Source of Lake Vostok Cations Constrained with Strontium Isotopes

Lake Vostok is the largest sub-glacial lake in Antarctica. The primary source of our current knowledge regarding the geochemistry and biology of the lake comes from the analysis of refrozen lake water associated with ice core drilling. Several sources of dissolved ions and particulate matter to the lake have been proposed, including materials from the melted glacier ice, the weathering of underlying geological materials, hydrothermal activity and underlying, ancient evaporitic deposits. A sample of Lake Vostok Type 1 accretion ice has been analyzed for its 87Sr/86Sr signature as well as its major cation and anion and Sr concentrations. The strontium isotope ratio of 0.71655 and the Ca/Sr ratio in the sample strongly indicate that the major source of the Sr is from aluminosilicate minerals from the continental crust. These data imply that at least a portion of the other cations in the Type 1 ice also are derived from continental crustal materials and not hydrothermal activity, the melted glacier ice, or evaporitic sources

Incorporation of particulates into accreted ice above subglacial Vostok lake, Antarctica

The nature of microscopic particulates in meteoric and accreted ice from the Vostok (Antarctica) ice core is assessed in conjunction with existing ice-core data to investigate the mechanism by which particulates are incorporated into refrozen lake water. Melted ice samples from a range of icecore depths were filtered through 0.2 μm polycarbonate membranes, and secondary electron images were collected at ×500 magnification using a scanning electron microscope. Image analysis software was used to characterize the size and shape of particulates. Similar distributions of major-axis lengths, surface areas and shape factors (aspect ratio and compactness) for particulates in all accreted ice samples suggest that a single process may be responsible for incorporating the vast majority of particulates for all depths. Calculation of Stokes settling velocities for particulates of various sizes implies that 98% of particulates observed could 'float' to the ice water interface with upward water velocities of 0.0003 m s-1 where they could be incorporated by growing ice crystals, or by rising frazil ice crystals. The presence of particulates that are expected to sink in the water column (2%) and the uneven distribution of particulates in the ice core further implies that periodic perturbations to the lake's circulation, involving increased velocities, may have occurred in the past

The hydrochemistry of subglacial Lake Vostok, Antarctica

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