Constitutive Equations and Processing Maps for 49MnVS3 Non-Quenched and Tempered Steel

Flow stress variations of 49MnVS3 non-quenched and tempered steel are studied in isothermal compression tests on a Gleeble-1500D thermal simulated test machine at a deformation temperatures of 950, 1000, 1150, and 1200° C, and strain rates of 0.1, 1, 5, and 10 s⁻¹, with obtaining the strain hardening exponent n and deformation activation energy Q of the alloy. Thus, the constitutive equations and processing maps of compression flow behavior for 49MnVS3 non-quenched and tempered steel at high temperatures are established. It shows that the peak stress is shownto significantly reduced with a decrease in the strain rate and increase in deformation temperature when the alloy deforms at high temperature, and the deformation activation energy is 350.98 kJ/mol. When the true strain of 49MnVS3 non-quenched and microalloyed steel high-temperature deformation is 0.5, the optimum process parameters of the alloy are determined to be 1150–1200° C for the deformation temperature and 2–10 s⁻¹ for the strain rate, based on the criterion that the process parameters of higher power dissipation efficiency values should be chosen in the dynamic recrystallization region as the best processing technology.Изменение напряжения течения незакаленной и закаленной стали 49MnVS3 исследовали путем проведения испытаний на изотермическое сжатие на установке Gleeble-1500D, моделирующей высокотемпературные условия, при температурах деформации 950, 1000, 1150, 1200° C и скоростях деформации 0,1; 1; 5 и 10 c⁻¹ с показателем степени деформационного упрочнения n и значением энергии активации деформации сплава Q. Установлены определяющие уравнения и схемы обработки компрессионного режима течения для незакаленной и закаленной стали 49MnVS3 при высокой температуре. Анализ уравнений показал, что максимальное значение напряжения значительно уменьшается при снижении скорости деформации и повышении температуры деформации, если сплав подвергается деформации при высокой температуре, а значение энергии активации деформации составляет 350,98 кДж/моль. Если значения истинной деформации незакаленной стали 49MnVS3 и высокотемпературной деформации микролегированной стали составляют 0,5, то оптимальные параметры процесса обработки сплава определяются при температуре деформирования 1150…1200° C и скорости деформации 2…10 c⁻¹ на основе критерия, который способствует отбору параметров с более высокой эффективностью рассеивания мощности в области динамической рекристаллизации в качестве оптимальной технологии обработки.Зміну напруження течії незагартованої і загартованої сталі 49MnVS3 досліджували шляхом проведення випробувань на ізотермічний стиск на установці Gleeble-1500D, що моделює високотемпературні умови, за температур деформації 950, 1000, 1150, 1200° C та швидкості деформації 0,1; 1; 5 і 10 c⁻¹ із показником степеня деформаційного зміцнення n і значенням енергії активації деформації сплаву Q. Установлено визначальні рівняння і схеми обробки компресійного режиму течії для незагартованої і загартованої сталі 49MnVS3 за високої температури. Аналіз рівнянь показав, що максимальне значення напруження значно зменшується зі зниженням швидкості деформації і підвищенні температури деформації, якщо сплав зазнає деформації за високої температури, а значення енергії активації деформації дорівнює 350,98 кДж/моль. Якщо значення істинної деформації незагартованої сталі 49MnVS3 і високотемпературної деформації мікролегованої сталі дорівнюють 0,5, то оптимальні параметри процесу обробки сплаву визначаються за температури деформування 1150...1200° C і швидкості деформації 2...10 c⁻¹ на основі критерію, який сприяє відбору параметрів із більш високою ефективністю розсіяння потужності в області динамічної рекристалізації як оптимальної технології обробки

Further investigations of linear trirhodium complexes: experimental and theoretical studies of Rh-3(dpa)(4)Cl-2 and Rh-3(dpa)(4)Cl-2 (BF4) dpa = bis(2-pyridyl)amido anion

The linear trirhodium compound, Rh-3(dpa)(4)Cl-2 (1), and its one-electron oxidation product, [Rh-3(dpa)(4)Cl-2]BF4 (2), have been synthesized and studied extensively. The magnetic measurement for compound 1 shows that it possesses one unpaired electron that is assigned to occupy the sigma(nb) orbital ((2)A(2)) by DFT calculations. Upon oxidation, a beta-spin electron of 1 is removed, that causes compound 2 to exhibit a triplet ground state. DFT calculations indicate that the two unpaired electrons of 2 occupy sigma(nb) and delta* orbitals (B-3(1)), which is supported by H-1 NMR spectrum. Unlike their isoelectronic analogues [Co-3(dpa)(4)Cl-2] (3) and [Co-3(dpa)(4)(Cl)(2)]BF4 (4), both compound 1 and 2 do not display the spin-crossover phenomenon. The reason may be attributed to the relative large energy gap between B-3(1) and open-shell singlet B-1(1) states

