383 research outputs found
Appareillage automatisé de mesure simultanée du pouvoir thermoélectrique et de la conductivité électrique. Application à l'étude de couches polymères semi-conductrices
Nous présentons dans cet article un système de mesure simultanée de la conductivité σ, et du pouvoir thermoélectrique S : il permet des mesures en fonction de la température (entre 130 K et 360 K) dans le cas de couches semi-conductrices relativement fragiles. A titre d'application, nous indiquons les résultats que nous avons obtenus dans le cas de couches polymères (PPP) implantées avec des ions sodium: alors que seule une semi-conduction par défaut est générée par de fortes énergies d'implantation (E = 250 keV ), il apparaît une semiconduction induite par le dopage n lors d'implantations à basse énergie (E = 30 keV )
Transport mechanisms in 8-tris-hydroxyquinoline aluminium (Alq3) electronic layers: a study by photodipolar absorption
International audienceThis paper describes the role of traps in the electronic conductivity of 8-tris-hydroxyquinoline aluminium in a conventional sandwich structure with indium tin oxide and aluminium electrodes. New results obtained by photodipolar absorption techniques and impedance spectroscopy are presented. The former method acts as a probe to highlight the role of traps. It is shown that optical pumping of electrons to trap levels gives a clear increase in dielectric absorption due to the reorientation of dipoles associated with trapped charges. The trap depth is estimated to be around Et= 0.19 eV, a value in good agreement with theoretical calculations and thermoluminescence measurements. The latter method permits a representation of the sample in terms of a circuit composed of a parallel capacitor (Cp) and resistor (Rp) both in series with a resistor Rs≈ 50 Ωlocated on the anode side. A logarithmic plot of Rp as a function of the dc bias voltage gives a linear law that is recognized, for the first time, to be a consequence of a trapped charge limited (TCL) current. The linearity can be improved by the introduction of a field-dependent mobility
Up-conversion injection in Rubrene/Perylene-diimide-heterostructure electroluminescent diodes
We implement and demonstrate a scheme that permits to drive
electroluminescence with an extremely low turn-on voltage. The device behaves
like compound semiconductors, in which the electroluminescence turn-on voltage
is about the same as the open circuit voltage for the photovoltaic effect.
However, the electroluminescence turn-on voltage is about half of the band gap
of the emitting material, that cannot be explained using current models of
charge injection in organic semiconductors. We hereby propose explanation
through an Auger-type two-step injection mechanism (Auger-fountain).Comment: we report the first evidence of an Auger-fountain electroluminescence
in a semiconductor heterojunctio
Etude par microanalyse ionique de films de poly(paraphénylène) et des phénomènes induits par implantation ionique
L'étude par microanalyse ionique de films de polyparaphénylène nous a permis de mettre en évidence la présence d'atomes d'azote et d'oxygène ; à partir de l'implantation préliminaire d'isotopes 15N et 18O nous avons pu évaluer les concentrations atomiques en azote et oxygène qui sont respectivement inférieures à 1 % et de l'ordre de 4 %. Ces atomes d'impuretés sont localisés dans une zone de défauts, située à l'arrière de la couche implantée et dont l'importance croît avec la valeur des paramètres d'implantation
High Temperature Thermopower in La_{2/3}Ca_{1/3}MnO_3 Films: Evidence for Polaronic Transport
Thermoelectric power, electrical resistivity and magnetization experiments,
performed in the paramagnetic phase of La_{2/3}Ca_{1/3}MnO_3, provide evidence
for polaron-dominated conduction in CMR materials. At high temperatures, a
large, nearly field-independent difference between the activation energies for
resistivity (rho) and thermopower (S), a characteristic of Holstein Polarons,
is observed, and ln(rho) ceases to scale with the magnetization. On approaching
T_c, both energies become field-dependent, indicating that the polarons are
magnetically polarized. Below T_c, the thermopower follows a law S(H) prop.
1/rho (H) as in non saturated ferromagnetic metals.Comment: 10 pages, 5 .gif figures. Phys. Rev B (in press
Recent advances in solid-state organic lasers
Organic solid-state lasers are reviewed, with a special emphasis on works
published during the last decade. Referring originally to dyes in solid-state
polymeric matrices, organic lasers also include the rich family of organic
semiconductors, paced by the rapid development of organic light emitting
diodes. Organic lasers are broadly tunable coherent sources are potentially
compact, convenient and manufactured at low-costs. In this review, we describe
the basic photophysics of the materials used as gain media in organic lasers
with a specific look at the distinctive feature of dyes and semiconductors. We
also outline the laser architectures used in state-of-the-art organic lasers
and the performances of these devices with regard to output power, lifetime,
and beam quality. A survey of the recent trends in the field is given,
highlighting the latest developments in terms of wavelength coverage,
wavelength agility, efficiency and compactness, or towards integrated low-cost
sources, with a special focus on the great challenges remaining for achieving
direct electrical pumping. Finally, we discuss the very recent demonstration of
new kinds of organic lasers based on polaritons or surface plasmons, which open
new and very promising routes in the field of organic nanophotonics
Acetylene-Based Materials in Organic Photovoltaics
Fossil fuel alternatives, such as solar energy, are moving to the forefront in a variety of research fields. Organic photovoltaic systems hold the promise of a lightweight, flexible, cost-effective solar energy conversion platform, which could benefit from simple solution-processing of the active layer. The discovery of semiconductive polyacetylene by Heeger et al. in the late 1970s was a milestone towards the use of organic materials in electronics; the development of efficient protocols for the palladium catalyzed alkynylation reactions and the new conception of steric and conformational advantages of acetylenes have been recently focused the attention on conjugated triple-bond containing systems as a promising class of semiconductors for OPVs applications. We review here the most important and representative (poly)arylacetylenes that have been used in the field. A general introduction to (poly)arylacetylenes, and the most common synthetic approaches directed toward making these materials will be firstly given. After a brief discussion on working principles and critical parameters of OPVs, we will focus on molecular arylacetylenes, (co)polymers containing triple bonds, and metallopolyyne polymers as p-type semiconductor materials. The last section will deal with hybrids in which oligomeric/polymeric structures incorporating acetylenic linkages such as phenylene ethynylenes have been attached onto C60, and their use as the active materials in photovoltaic devices
ZnO anchored graphene hydrophobic nanocomposite-based bulk heterojunction solar cells showing enhanced short-circuit current
Hydrophobic and surfactant-free ZnO nanoparticles and ZnO decorated graphene nanocomposite (Z@G) with narrow and uniform size distribution were synthesized by a time-efficient microwave-assisted hydrothermal reaction that can be used specifically for application in hybrid photovoltaics. The synthesized ZnO nanoparticles and Z@G nanocomposite showed stable and clear dispersion in chloroform and methanol (with volume ratio of 9 : 1) and chloroform and ethanol (volume ratio 9 : 1). Being hydrophobic, these inorganic samples blend very well with organic polymer solution in chlorobenzene, which is a prerequisite to cast smooth and undisrupted film for hybrid solar cell application. The introduction of these hydrophobic nanoparticles into PCPDTBT: PCBM-based bulk-heterojunction polymer solar cells resulted in significant improvement in solar cell J-V characteristics with enhancement in open circuit voltage (VOC), short circuit current density (JSC) and thereby overall improvement in cell efficiency. With the optimization of the weight ratio of polymer, fullerene and synthesized ZnO nanoparticles/Z@G nanocomposite, the power conversion efficiencies 1.76% and 3.65% were achieved
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