Asiago eclipsing binaries program. I. V432 Aur

The orbit and physical parameters of the previously unsolved eclipsing binary V432 Aur, discovered by Hipparcos, have been derived with errors better than 1% from extensive Echelle spectroscopy and B, V photometry. Synthetic spectral analysis of both components has been performed, yielding T_eff and log g in close agreement with the orbital solution, a metallicity [Z/Z_sun]=-0.60 and rotational synchronization for both components. Direct comparison on the theoretical L, T_eff plane with the Padova evolutionary tracks and isochrones for the masses of the two components (1.22 and 1.08 M_sun) provides a perfect match and a 3.75 Gyr age. The more massive and cooler component is approaching the base of the giant branch and displays a probable pulsation activity with an amplitude of Delta V = 0.075 mag and Delta rad.vel. = 1.5 km/sec. With a T_eff = 6080 K it falls to the red of the nearby instability strip populated by delta Sct and gamma Dor types of pulsating variables. Orbital modeling reveals a large and bright surface spot on it. The pulsations activity and the large spot(s) suggest the presence of macro-turbulent motions in its atmosphere. They reflect in a line broadening that at cursory inspection could be taken as indication of a rotation faster than synchronization, something obviously odd for an old, expanding star.Comment: A&A, 11 pages, accepted Jan 7, 200

<i>Gaia</i> Data Release 1. Summary of the astrometric, photometric, and survey properties

Context. At about 1000 days after the launch of Gaia we present the first Gaia data release, Gaia DR1, consisting of astrometry and photometry for over 1 billion sources brighter than magnitude 20.7. Aims. A summary of Gaia DR1 is presented along with illustrations of the scientific quality of the data, followed by a discussion of the limitations due to the preliminary nature of this release. Methods. The raw data collected by Gaia during the first 14 months of the mission have been processed by the Gaia Data Processing and Analysis Consortium (DPAC) and turned into an astrometric and photometric catalogue. Results. Gaia DR1 consists of three components: a primary astrometric data set which contains the positions, parallaxes, and mean proper motions for about 2 million of the brightest stars in common with the HIPPARCOS and Tycho-2 catalogues – a realisation of the Tycho-Gaia Astrometric Solution (TGAS) – and a secondary astrometric data set containing the positions for an additional 1.1 billion sources. The second component is the photometric data set, consisting of mean G-band magnitudes for all sources. The G-band light curves and the characteristics of ∼3000 Cepheid and RR-Lyrae stars, observed at high cadence around the south ecliptic pole, form the third component. For the primary astrometric data set the typical uncertainty is about 0.3 mas for the positions and parallaxes, and about 1 mas yr−1 for the proper motions. A systematic component of ∼0.3 mas should be added to the parallax uncertainties. For the subset of ∼94 000 HIPPARCOS stars in the primary data set, the proper motions are much more precise at about 0.06 mas yr−1. For the secondary astrometric data set, the typical uncertainty of the positions is ∼10 mas. The median uncertainties on the mean G-band magnitudes range from the mmag level to ∼0.03 mag over the magnitude range 5 to 20.7. Conclusions. Gaia DR1 is an important milestone ahead of the next Gaia data release, which will feature five-parameter astrometry for all sources. Extensive validation shows that Gaia DR1 represents a major advance in the mapping of the heavens and the availability of basic stellar data that underpin observational astrophysics. Nevertheless, the very preliminary nature of this first Gaia data release does lead to a number of important limitations to the data quality which should be carefully considered before drawing conclusions from the data

Photodegradation of Pollutants in Air: Enhanced Properties of Nano-TiO2Prepared by Ultrasound

Nanocrystalline TiO2samples were prepared by promoting the growth of a sol–gel precursor, in the presence of water, under continuous (CW), or pulsed (PW) ultrasound. All the samples turned out to be made of both anatase and brookite polymorphs. Pulsed US treatments determine an increase in the sample surface area and a decrease of the crystallite size, that is also accompanied by a more ordered crystalline structure and the samples appear to be more regular and can be considered to contain a relatively low concentration of lattice defects. These features result in a lower recombination rate between electrons and holes and, therefore, in a good photocatalytic performance toward the degradation of NOxin air. The continuous mode induces, instead, the formation of surface defects (two components are present in XPS Ti 2p3/2region) and consequently yields the best photocatalyst. The analysis of all the characterization data seems to suggest that the relevant parameter imposing the final features of the oxides is the ultrasound total energypervolume (Etot/V) and not the acoustic intensity or the pulsed/continuous mode

