/FISMAC/6606/2020

Advancements in phase change materials in asphalt pavements for mitigation of urban heat island effect: bibliometric analysis and systematic review

This research presents a dual-pronged bibliometric and systematic review of the integration of phase change materials (PCMs) in asphalt pavements to counteract the urban heat island (UHI) effect. The bibliometric approach discerns the evolution of PCM-inclusion asphalt research, highlighting a marked rise in the number of publications between 2019 and 2022. Notably, Chang’an University in China has emerged as a leading contributor. The systematic review addresses key questions like optimal PCM types for UHI effect mitigation, strategies for PCM leakage prevention in asphalt, and effects on mechanical properties. The findings identify polyethylene glycols (PEGs), especially PEG2000 and PEG4000, as prevailing PCMs due to their wide phase-change temperature range and significant enthalpy during phase transitions. While including PCMs can modify asphalt’s mechanical attributes, such mixtures typically stay within performance norms. This review emphasises the potential of PCMs in urban heat management and the need for further research to achieve optimal thermal and mechanical balanceThis research was partially funded by the Portuguese Foundation for Science and Technology (FCT) under the framework of the projects MicroCoolPav EXPL/EQU-EQU/1110/2021, NanoAir PTDC/FIS-MAC/6606/2020, UIDB/04650/2020, and UIDB/04029/2020. This research was also supported by the doctoral Grant PRT/BD/154269/2022 financed by the FCT, and with funds from POR Norte-Portugal 2020 and State Budget, under MIT Portugal Program. I.R.S. would like to acknowledge the FCT for funding (2022.00763.CEECIND). V.C.B. acknowledges the Fundação Cearense de Apoio ao Desenvolvimento Científico e Tecnológico (Funcap), MLC-0191- 00144.01.00/22 (Edital Mulheres na Ciência), and the National Council for Scientific and Technological Development (CNPq), Process 404978/2021-5—Call CNPq/MCTI/FNDCT N° 18/2021—Faixa B—Consolidated Groups

Asphalt binder "Skincare"? aging evaluation of an asphalt binder modified by Nano-TiO2

Aging by oxidation of asphalt roadway material promotes changes in its physical, chemical, and rheological properties, affecting its hardening and accelerating the degradation of its corresponding asphalt mixture. Titanium dioxide (TiO2) has been applied in engineering investigations to promote anti-aging and photocatalytic properties. In this study, a commercial binder was modified with nano-TiO2 (using contents of 0.1, 0.25, 0.5, 1, 2, 3, and 6%). It was evaluated by physicochemical and rheological tests (penetration, softening point, mass loss, dynamic viscosity, rheology, and Fourier transform infrared spectroscopy-FTIR) before and after aging by rolling thin-film oven test (RTFOT) and pressure aging vessel (PAV). The results indicated that incorporating nano-TiO2 mitigates binder aging, pointing out 0.25% as an optimum modification content for the investigated asphalt binder.This research was partially funded by the Portuguese Foundation for Science and Technology (FCT), PhD scholarship SFRH/BD/137421/2018, NanoAir PTDC/FISMAC/6606/2020, UIDB/04650/2020, and UIDB/04029/2020. V.C.B. would like to acknowledge National Council for Scientific and Technological Development (CNPq) for the funding on behalf of the scholarship 308360/2017-6. Furthermore, we would like to thank the Industrial Research Fund (IOF) for funding the PAPPoA project (IOF/SBO/41859/2020)

Pavimentos rodoviários termosensitivos: funcionalização com termocápsulas para mitigação dos efeitos de ilha de calor

A coloração preta dos pavimentos rodoviários acentua a absorção de energia em forma de calor e contribui para o fenómeno de ilha de calor, que possui impactos relacionados com o ambiente, o consumo de energia e a saúde. Através da concessão de novas habilidades (funcionalização) por aspersão superficial de um revestimento contendo uma solução com corante e partículas termocromáticas (termocápsulas), cuja mudança de cor é sensível a variações de temperatura, foi possível alterar reversivelmente a cor da superfície do pavimento a partir de 30 °C e apresentar uma solução capaz de ajudar a reduzir a temperatura em meio urbano.Os autores agradecem o apoio da Fundação para a Ciência e Tecnologia (FCT), NanoAir PTDC/FISMAC/6606/2020, UIDB/04650/2020 e UIDB/04029/2020

Search for chargino-neutralino production with mass splittings near the electroweak scale in three-lepton final states in √s=13 TeV pp collisions with the ATLAS detector

A search for supersymmetry through the pair production of electroweakinos with mass splittings near the electroweak scale and decaying via on-shell W and Z bosons is presented for a three-lepton final state. The analyzed proton-proton collision data taken at a center-of-mass energy of √s=13  TeV were collected between 2015 and 2018 by the ATLAS experiment at the Large Hadron Collider, corresponding to an integrated luminosity of 139  fb−1. A search, emulating the recursive jigsaw reconstruction technique with easily reproducible laboratory-frame variables, is performed. The two excesses observed in the 2015–2016 data recursive jigsaw analysis in the low-mass three-lepton phase space are reproduced. Results with the full data set are in agreement with the Standard Model expectations. They are interpreted to set exclusion limits at the 95% confidence level on simplified models of chargino-neutralino pair production for masses up to 345 GeV

