157 research outputs found

    Wide-field compensation of monochromatic eye aberrations: expected performance and design trade-offs

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    Contiene: fórmulas y 6 ilustraciones.The optical quality of the human eye varies across the visual field. Hence an exact compensation of the eye aberration for a given field point can give rise to a less-than-optimum compensation in neighboring field regions. We have studied some aspects of this problem and present here an approach to design wide-field (,10°) optically thin correcting elements, e.g., phase plates, deformable mirrors, and liquid-crystal displays. Their expected performance is assessed using actual eye aberration data. Particular attention is given to the design of elements providing a minimum averaged rms residual aberration and those providing a nearly uniform rms residual aberration across a given field.Work supported by the Spanish Ministerio de Ciencia y Tecnología, Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica (I 1 D 1 I), DPI2002-04370-C02. - This paper was published in Journal of the Optical Society of America A, and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: http://www.opticsinfobase.org/abstract.cfm?URI=josaa-20-1-1. Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under law.Peer reviewe

    A guide to qualitative haze measurements demonstrated on inkjet-printed silver electrodes for flexible OLEDs

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    The search for alternative transparent electrodes to the commonly used indium tin oxide (ITO) in optoelectronic devices has led to solution-based approaches based on inkjet printing. As an additive manufacturing technique that allows drops to be positioned only where necessary, inkjet printing shows reduced waste of starting material compared to other methods such as spin coating. As a result, functional materials can be both coated and structured without the need for masks or lithographic pre-patterning of the substrate. For this contribution, we utilized a particle-free silver ink to produce a transparent electrode by inkjet printing. After printing, the silver ions were reduced to metallic silver by an argon plasma. The process takes place at low temperatures (ca. 40 – 50°C), making it suitable for use with flexible substrates, which are often temperature-sensitive. The printed silver layers show good electrical conductivity and optical transmittance, with a crystalline grain structure being formed and maintained during the metallization process. This structure forms a self-organized nanometer-size grid, whose structure allows light to pass through. Due to its nano-structured property, the haze of the electrode was investigated using a simple experimental setup based on a light source shining through the electrode and analyzing the size of the projected pattern. Such qualitative assessment can be a useful indication of the quality of the electrode and we provide details on how to replicate this setup. The final electrodes were implemented in solution-processed OLEDs, which showed bright luminance and overall low haze compared to ITO-based reference devices.Peer Reviewe

    Bicolour, large area, inkjet-printed metal halide perovskite light emitting diodes†

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    We demonstrate a bicoloured metal halide perovskite (MHP) light emitting diode (LED) fabricated in two sequential inkjet printing steps. By adjusting the printing parameters, we selectively and deliberately redissolve and recrystallize the first printed emissive layer to add a pattern emitting in a different color. The red light emitting features (on a green light emitting background) have a minimum size of 100 μm and originate from iodide-rich domains in a phase-segregated, mixed MHP. This phase forms between the first layer, a bromide-based MHP, which is partially dissolved by printing, and the second layer, an iodide-containing MHP. With an optimised printing process we can retain the active layer integrity and fabricate bicolour, large area MHP-based LEDs with up to 1600 mm2 active area. The two emission peaks at 535 nm and 710 nm are well separated and produce a strong visual contrast.Bundesministerium für Bildung und Forschung 10.13039/501100002347Helmholtz Energy Materials Foundry 10.13039/501100015608Peer Reviewe

    Using Combinatorial Inkjet Printing for Synthesis and Deposition of Metal Halide Perovskites in Wavelength‐Selective Photodetectors

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    Metal halide perovskites have received great attention in recent years, predominantly due to the high performance of perovskite solar cells. The versatility of the material, which allows the tunability of the bandgap, has led to its use in light-emitting diodes, photo, and X-ray detectors, among other optoelectronic device applications. Specifically in photodetectors, the tunability of the bandgap allows fabrication of spectrally selective devices. Utilizing a combinatorial inkjet printing approach, multiple perovskite compositions absorbing at specific wavelengths in a single printing step are fabricated. The drop-on-demand capabilities of inkjet printing enable the deposition of inks in a precise ratio to produce specific perovskite compositions in the printed thin film. By controlling the halide ratio in the compositions, a mixed halide gradient ranging from pure MAPbI3 via MAPbBr3 to MAPbCl3 is produced. The tunability in the absorption onset from 410 to 790 nm is demonstrated, covering the whole visible spectrum, with a precision of 8 nm steps for MAPb(BrxCl1−x)3 compositions. From this range of mixed halide perovskites, photodetectors which show spectral selectivity corresponding to the measured absorption onset are demonstrated, paving the way for use in a printed visible light spectrometer without the need for a dispersion element.Peer Reviewe

