Polymeric Squaraine Dyes as Electron Donors in Bulk Heterojunction Solar Cells

A polysquaraine low band gap polymer was synthesized by Yamamoto coupling of a monomeric dibromo indolenine squaraine dye. The resulting polymer has a weight average molar mass in the order of Mw ~30.000-50.000 and a polydispersity of ca. 1.7 as determined by gel-permeation chromatography (GPC). The electronic properties of monomer and polymer were investigated by cyclic voltammetry, absorption and emission spectroscopy. Owing to exciton coupling the absorption bands of the polymer are red-shifted and strongly broadened compared to the monomer squaraine dye. Bulk heterojunction solar cells were prepared from blends of the polysquaraine with the fullerene derivative [6,6]-phenyl C61-butyric acid methyl ester (PCBM) in different weight ratios (1:3 to 1:1). The power conversion efficiencies under simulated AM 1.5 conditions yielded 0.45 % for these non-optimized systems. The external quantum efficiency (EQE) shows that the photoresponse spans the range from 300 to 850 nm, which illustrates the promising properties of this novel organic semiconductor as a low band gap donor material in organic photovoltaics.Comment: 10 pages, 7 figure

Self-Similar Dynamical Relaxation of Dark Matter Halos in an Expanding Universe

We investigate the structure of cold dark matter halos using advanced models of spherical collapse and accretion in an expanding Universe. These base on solving time-dependent equations for the moments of the phase-space distribution function in the fluid approximation; our approach includes non-radial random motions, and most importantly, an advanced treatment of both dynamical relaxation effects that takes place in the infalling matter: phase-mixing associated to shell crossing, and collective collisions related to physical clumpiness. We find self-similar solutions for the spherically-averaged profiles of mass density rho(r), pseudo phase-space density Q(r) and anisotropy parameter beta(r). These profiles agree with the outcomes of state-of-the-art N-body simulations in the radial range currently probed by the latter; at smaller radii, we provide specific predictions. In the perspective provided by our self-similar solutions we link the halo structure to its two-stage growth history, and propose the following picture. During the early fast collapse of the inner region dominated by a few merging clumps, efficient dynamical relaxation plays a key role in producing a closely universal mass density and pseudo phase-space density profiles; in particular, these are found to depend only weakly on the detailed shape of the initial perturbation and the related collapse times. The subsequent inside-out growth of the outer regions feeds on the slow accretion of many small clumps and diffuse matter; thus the outskirts are only mildly affected by dynamical relaxation but are more sensitive to asymmetries and cosmological variance.Comment: 31 pages, 16 figures. Typos corrected. Accepted by Ap

The role of tool geometry in process damped milling

The complex interaction between machining structural systems and the cutting process results in machining instability, so called chatter. In some milling scenarios, process damping is a useful phenomenon that can be exploited to mitigate chatter and hence improve productivity. In the present study, experiments are performed to evaluate the performance of process damped milling considering different tool geometries (edge radius, rake and relief angles and variable helix/pitch). The results clearly indicate that variable helix/pitch angles most significantly increase process damping performance. Additionally, increased cutting edge radius moderately improves process damping performance, while rake and relief angles have a smaller and closely coupled effect

The joint evolution of baryons and dark matter haloes

We have studied the dark matter (DM) distribution in a approx 10^12 h^-1 M_sun mass halo extracted from a simulation consistent with the concordance cosmology, where the physics regulating the transformation of gas into stars was allowed to change producing galaxies with different morphologies. The presence of baryons produces the concentration of the DM halo with respect to its corresponding dissipationless run, but we found that this response does not only depend on the amount of baryons gathered in the central region but also on the way they have been assembled. DM and baryons affect each other in a complex way so the formation history of a galaxy plays an important role on its final total mass distribution. Supernova (SN) feedback regulates the star formation and triggers galactic outflows not only in the central galaxy but also in its satellites. Our results suggest that, as the effects of SN feedback get stronger, satellites get less massive and can even be more easily disrupted by dynamical friction, transferring less angular momentum. We found indications that this angular momentum could be acquired not only by the outer part of the DM halo but also by the inner ones and by the stellar component in the central galaxy. The latter effect produces stellar migration which contributes to change the inner potential well, probably working against further DM contraction. As a consequence of the action of these processes, when the halo hosts a galaxy with an important disc structure formed by smooth gas accretion, it is more concentrated than when it hosts a spheroidal system which experienced more massive mergers and interactions. (abridged)Comment: 16 pages, 16 figures, accepted to MNRA

