Análisis de las potencialidades de un destino como sede receptora de eventos

El presente trabajo pretende mostrar la repercusion del turismo de reuniones como elemento desestacionalizador respecto a los mercados ya consolidados en algunos destinos y como diversificador de la economía local al contribuir a la generación de empleo y a la creación de nuevos flujos económicos para los destinos emergentes. A lo largo del presente trabajo se analizarán los factores clave de éxito de un destino como sede receptora de eventos. Se analizan los principales atractivos y servicios, aspectos económicos y sociales, beneficios e los impactos negativos que influyen en la apuesta de un destino por esta modalidad turística. La segunda parte del tfg presenta una aproximación metodológica orientada a la identificación de las potencialidades de un destino como sede de eventos basada en tres grandes bloques: El análisis de la situación actual del destino. La identificación del perfil del turista potencial. Y, el tercer bloque consiste en la definición de un producto de turismo de reuniones.This paper aims to show the repercussions of business tourism as diversifier element regarding already established in some markets and destinations for diversifying the local economy by contributing to the creation of jobs and the creation of new financial flows to emerging destinations. Throughout the present work the key success factors of a destination like receiving host events will be analyzed. The main attractions and services, economic and social aspects, benefits and negative impacts that influence the wager by this tourist destination mode are analyzed. The second part of tfg presents a methodological approach aimed at identifying the potential of a destination to host events based on three main blocks: Analysis of the current situation of the destination. Identification of potential tourist profile. And, the third block is the definition of a product of business tourism.Cabrelles Lopez, G. (2014). Análisis de las potencialidades de un destino como sede receptora de eventos. Universitat Politècnica de València. http://hdl.handle.net/10251/46955Archivo delegad

A fluorinated 2D magnetic coordination polymer

Herein we show the versatility of coordination chemistry to design and expand a family of 2D materials by incorporating F groups at the surface of the layers. Through of use of a prefuntionalized organic linker with F groups, it is possible to achieve a layered magnetic material based on Fe(II) centers that are chemically stable in open air, contrary to the known 2D inorganic magnetic materials. The high quality of the single crystals and their robustness allow to fabricate 2D molecular materials by micromechanical exfoliation, preserving the crystalline nature of these layers together with the desired functionalization

How reproducible is the synthesis of Zr--porphyrin metal--organic frameworks? An interlaboratory study

Metal--organic frameworks (MOFs) are a rapidly growing class of materials that offer great promise in various applications. However, the synthesis remains challenging: for example, a range of crystal structures can often be accessed from the same building blocks, which complicates the phase selectivity. Likewise, the high sensitivity to slight changes in synthesis conditions may cause reproducibility issues. This is crucial, as it hampers the research and commercialisation of affected MOFs. Here, we present the first-ever interlaboratory study of the synthetic reproducibility of two Zr--porphyrin MOFs, PCN-222 and PCN-224, to investigate the scope of this problem. For PCN-222, only one sample out of ten was phase pure and of the correct symmetry, while for PCN-224, three were phase pure, although none of these show the spatial linker order characteristic of PCN-224. Instead, these samples resemble dPCN-224 (disordered PCN-224), which was recently reported by us. The variability in thermal behaviour, defect content, and BET surface area of the synthesised samples are also studied. Our results have important ramifications for field of metal--organic frameworks and their crystallisation, by highlighting the synthetic challenges associated with a multi-variable synthesis space and flat energy landscapes characteristic of MOFs

How reproducible is the synthesis of Zr–porphyrin metal–organic frameworks? An interlaboratory study

Metal–organic frameworks (MOFs) are a rapidly growing class of materials that offer great promise in various applications. However, the synthesis remains challenging: for example, a range of crystal structures can often be accessed from the same building blocks, which complicates the phase selectivity. Likewise, the high sensitivity to slight changes in synthesis conditions may cause reproducibility issues. This is crucial, as it hampers the research and commercialisation of affected MOFs. Here, we present the first-ever interlaboratory study of the synthetic reproducibility of two Zr–porphyrin MOFs, PCN-222 and PCN-224, to investigate the scope of this problem. For PCN-222, only one sample out of ten was phase pure and of the correct symmetry, while for PCN-224, three were phase pure, although none of these show the spatial linker order characteristic of PCN-224. Instead, these samples resemble dPCN-224 (disordered PCN-224), which was recently reported by us. The variability in thermal behavior, defect content, and BET surface area of the synthesised samples are also studied. Our results have important ramifications for field of metal–organic frameworks and their crystallisation, by highlighting the synthetic challenges associated with a multi-variable synthesis space and flat energy landscapes characteristic of MOFs