Observation of associated near-side and away-side long-range correlations in √sNN=5.02 TeV proton-lead collisions with the ATLAS detector

Two-particle correlations in relative azimuthal angle (Δϕ) and pseudorapidity (Δη) are measured in √sNN=5.02  TeV p+Pb collisions using the ATLAS detector at the LHC. The measurements are performed using approximately 1  μb-1 of data as a function of transverse momentum (pT) and the transverse energy (ΣETPb) summed over 3.1<η<4.9 in the direction of the Pb beam. The correlation function, constructed from charged particles, exhibits a long-range (2<|Δη|<5) “near-side” (Δϕ∼0) correlation that grows rapidly with increasing ΣETPb. A long-range “away-side” (Δϕ∼π) correlation, obtained by subtracting the expected contributions from recoiling dijets and other sources estimated using events with small ΣETPb, is found to match the near-side correlation in magnitude, shape (in Δη and Δϕ) and ΣETPb dependence. The resultant Δϕ correlation is approximately symmetric about π/2, and is consistent with a dominant cos⁡2Δϕ modulation for all ΣETPb ranges and particle pT

Measurement of the cross-section of high transverse momentum vector bosons reconstructed as single jets and studies of jet substructure in pp collisions at √s = 7 TeV with the ATLAS detector

This paper presents a measurement of the cross-section for high transverse momentum W and Z bosons produced in pp collisions and decaying to all-hadronic final states. The data used in the analysis were recorded by the ATLAS detector at the CERN Large Hadron Collider at a centre-of-mass energy of √s = 7 TeV;{\rm Te}{\rm V}$and correspond to an integrated luminosity of$4.6\;{\rm f}{{{\rm b}}^{-1}}$. The measurement is performed by reconstructing the boosted W or Z bosons in single jets. The reconstructed jet mass is used to identify the W and Z bosons, and a jet substructure method based on energy cluster information in the jet centre-of-mass frame is used to suppress the large multi-jet background. The cross-section for events with a hadronically decaying W or Z boson, with transverse momentum${{p}_{{\rm T}}}\gt 320\;{\rm Ge}{\rm V}$and pseudorapidity$|\eta |\lt 1.9$, is measured to be${{\sigma }_{W+Z}}=8.5\pm 1.7$ pb and is compared to next-to-leading-order calculations. The selected events are further used to study jet grooming techniques

Search for the neutral Higgs bosons of the minimal supersymmetric standard model in pp collisions at root s=7 TeV with the ATLAS detector

A search for neutral Higgs bosons of the Minimal Supersymmetric Standard Model (MSSM) is reported. The analysis is based on a sample of proton-proton collisions at a centre-of-mass energy of 7TeV recorded with the ATLAS detector at the Large Hadron Collider. The data were recorded in 2011 and correspond to an integrated luminosity of 4.7 fb-1 to 4.8 fb-1. Higgs boson decays into oppositely-charged muon or τ lepton pairs are considered for final states requiring either the presence or absence of b-jets. No statistically significant excess over the expected background is observed and exclusion limits at the 95% confidence level are derived. The exclusion limits are for the production cross-section of a generic neutral Higgs boson, φ, as a function of the Higgs boson mass and for h/A/H production in the MSSM as a function of the parameters mA and tan β in the mhmax scenario for mA in the range of 90GeV to 500 GeV. Copyright CERN

Measurements of fiducial and differential cross sections for Higgs boson production in the diphoton decay channel at s√=8 TeV with ATLAS

Measurements of fiducial and differential cross sections are presented for Higgs boson production in proton-proton collisions at a centre-of-mass energy of s√=8 TeV. The analysis is performed in the H → γγ decay channel using 20.3 fb−1 of data recorded by the ATLAS experiment at the CERN Large Hadron Collider. The signal is extracted using a fit to the diphoton invariant mass spectrum assuming that the width of the resonance is much smaller than the experimental resolution. The signal yields are corrected for the effects of detector inefficiency and resolution. The pp → H → γγ fiducial cross section is measured to be 43.2 ±9.4(stat.) − 2.9 + 3.2 (syst.) ±1.2(lumi)fb for a Higgs boson of mass 125.4GeV decaying to two isolated photons that have transverse momentum greater than 35% and 25% of the diphoton invariant mass and each with absolute pseudorapidity less than 2.37. Four additional fiducial cross sections and two cross-section limits are presented in phase space regions that test the theoretical modelling of different Higgs boson production mechanisms, or are sensitive to physics beyond the Standard Model. Differential cross sections are also presented, as a function of variables related to the diphoton kinematics and the jet activity produced in the Higgs boson events. The observed spectra are statistically limited but broadly in line with the theoretical expectations