Late stage C―H activation of a privileged scaffold; synthesis of a library of benzodiazepines

A library of over twenty 5-(2-arylphenyl)-1,3-dihydro-2H-1,4-benzodiazepin-2-ones has been formed by a microwave-mediated late-stage palladium-catalysed arylation of 1,4-benzodiazepines using diaryliodonium salts. This can also be applied to nordazepam (7-chloro-5-phenyl-1,3-dihydro-2H-1,4-benzodiazepin-2-one), the active metabolite of diazepam, and subsequent N-alkylation and/or H/D exchange allows further diversification towards elaborated pharmaceuticals and their 3,3'-deuterated analogues

Galactic cannibalism and CDM density profiles

Using N-body simulations we show that the process of formation of the brightest cluster galaxy through dissipationless galactic cannibalism can affect the inner cluster dark matter density profile. In particular, we use as realistic test case the dynamical evolution of the galaxy cluster C0337-2522 at redshift z=0.59, hosting in its centre a group of five elliptical galaxies which are likely to be the progenitor of a central giant elliptical. After the formation of the brightest cluster galaxy, the inner cluster dark matter density profile is significantly flatter (logarithmic slope 0.49<beta<0.90) than the original cusp (beta=1), as a consequence of dynamical friction heating of the massive galaxies against the diffuse cluster dark matter. In our simulations we have assumed that the cluster galaxies are made of stars only. We also show that the presence of galactic dark matter haloes can steepen the cluster central density profile. We conclude that galactic cannibalism could be a viable physical mechanism to reconcile - at least at the cluster scale - the flat dark matter haloes inferred observationally in some galaxy clusters with the steep haloes predicted by cosmological simulations.Comment: 6 pages with 3 figures. Version accepted for publication in MNRAS. Longer than first version, with results from additional simulations. Conclusions unchange

The impact of a major cluster merger on galaxy evolution in MACS\,J0025.4-1225

We present results of an extensive morphological, spectroscopic, and photometric study of the galaxy population of MACS J0025.4$-$1225 (z=0.586), a major cluster merger with clear segregation of dark and luminous matter, to examine the impact of mergers on galaxy evolution. Based on 436 galaxy spectra obtained with Keck DEIMOS, we identified 212 cluster members within 4 Mpc of the cluster centre, and classified them using three spectroscopic types; we find 111 absorption-line, 90 emission-line (including 23 e(a) and 11 e(b)), and 6 E+A galaxies. The fraction of absorption(emission)-line galaxies is a monotonically increasing(decreasing) function of both projected galaxy density and radial distance to the cluster center. More importantly, the 6 observed E+A cluster members are all located between the dark-matter peaks of the cluster and within ~0.3Mpc radius of the X-ray flux peak, unlike the E+A galaxies in other intermediate-redshift clusters which are usually found to avoid the core region. In addition, we use Hubble Space Telescope imaging to classify cluster members according to morphological type. We find the global fraction of spiral and lenticular galaxies in MACS J0025 to be among the highest observed to date in clusters at z>0.5. The observed E+A galaxies are found to be of lenticular type with Sersic indices of ~2, boosting the local fraction of S0 to 70 per cent between the dark-matter peaks. Combing the results of our analysis of the spatial distribution, morphology, and spectroscopic features of the galaxy population, we propose that the starburst phase of these E+A galaxies was both initiated and terminated during the first core-passage about 0.5--1Gyr ago, and that their morphology has already been transformed into S0 due to ram pressure and/or tidal forces near the cluster core. By contrast, ongoing starbursts are observed predominantly in infalling galaxies, and thus appears to be unrelated to the cluster merger.Comment: 18 pages, 17 figures, accepted by MNRA

