Impact of stirring regime on piezocatalytic dye degradation using BaTiO3 nanoparticles

There is increasing demand to use readily accessible waste energy to drive environmentally friendly processes. Piezocatalysis, the process of converting mechanical energy such as vibration into a chemical process, is a breakthrough next generation approach to meet this challenge. However, these systems currently focus on using ultrasound to drive the chemical reaction and are therefore expensive to operate. We show that by using simple mechanical stirring and BaTiO3 particles we can remove Rhodamine B dye molecules from solution. After evaluating a range of stirring parameters, we demonstrate that there is an interplay between stirring speed, volume of liquid, catalyst structure and rate of dye removal. Our maximum degradation rate was 12.05 mg. g-1 catalyst after 1 hour of mechanical stirring at favourable conditions. This development provides a new insight into a low energy physical technique that can be used in environmental remediation processes

Understanding the effect of saturated gases on catalytic performance of graphitic‐carbon nitride (g‐C₃N₄) for H₂O₂ generation and dye degradation in the presence of ultrasound

This paper examines the effect of saturated gases on H2O2 generation and dye degradation using graphitic‐carbon nitride (g‐C3N4) as a piezoelectric catalyst. A detailed catalytic evaluation was carried out using a double‐bath sono‐reactor, where the performance of g‐C3N4 for H2O2 production and degradation of rhodamine B and indigo carmine dyes was evaluated for a range of catalyst dosage levels and saturated gases. Specific gases were selected to understand their role in the sonochemical production of reactive oxygen species (ROS) and reactive nitrogen species (RNS) and to elucidate the potential catalytic mechanism. The use of an Ar‐O2 gas mixture led to the highest yield for H2O2 production and dye degradation due to the positive effect of argon and oxygen in the generation of H2O2 and reactive oxygen species, respectively. The presence of nitrogen in both air and in an Ar‐air mixture increased H2O2 generation since reactive nitrogen species improved the conversion of •OH into H2O2. In contrast, air and Ar‐air negatively influenced the generation of ROS, which resulted in a low rate of dye degradation. This work provides new insights of the mechanisms of sonochemical and piezocatalytic processes in the use of graphitic‐carbon nitride in catalytic applications.This article is protected by copyright. All rights reserved

Village Baseline Study: Site Analysis Report for Tra Hat Village, Vinh Loi, Bac Lieu, Viet Nam (VNM 03)

This report presents data collected from the Village Baseline Study conducted on 2-4 October 2014 at the Tra Hat village, Vinh Loi district, Bac Lieu, Vietnam. Data were collected through focus group discussions and participatory resource mapping with community members in the village. The Village Baseline Study is part of the baseline activities conducted under the CGIAR Research Program on Climate Change, Agriculture, and Food Security (CCAFS) in South East Asia. The purpose is to collect data for indicators that will allow site comparability and monitoring to assess changes in terms of food security and natural resource management across time. Results show that the men and women in Tra Hat village consider farmland, rivers and canals as important natural resources. The quality, however, of land, water and wildlife habitats has declined in the last decade along with the improvement of farming techniques and intensive use of chemical fertilizers and pesticides. Infrastructures such as roads, internal canals, hospitals, schools, water supply station and electricity transformer station have improved. The future is envisioned to have improved internal canals in farmlands and a developed irrigation system, dykes and sluices to support high agriculture production. Home garden diversification was also believed to enhance food security and improve livelihood resilience. To turn the vision into reality, the community expects support from the different organizations working in the area considering current impacts of salinity intrusion and sea level rise, the need interventions of CCAFS and its partners. Strengthening the irrigation system, improving local rice variety, and introducing modern farming techniques taking into account negative impacts of climate change are major recommendation for future intervention

Exponential decay of Laplacian eigenfunctions in domains with branches

The behavior of Laplacian eigenfunctions in domains with branches is investigated. If an eigenvalue is below a threshold which is determined by the shape of the branch, the associated eigenfunction is proved to exponentially decay inside the branch. The decay rate is twice the square root of the difference between the threshold and the eigenvalue. The derived exponential estimate is applicable for arbitrary domains in any spatial dimension. Numerical simulations illustrate and further extend the theoretical estimate

First Observation of Coherent π0\pi^0 Production in Neutrino Nucleus Interactions with Eν<E_{\nu}< 2 GeV

The MiniBooNE experiment at Fermilab has amassed the largest sample to date of $\pi^0$s produced in neutral current (NC) neutrino-nucleus interactions at low energy. This paper reports a measurement of the momentum distribution of $\pi^0$s produced in mineral oil (CH$_2$) and the first observation of coherent $\pi^0$ production below 2 GeV. In the forward direction, the yield of events observed above the expectation for resonant production is attributed primarily to coherent production off carbon, but may also include a small contribution from diffractive production on hydrogen. Integrated over the MiniBooNE neutrino flux, the sum of the NC coherent and diffractive modes is found to be (19.5 $\pm$1.1 (stat) $\pm$2.5 (sys))% of all exclusive NC $\pi^0$ production at MiniBooNE. These measurements are of immediate utility because they quantify an important background to MiniBooNE's search for $\nu_{\mu} \to \nu_e$ oscillations.Comment: Submitted to Phys. Lett.

