Steroid estrogens in primary and tertiary wastewater treatment plants

The concentrations of two natural estrogens (Estrone (E1) and Estradiol (E2)) and one synthetic progestin (Ethinylestradiol (EE2)) were measured for different unit operations in an advanced sewage treatment plant and in a large coastal enhanced primary sewage treatment plant. The average influent concentration to both plants was similar – 55 and 53 ng/L for E1 and 22 and 12 ng/L for E2 for the advanced and enhanced primary STPs, respectively. The activated sludge process at the advanced STP removed up to 85% and 96% of E1 and E2, respectively. The enhanced primary sewage treatment plant was mostly ineffective at removing the steroids with only 14% of E1 and 5% of E2 being removed during the treatment process. EE2 was not been detected during the study period in the influent or effluent of either STP. The difference in the observed removal between the two plants is primarily linked to plant performance but the extent to which removal of steroid estrogens is due to bacterial metabolism (i.e. the advanced STP) rather than adsorption to the bacterial biomass remains unclear. The poor removal observed for the coastal enhanced primary STP may have implications for the receiving environment in terms of a greater potential for abnormal reproductive systems in marine animals, particularly if discharges are into large bays or harbours where flushing is limited

Quantifying CO2 leak rates in aquatic environments

The Daylesford region of Victoria (Australia), is a region of natural CO2 seepage. Small bubble streams of CO2 are released into ephemeral river beds proximal to mineral springs that contain high dissolved CO2 content. We study four sites of CO2 degassing to (i) establish the characteristics of CO2 seepage caused by transport to surface of CO2-rich water, (ii) provide an estimate of CO2 flux in the region, and (iii) investigate seasonal effects on CO2 seepage. We observe that bubbling behavior varies considerably between sites, including the number and distribution of bubbling points, and bubble stream the continuity. Total CO2 seep rates at each site were low (< 20 kg/d) but varied substantially between different sites. There were no obvious indicators of total emission rate; the bubble density or other characteristics at the highest emission seep were not remarkably different to the smaller seeps. We find that the total CO2 emission varies inconsistently with season, with some seep rates increasing and other decreasing in the dry season when water levels are lower. We find there are challenges in quantifying the total gas leakage at sites of highly localized and intermittent degassing. Our work has implications for detecting and quantifying leaks from engineered CO2 storage sites which emerge in aqueous environments, which could be these are marine or terrestrial (lakes or rivers)

Fate of Steroid Estrogens in Australian Inland and Coastal Wastewater Treatment Plants

A comparison of estrone (E1), 17b-estradiol (E2) and 17a-ethinylestradiol (EE2) removal at a coastal enhanced primary and inland advanced sewage treatment plant (STP) is reported. The average concentration of estrogens in the raw sewage is similar to reports in other studies. The sequential batch reactor at the advanced STP removed on average 85% of the incoming E1 and 96% of the E2. Further removal was observed during later microfiltration with the estrogen concentration below detection (<0.1 ng.L-1) after reverse osmosis. Some 6% of the influent E1+E2 was removed in the waste activated sludge. The detection of EE2 in the waste activated sludge (0.42 ng.g-1 solids dry weight), undetectable in the raw sewage, suggests that EE2 is resistant to biological treatment in the sequential batch reactor and is primarily removed due to sorption. Little estrogen removal was observed at the enhanced primary with only 7% of E1 and 0% of E2 removed. Low removal is expected based on the degree of estrogens partitioning in the organic fraction given the relatively low solids concentration, but surprisingly, some 43% of E2, 24% of E1 and 100% of EE2 remains associated with the solids fraction in the treated effluent. Further research is necessary to determine whether the low level of estrogen removal for the coastal treatment plant will adversely affect the receiving marine environment

Evaluating the Economic Potential for Geological Hydrogen Storage in Australia

Australia has ambitions to become a major global hydrogen producer by 2030. The establishment of Australia’s and the world’s hydrogen economy, however, will depend upon the availability of affordable and reliable hydrogen storage. Geological hydrogen storage is a practical solution for large scale storage requirements ensuring hydrogen supply can always meet demand, and excess renewable electricity can be stored for later use, improving electricity network reliability. Hosting thick, underground halite (salt) deposits and an abundance of onshore depleted gas fields, Australia is well placed to take advantage of geological hydrogen storage options to support its ambition of building a global hydrogen hub export industry. Using the Bluecap modelling software, we identify regions in Australia that are potentially profitable for large scale hydrogen production and storage. We use the results of this work to suggest high-potential regions for hydrogen development, supporting policymaker and investor decisions on the locations of new infrastructure and hydrogen projects in Australia