Cosmology Using Cluster Internal Velocity Dispersions

We compare the distribution of internal velocity dispersions of galaxy clusters for an observational sample to those obtained from a set of N-body simulations of seven COBE-normalised cosmological scenarios: the standard CDM (SCDM) and a tilted (n=0.85) CDM (TCDM) model, a CHDM model with 25% of massive neutrinos, two low-density LCDM models with Omega_0=0.3 and 0.5, two open OCDM models with Omega_0=0.4 and 0.6. Simulated clusters are observed in projection so as to reproduce the main observational biases and are analysed by applying the same algorithm for interlopers removal and velocity dispersion estimate as for the reference observational sample. Velocity dispersions for individual clusters can be largely affected by observational biases in a model-dependent way: models in which clusters had less time to virialize show larger discrepancies between 3D and projected velocity dispersions. From the comparison with real clusters we find that both SCDM and TCDM largely overproduce clusters. The CHDM model marginally overproduces clusters and requires a somewhat larger sigma_8 than a purely CDM model in order to produce the same cluster abundance. The LCDM model with Omega_0=0.3 agrees with data, while the open model with Omega_0=0.4 and 0.6 underproduces and marginally overproduces clusters, respectively.Comment: 28 pages, LaTeX uses Elsevier style file, 7 postscript figures (3 bitmapped to lower res.) included. Submitted to New Astronom

An Over-Massive Black Hole in the Compact Lenticular Galaxy NGC1277

All massive galaxies likely have supermassive black holes at their centers, and the masses of the black holes are known to correlate with properties of the host galaxy bulge component. Several explanations have been proposed for the existence of these locally-established empirical relationships; they include the non-causal, statistical process of galaxy-galaxy merging, direct feedback between the black hole and its host galaxy, or galaxy-galaxy merging and the subsequent violent relaxation and dissipation. The empirical scaling relations are thus important for distinguishing between various theoretical models of galaxy evolution, and they further form the basis for all black hole mass measurements at large distances. In particular, observations have shown that the mass of the black hole is typically 0.1% of the stellar bulge mass of the galaxy. The small galaxy NGC4486B currently has the largest published fraction of its mass in a black hole at 11%. Here we report observations of the stellar kinematics of NGC 1277, which is a compact, disky galaxy with a mass of 1.2 x 10^11 Msun. From the data, we determine that the mass of the central black hole is 1.7 x 10^10 Msun, or 59% its bulge mass. Five other compact galaxies have properties similar to NGC 1277 and therefore may also contain over-sized black holes. It is not yet known if these galaxies represent a tail of a distribution, or if disk-dominated galaxies fail to follow the normal black hole mass scaling relations.Comment: 7 pages. 6 figures. Nature. Animation at http://www.mpia.de/~bosch/blackholes.htm

The Galactic Center Black Hole Laboratory

The super-massive 4 million solar mass black hole Sagittarius~A* (SgrA*) shows flare emission from the millimeter to the X-ray domain. A detailed analysis of the infrared light curves allows us to address the accretion phenomenon in a statistical way. The analysis shows that the near-infrared flare amplitudes are dominated by a single state power law, with the low states in SgrA* limited by confusion through the unresolved stellar background. There are several dusty objects in the immediate vicinity of SgrA*. The source G2/DSO is one of them. Its nature is unclear. It may be comparable to similar stellar dusty sources in the region or may consist predominantly of gas and dust. In this case a particularly enhanced accretion activity onto SgrA* may be expected in the near future. Here the interpretation of recent data and ongoing observations are discussed.Comment: 30 pages - 7 figures - accepted for publication by Springer's "Fundamental Theories of Physics" series; summarizing GC contributions of 2 conferences: 'Equations of Motion in Relativistic Gravity' at the Physikzentrum Bad Honnef, Bad Honnef, Germany, (Feb. 17-23, 2013) and the COST MP0905 'The Galactic Center Black Hole Laboratory' Granada, Spain (Nov. 19 - 22, 2013