Application of Anodic Stripping Voltammetry to assess sorption performance of an industrial waste entrapped in alginate beads to remove As(V)

AbstractA solid waste material containing Fe(III) and other metal (hydr)oxides produced in a metal surface treatment industry has been investigated for As(V) removal. In order to facilitate sorbent application, 2% of raw material has been entrapped in calcium alginate gel matrix (2% O-CA).An accurate characterization of the sorption on gel beads was undertaken, considering thermodynamic and kinetic aspects. All experiments were carried out at pH 8, since the maximum As(V) sorption was reached between pH 6 and 9. About isotherms, the best fit was obtained considering the Langmuir model and a capacity of 1.9mg/g was achieved. The kinetic profiles evidenced that a quantitative sorption was obtained within 10h. The 2% O-CA beads were also tested for continuous As(V) removal in a fixed bed column. Experiments were performed at constant flow rate, and varying the inlet As(V) concentration. With a view to design an automatic system for As(V) analysis in the outlet flow, the suitability of applying Anodic Stripping Voltammetry was evaluated: the method resulted appropriated to follow the As(V) content in the outlet solutions of columns with metal inlet concentration <1 mg/L.These results suggested that 2% O-CA beads could be a promising sorbent candidate for As(V) removal

Anomalous scaling and Lee-Yang zeroes in Self-Organized Criticality

We show that the generating functions of avalanche observables in SOC models exhibits a Lee-Yang phenomenon. This establishes a new link between the classical theory of critical phenomena and SOC. A scaling theory of the Lee-Yang zeroes is proposed including finite sampling effects.Comment: 33 pages, 19 figures, submitte

A Model for Ferromagnetic Nanograins with Discrete Electronic States

We propose a simple phenomenological model for an ultrasmall ferromagnetic grain, formulated in terms of the grain's discrete energy levels. We compare the model's predictions with recent measurements of the discrete tunneling spectrum through such a grain. The model can qualitatively account for the observed features if we assume (i) that the anisotropy energy varies among different eigenstates of one grain, and (ii) that nonequilibrium spin accumulation occurs.Comment: 4 pages, 2 figure

Measure representation and multifractal analysis of complete genomes

This paper introduces the notion of measure representation of DNA sequences. Spectral analysis and multifractal analysis are then performed on the measure representations of a large number of complete genomes. The main aim of this paper is to discuss the multifractal property of the measure representation and the classification of bacteria. From the measure representations and the values of the $D_{q}$ spectra and related $C_{q}$ curves, it is concluded that these complete genomes are not random sequences. In fact, spectral analyses performed indicate that these measure representations considered as time series, exhibit strong long-range correlation. For substrings with length K=8, the $D_{q}$ spectra of all organisms studied are multifractal-like and sufficiently smooth for the $C_{q}$ curves to be meaningful. The $C_{q}$ curves of all bacteria resemble a classical phase transition at a critical point. But the 'analogous' phase transitions of chromosomes of non-bacteria organisms are different. Apart from Chromosome 1 of {\it C. elegans}, they exhibit the shape of double-peaked specific heat function.Comment: 12 pages with 9 figures and 1 tabl

Marine Delay and Disruption Tolerant Networks (MaDTN): Application for Artisanal Fisheries

The artisanal fishing activity carried out on the coasts where the production of fish can be exploited is affected by a lack of communication between the vessels in order to provide relevant information related to multiple marine sensor parameters. It is mainly due to the rugged geographic area that causes highly disruptive communication links and in which traditional IP-based communications with transport protocols such as TCP or UDP do not work properly. This paper presents and evaluates a new communications architecture to provide services to marine sensor networks using a disruption tolerant networking (DTN) based solution. We propose a new architecture that takes into account the different vessels densities. We assume a finite sensor population model and a saturated traffic condition where every sensor always has frames to transmit. The performance was evaluated in terms of delivery probabilities, delay and a DTN scenario indicator (DSI) proposed. Through simulations, this paper reveals that Low Density scenery yield greater latency, and more density of nodes has better results. We achieved a successful delivery rate of 74% and a latency of 2 h approximately. Finally indicators shows that high density of nodes is strongly recommended for fishery scenery models