On the distance, reddening and progenitor of V838 Mon

Extensive optical and infrared photometry as well as low and high resolution spectroscopy are used as inputs in deriving robust estimates of the reddening, distance and nature of the progenitor of V838 Mon. The reddening is found to obey the R_V=3.1 law and amounts to (i) E(B-V)=0.86 from the interstellar NaI and KI lines, (ii) E(B-V)=0.88 from the energy distribution of the B3V component and (iii) E(B-V)=0.87 from the progression of extinction along the line of sight. The adopted E(B-V)=0.87(+/-0.01) is also the amount required by fitting the progenitor with theoretical isochrones of appropriate metallicity. The distance is estimated from (a) the galactic kinematics of the three components of the interstellar lines, (b) the amount of extinction vs the HI column density and vs the dust emission through the whole Galaxy in that direction, from (c) spectrophotometric parallax to the B3V companion, from (d) comparison of the observed color-magnitude diagram of field stars with 3D stellar population models of the Galaxy, from (e) comparison of theoretical isochrones with the components of the binary system in quiescence and found to be around 10 kpc. Pre-outburst optical and IR energy distributions show that the component erupting in 2002 was brighter and hotter than the B3V companion. The best fit is obtained for a 50,000 K source, 0.5 mag brighter than the B3V companion. Comparison with theoretical isochrones suggests an age of 4 million year for the system and a mass around 65 M(sun) for the progenitor of the outbursting component, which at the time of the outburst was approaching the Carbon ignition stage in its core. The 2002 event is probably just a shell thermonuclear event in the outer envelope of the star.Comment: in press in A&

Regioisomeric and substituent effects upon the outcome of the reaction of 1-borodienes with nitrosoarene compounds

A study of the reactivity of 1-borodienes with nitrosoarene compounds has been carried out showing an outcome that differs according to the hybridization state of the boron moiety. Using an sp2 boron substituent, a one-pot hetero-Diels–Alder/ring contraction cascade occurred to afford N-arylpyrroles with low to good yields depending on the electronic properties of the substituents on the borodiene, whereas an sp3 boron substituent led to the formation of stable boro-oxazines with high regioselectivity in most of the cases, in moderate to good yields. 1H and 11B NMR studies on two boro-oxazine regioisomers showed that selective deprotection can be performed. Formation of either the pyrrole or the furan derivative is pH- and regioisomer-structure-dependent. The results obtained, together with previous B3LYP calculations, support mechanistic proposals which suggest that pyrrole, or furan, formation proceeds via oxazine formation, followed by a boryl rearrangement and an intramolecular addition–elimination sequence

Gaia Data Release 3: Processing and validation of BP/RP low-resolution spectral data

(Abridged) Blue (BP) and Red (RP) Photometer low-resolution spectral data is one of the exciting new products in Gaia Data Release 3 (Gaia DR3). We calibrate about 65 billion individual transit spectra onto the same mean BP/RP instrument through a series of calibration steps, including background subtraction, calibration of the CCD geometry and an iterative procedure for the calibration of CCD efficiency as well as variations of the line-spread function and dispersion across the focal plane and in time. The calibrated transit spectra are then combined for each source in terms of an expansion into continuous basis functions. Time-averaged mean spectra covering the optical to near-infrared wavelength range [330, 1050] nm are published for approximately 220 million objects. Most of these are brighter than G = 17.65 but some BP/RP spectra are published for sources down to G = 21.43. Their signal- to-noise ratio varies significantly over the wavelength range covered and with magnitude and colour of the observed objects, with sources around G = 15 having S/N above 100 in some wavelength ranges. The top-quality BP/RP spectra are achieved for sources with magnitudes 9 < G < 12, having S/N reaching 1000 in the central part of the RP wavelength range. Scientific validation suggests that the internal calibration was generally successful. However, there is some evidence for imperfect calibrations at the bright end G < 11, where calibrated BP/RP spectra can exhibit systematic flux variations that exceed their estimated flux uncertainties. We also report that due to long-range noise correlations, BP/RP spectra can exhibit wiggles when sampled in pseudo-wavelength.Comment: Submitted to A&

Gaia data release 1, the photometric data

CONTEXT. This paper presents an overview of the photometric data that are part of the first Gaia data release. AIMS. The principles of the processing and the main characteristics of the Gaia photometric data are presented. METHODS. The calibration strategy is outlined briefly and the main properties of the resulting photometry are presented. RESULTS. Relations with other broadband photometric systems are provided. The overall precision for the Gaia photometry is shown to be at the milli-magnitude level and has a clear potential to improve further in future releases