Grain Surface Models and Data for Astrochemistry

AbstractThe cross-disciplinary field of astrochemistry exists to understand the formation, destruction, and survival of molecules in astrophysical environments. Molecules in space are synthesized via a large variety of gas-phase reactions, and reactions on dust-grain surfaces, where the surface acts as a catalyst. A broad consensus has been reached in the astrochemistry community on how to suitably treat gas-phase processes in models, and also on how to present the necessary reaction data in databases; however, no such consensus has yet been reached for grain-surface processes. A team of ∼25 experts covering observational, laboratory and theoretical (astro)chemistry met in summer of 2014 at the Lorentz Center in Leiden with the aim to provide solutions for this problem and to review the current state-of-the-art of grain surface models, both in terms of technical implementation into models as well as the most up-to-date information available from experiments and chemical computations. This review builds on the results of this workshop and gives an outlook for future directions

Time-integrated luminosity recorded by the BABAR detector at the PEP-II e+e- collider

This article is the Preprint version of the final published artcile which can be accessed at the link below.We describe a measurement of the time-integrated luminosity of the data collected by the BABAR experiment at the PEP-II asymmetric-energy e+e- collider at the ϒ(4S), ϒ(3S), and ϒ(2S) resonances and in a continuum region below each resonance. We measure the time-integrated luminosity by counting e+e-→e+e- and (for the ϒ(4S) only) e+e-→μ+μ- candidate events, allowing additional photons in the final state. We use data-corrected simulation to determine the cross-sections and reconstruction efficiencies for these processes, as well as the major backgrounds. Due to the large cross-sections of e+e-→e+e- and e+e-→μ+μ-, the statistical uncertainties of the measurement are substantially smaller than the systematic uncertainties. The dominant systematic uncertainties are due to observed differences between data and simulation, as well as uncertainties on the cross-sections. For data collected on the ϒ(3S) and ϒ(2S) resonances, an additional uncertainty arises due to ϒ→e+e-X background. For data collected off the ϒ resonances, we estimate an additional uncertainty due to time dependent efficiency variations, which can affect the short off-resonance runs. The relative uncertainties on the luminosities of the on-resonance (off-resonance) samples are 0.43% (0.43%) for the ϒ(4S), 0.58% (0.72%) for the ϒ(3S), and 0.68% (0.88%) for the ϒ(2S).This work is supported by the US Department of Energy and National Science Foundation, the Natural Sciences and Engineering Research Council (Canada), the Commissariat à l’Energie Atomique and Institut National de Physique Nucléaire et de Physiquedes Particules (France), the Bundesministerium für Bildung und Forschung and Deutsche Forschungsgemeinschaft (Germany), the Istituto Nazionale di Fisica Nucleare (Italy), the Foundation for Fundamental Research on Matter (The Netherlands), the Research Council of Norway, the Ministry of Education and Science of the Russian Federation, Ministerio de Ciencia e Innovación (Spain), and the Science and Technology Facilities Council (United Kingdom). Individuals have received support from the Marie-Curie IEF program (European Union) and the A.P. Sloan Foundation (USA)

Search for direct production of charginos and neutralinos in events with three leptons and missing transverse momentum in √s = 7 TeV pp collisions with the ATLAS detector

A search for the direct production of charginos and neutralinos in final states with three electrons or muons and missing transverse momentum is presented. The analysis is based on 4.7 fb−1 of proton–proton collision data delivered by the Large Hadron Collider and recorded with the ATLAS detector. Observations are consistent with Standard Model expectations in three signal regions that are either depleted or enriched in Z-boson decays. Upper limits at 95% confidence level are set in R-parity conserving phenomenological minimal supersymmetric models and in simplified models, significantly extending previous results

Jet size dependence of single jet suppression in lead-lead collisions at sqrt(s(NN)) = 2.76 TeV with the ATLAS detector at the LHC

Measurements of inclusive jet suppression in heavy ion collisions at the LHC provide direct sensitivity to the physics of jet quenching. In a sample of lead-lead collisions at sqrt(s) = 2.76 TeV corresponding to an integrated luminosity of approximately 7 inverse microbarns, ATLAS has measured jets with a calorimeter over the pseudorapidity interval |eta| < 2.1 and over the transverse momentum range 38 < pT < 210 GeV. Jets were reconstructed using the anti-kt algorithm with values for the distance parameter that determines the nominal jet radius of R = 0.2, 0.3, 0.4 and 0.5. The centrality dependence of the jet yield is characterized by the jet "central-to-peripheral ratio," Rcp. Jet production is found to be suppressed by approximately a factor of two in the 10% most central collisions relative to peripheral collisions. Rcp varies smoothly with centrality as characterized by the number of participating nucleons. The observed suppression is only weakly dependent on jet radius and transverse momentum. These results provide the first direct measurement of inclusive jet suppression in heavy ion collisions and complement previous measurements of dijet transverse energy imbalance at the LHC.Comment: 15 pages plus author list (30 pages total), 8 figures, 2 tables, submitted to Physics Letters B. All figures including auxiliary figures are available at http://atlas.web.cern.ch/Atlas/GROUPS/PHYSICS/PAPERS/HION-2011-02