Triaxial projected shell model study of chiral rotation in odd-odd nuclei

Chiral rotation observed in $^{128}$Cs is studied using the newly developed microscopic triaxial projected shell model (TPSM) approach. The observed energy levels and the electromagnetic transition probabilities of the nearly degenerate chiral dipole bands in this isotope are well reproduced by the present model. This demonstrates the broad applicability of the TPSM approach, based on a schematic interaction and angular-momentum projection technique, to explain a variety of low- and high-spin phenomena in triaxial rotating nuclei.Comment: 14 pages, 4 figures, 1 Tabl

Manipulation of electronic structure via supporting ligands: a charge disproportionate model within the linear metal framework of asymmetric nickel string Ni-7(phdptrany)(4)Cl (PF6)

This paper describes the synthesis and physical properties of an uniquely asymmetric heptanickel string complex exhibiting a charge disproportionate model along the linear nickel framework

The improvement of Pd nanoclusters electro-catalytic properties for FAO by the addition of Co element

Conference Name:2014 International Conference on Materials Science and Engineering Technology, MSET 2014. Conference Address: Shanghai, China. Time:June 28, 2014 - June 29, 2014.East China University of Science and Technology; Engineering and Industry Technology Institute; Shanghai JiaoTong University; Shanghai University of Engineering ScienceNear-monodisperse Pd and PdCo nanoclusters were synthesized by physical vapor deposition using a plasma-gas-condensation cluster deposition system and tested for catalyzing formic acid oxidation. Under the condition of high vacuum and inert gas, NCs with clean surface and uniform size were obtained. The cyclic voltammetry tests revealed that the electrochemical surface area was increased from 49.7 m2 g-1 to 51.7 m2 g-1 and the peak current density of catalyzing FAO was raised from 0.115 mA cm-2 to 0.125 mA cm-2 when about 12wt. % Co element was added. Additionally, the tolerance to CO poisoning of Pd could also be improved by the addition of Co. The result indicated that this method offered a chemical-free way to prepare clean and efficient Pd-based nanoscale catalytics and encouraged deeper exploration for electrochemichal catalytic reactions. ? (2014) Trans Tech Publications, Switzerland

Search for direct production of charginos and neutralinos in events with three leptons and missing transverse momentum in √s = 7 TeV pp collisions with the ATLAS detector

A search for the direct production of charginos and neutralinos in final states with three electrons or muons and missing transverse momentum is presented. The analysis is based on 4.7 fb−1 of proton–proton collision data delivered by the Large Hadron Collider and recorded with the ATLAS detector. Observations are consistent with Standard Model expectations in three signal regions that are either depleted or enriched in Z-boson decays. Upper limits at 95% confidence level are set in R-parity conserving phenomenological minimal supersymmetric models and in simplified models, significantly extending previous results

Jet size dependence of single jet suppression in lead-lead collisions at sqrt(s(NN)) = 2.76 TeV with the ATLAS detector at the LHC

Measurements of inclusive jet suppression in heavy ion collisions at the LHC provide direct sensitivity to the physics of jet quenching. In a sample of lead-lead collisions at sqrt(s) = 2.76 TeV corresponding to an integrated luminosity of approximately 7 inverse microbarns, ATLAS has measured jets with a calorimeter over the pseudorapidity interval |eta| < 2.1 and over the transverse momentum range 38 < pT < 210 GeV. Jets were reconstructed using the anti-kt algorithm with values for the distance parameter that determines the nominal jet radius of R = 0.2, 0.3, 0.4 and 0.5. The centrality dependence of the jet yield is characterized by the jet "central-to-peripheral ratio," Rcp. Jet production is found to be suppressed by approximately a factor of two in the 10% most central collisions relative to peripheral collisions. Rcp varies smoothly with centrality as characterized by the number of participating nucleons. The observed suppression is only weakly dependent on jet radius and transverse momentum. These results provide the first direct measurement of inclusive jet suppression in heavy ion collisions and complement previous measurements of dijet transverse energy imbalance at the LHC.Comment: 15 pages plus author list (30 pages total), 8 figures, 2 tables, submitted to Physics Letters B. All figures including auxiliary figures are available at http://atlas.web.cern.ch/Atlas/GROUPS/PHYSICS/PAPERS/HION-2011-02