    Blue cadmium-free and air-fabricated quantum dot light-emitting diodes

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    The article processing charge was funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – 491192747 and the Open Access Publication Fund of Humboldt-Universität zu Berlin.Quantum dot (QD) materials have found increasing use in display applications because of their high color purity and fluorescence quantum yield, enabling devices with higher brightness and efficiency. However, to access large-area printing and coating methods that are carried out in ambient conditions, it is necessary to, first, move away from toxic cadmium, and second, to target materials that can be air-processed. Herein, we synthesize zinc selenide-based blue QD material and air-fabricate light-emitting diodes (LEDs) and single-carrier devices. The encapsulated devices were also measured under ambient conditions. Multi-shell-structured ZnSeTe/ZnSe/ZnS (core/shell/shell) QDs show pure deep blue/purple fluorescence emission with a high photoluminescence quantum yield of 78%. The blue QD-LED devices are fabricated in a conventional structure with bottom light emission with two electron transport materials (ZnO and ZnMgO). The QD-LED devices with ZnO electron transport layer show a maximum luminance of ∼6200 cd m−2 at 9 V with a turn-on voltage of 3.5 V and current efficacy of 0.38 cd A−1, while with ZnMgO electron transport layer, the devices show a maximum luminance of 3000 cd m−2 at 7 V with a turn-on voltage of 3 V and current efficacy of 0.6 cd A−1. Electron-only and hole-only devices were fabricated to show and confirm the underlying charge transport mechanisms. To our knowledge, these results show for the first-time air-fabricated ZnSe-based QD-LEDs, paving the way for scaling up display applications and moving toward high-performance printed electronics.Peer Reviewe

    Risky choice in the limelight

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    This paper examines how risk behavior in the limelight differs from that in anonymity. In two separate experiments we find that subjects are more risk averse in the limelight. However, risky choices are similarly path dependent in the different treatments. Under both limelight and anonymous laboratory conditions, a simple prospect theory model with a path-dependent reference point provides a better explanation for subjects’ behavior than a flexible specification of expected utility theory. Additionally, our findings suggest that ambiguity aversion depends on being in the limelight, that passive experience has little effect on risk taking, and that reference points are determined by imperfectly updated expectations

    [Comment] Redefine statistical significance

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    The lack of reproducibility of scientific studies has caused growing concern over the credibility of claims of new discoveries based on “statistically significant” findings. There has been much progress toward documenting and addressing several causes of this lack of reproducibility (e.g., multiple testing, P-hacking, publication bias, and under-powered studies). However, we believe that a leading cause of non-reproducibility has not yet been adequately addressed: Statistical standards of evidence for claiming discoveries in many fields of science are simply too low. Associating “statistically significant” findings with P < 0.05 results in a high rate of false positives even in the absence of other experimental, procedural and reporting problems. For fields where the threshold for defining statistical significance is P<0.05, we propose a change to P<0.005. This simple step would immediately improve the reproducibility of scientific research in many fields. Results that would currently be called “significant” but do not meet the new threshold should instead be called “suggestive.” While statisticians have known the relative weakness of using P≈0.05 as a threshold for discovery and the proposal to lower it to 0.005 is not new (1, 2), a critical mass of researchers now endorse this change. We restrict our recommendation to claims of discovery of new effects. We do not address the appropriate threshold for confirmatory or contradictory replications of existing claims. We also do not advocate changes to discovery thresholds in fields that have already adopted more stringent standards (e.g., genomics and high-energy physics research; see Potential Objections below). We also restrict our recommendation to studies that conduct null hypothesis significance tests. We have diverse views about how best to improve reproducibility, and many of us believe that other ways of summarizing the data, such as Bayes factors or other posterior summaries based on clearly articulated model assumptions, are preferable to P-values. However, changing the P-value threshold is simple and might quickly achieve broad acceptance

    Promoting novelty, rigor, and style in energy social science: towards codes of practice for appropriate methods and research design

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    A series of weaknesses in creativity, research design, and quality of writing continue to handicap energy social science. Many studies ask uninteresting research questions, make only marginal contributions, and lack innovative methods or application to theory. Many studies also have no explicit research design, lack rigor, or suffer from mangled structure and poor quality of writing. To help remedy these shortcomings, this Review offers suggestions for how to construct research questions; thoughtfully engage with concepts; state objectives; and appropriately select research methods. Then, the Review offers suggestions for enhancing theoretical, methodological, and empirical novelty. In terms of rigor, codes of practice are presented across seven method categories: experiments, literature reviews, data collection, data analysis, quantitative energy modeling, qualitative analysis, and case studies. We also recommend that researchers beware of hierarchies of evidence utilized in some disciplines, and that researchers place more emphasis on balance and appropriateness in research design. In terms of style, we offer tips regarding macro and microstructure and analysis, as well as coherent writing. Our hope is that this Review will inspire more interesting, robust, multi-method, comparative, interdisciplinary and impactful research that will accelerate the contribution that energy social science can make to both theory and practice

    CMS physics technical design report : Addendum on high density QCD with heavy ions

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