Emergence of quasi-metallic state in disordered 2D electron gas due to strong interactions

The interrelation between disorder and interactions in two dimensional electron liquid is studied beyond weak coupling perturbation theory. Strong repulsion significantly reduces the electronic density of states on the Fermi level. This makes the electron liquid more rigid and strongly suppresses elastic scattering off impurities. As a result the weak localization, although ultimately present at zero temperature and infinite sample size, is unobservable at experimentally accessible temperature at high enough densities. Therefore practically there exists a well defined metallic state. We study diffusion of electrons in this state and find that the diffusion pole is significantly modified due to "mixture" with static photons similar to the Anderson - Higgs mechanism in superconductivity. As a result several effects stemming from the long range nature of diffusion like the Aronov - Altshuler logarithmic corrections to conductivity are less pronounced.Comment: to appear in Phys. Rev.

Search for direct production of charginos and neutralinos in events with three leptons and missing transverse momentum in √s = 7 TeV pp collisions with the ATLAS detector

A search for the direct production of charginos and neutralinos in final states with three electrons or muons and missing transverse momentum is presented. The analysis is based on 4.7 fb−1 of proton–proton collision data delivered by the Large Hadron Collider and recorded with the ATLAS detector. Observations are consistent with Standard Model expectations in three signal regions that are either depleted or enriched in Z-boson decays. Upper limits at 95% confidence level are set in R-parity conserving phenomenological minimal supersymmetric models and in simplified models, significantly extending previous results

Measurement of D*+/- meson production in jets from pp collisions at sqrt(s) = 7 TeV with the ATLAS detector

This paper reports a measurement of D*+/- meson production in jets from proton-proton collisions at a center-of-mass energy of sqrt(s) = 7 TeV at the CERN Large Hadron Collider. The measurement is based on a data sample recorded with the ATLAS detector with an integrated luminosity of 0.30 pb^-1 for jets with transverse momentum between 25 and 70 GeV in the pseudorapidity range |eta| < 2.5. D*+/- mesons found in jets are fully reconstructed in the decay chain: D*+ -> D0pi+, D0 -> K-pi+, and its charge conjugate. The production rate is found to be N(D*+/-)/N(jet) = 0.025 +/- 0.001(stat.) +/- 0.004(syst.) for D*+/- mesons that carry a fraction z of the jet momentum in the range 0.3 < z < 1. Monte Carlo predictions fail to describe the data at small values of z, and this is most marked at low jet transverse momentum.Comment: 10 pages plus author list (22 pages total), 5 figures, 1 table, matches published version in Physical Review

Search for supersymmetry in final states with jets, missing transverse momentum and one isolated lepton in sqrt{s} = 7 TeV pp collisions using 1 fb-1 of ATLAS data

We present an update of a search for supersymmetry in final states containing jets, missing transverse momentum, and one isolated electron or muon, using 1.04 fb^-1 of proton-proton collision data at sqrt{s} = 7 TeV recorded by the ATLAS experiment at the LHC in the first half of 2011. The analysis is carried out in four distinct signal regions with either three or four jets and variations on the (missing) transverse momentum cuts, resulting in optimized limits for various supersymmetry models. No excess above the standard model background expectation is observed. Limits are set on the visible cross-section of new physics within the kinematic requirements of the search. The results are interpreted as limits on the parameters of the minimal supergravity framework, limits on cross-sections of simplified models with specific squark and gluino decay modes, and limits on parameters of a model with bilinear R-parity violation.Comment: 18 pages plus author list (30 pages total), 9 figures, 4 tables, final version to appear in Physical Review

Reducing heterotic M-theory to five dimensional supergravity on a manifold with boundary

This paper constructs the reduction of heterotic $M$-theory in eleven dimensions to a supergravity model on a manifold with boundary in five dimensions using a Calabi-Yau three-fold. New results are presented for the boundary terms in the action and for the boundary conditions on the bulk fields. Some general features of dualisation on a manifold with boundary are used to explain the origin of some topological terms in the action. The effect of gaugino condensation on the fermion boundary conditions leads to a `twist' in the chirality of the gravitino which can provide an uplifting mechanism in the vacuum energy to cancel the cosmological constant after moduli stabilisation.Comment: 16 pages, RevTe