Could faults provide conduits for fluid escape? New field data in the vicinity of the Otway International Test Centre

Introduction It is well known that faults affect fluid movement within the subsurface and this can have a host of implications for the measurement, monitoring, and verification of subsurface technologies (e.g., carbon capture and storage (CCS), energy storage, geothermal energy, and radioactive waste disposal). Faults are an important control on the escape of fluids from depth (e.g., Dockrill and Shipton, 2010). It is therefore important to consider the potential effect of faults in the shallow overburden to any future CCS sites. However, there is very little data on fault architecture in shallow sediments, and consequently their effect on fluid flow is far less well understood than flow through faults at hydrocarbon reservoir depths. In early 2024, a novel field trial injection will be conducted at the CO2CRC Otway International Test Centre (OITC), located in southern Victoria, Australia (Figure 1). The injection will involve a small volume of CO2 (~10 t) being injected into the Brumbys Fault, which will be monitored using various surface and downhole monitoring techniques (Tenthorey et al., 2022), to provide data on the transport of CO2 through shallow faults. The 1.2km long Brumbys Fault is hosted in the Miocene Port Campbell Limestone (PCL) carbonate sequence that outcrops across southern Victoria, with varying thickness from ~30m to 270m (Radke et al., 2022). Brumbys Fault has been interpreted as a strike-slip fault, due to its near-vertical dip (~80°), small throw (2-4m), and favorable orientation to the present-day stress (~30° from the maximum horizontal stress) (Feitz et al., 2018). However, there are no convincing surface markers indicating horizontal displacement. To reduce the uncertainty regarding the fault kinematics, we attempt to reconcile the styles of faulting observed in nearby field exposures with the observations made at the OITC boreholes. Method The Port Campbell Limestone is exposed in coastal cliffs, from Childers Cove in the west (38.489101, 142.672736) to Gibson Beach in the east (-38.674070, 143.117769) and inland in Kurdeez quarry (Figure 1). Access to the cliff faces is limited due to the lack of access points and tides, precluding the collection of detailed field data therefore most field observations were made from adjacent cliffs and tourist lookout spots where available. Results Reverse faulting (1-2m throw) was observed along coastal outcrops (Figure 2) in the eastern portion of field area: outcrops examined west of Port Campbell did not exhibit any faulting. Reverse features had a strike ~50-60°, which is consistent with the maximum horizontal stress direction (~142°). There is some evidence of large vertical fractures (10s m vertical extent) that could be associated with strike slip movement, but horizontal offset could not be seen in cliff and quarry outcrops due to limitations is 3D accessibility of features. These features had a strike of either ~105-110° or ~170-175°. Smaller, more localized vertical and sub-vertical fractures striking ~175° are confined to individual layers within the PCL, highlighting the variation in mechanical properties within different sections of the PCL sequence. At Kurdeez quarry, the PCL is significantly less consolidated compared to the coastal outcrops, which is similar to the rock core retrieved from the Brumbys-1, 2 and 3 wells. Spatial variations in diagenetic or depositional history have influenced the mechanical properties of the PCL and may in turn have influenced the fault formation. Conclusions There is a spatial variation in the location and type of faulting in the study area: eastern coastal areas host reverse faulting, whereas western coastal areas and inland areas lack evidence of reverse faulting and are unconsolidated. The PCL is much thicker to the west and north (where it reaches its maximum thickness of ~270m thick), which may explain this spatial variation in deformation style. Further work on the interpretation and characterisation of Brumbys Fault will be necessary before any injection experiment to ensure the fault geometry and fluid flow implications are fully understood

Structural controls on the location and distribution of CO2 emission at a natural CO2 spring in Daylesford, Australia

Secure storage of CO2 is imperative for carbon capture and storage technology, and relies on a thorough understanding of the mechanisms of CO2 retention and leakage. Observations at CO2 seeps around the world find that geological structures at a local and regional scale control the location, distribution and style of CO2 emission. Bedrock-hosted natural CO2 seepage is found in the Daylesford region in Victoria, Australia, where many natural springs contain high concentrations of dissolved CO2. Within a few meters of the natural Tipperary Mineral Spring, small CO2 bubble streams are emitted from bedrock into an ephemeral creek. We examine the relationship between structures in the exposed adjacent outcropping rocks and characteristics of CO2 gas leakage in the stream, including CO2 flux and the distribution of gas emissions. We find that degassing is clustered within ~1 m of a shale-sandstone geological contact. CO2 emission points are localised along bedding and fracture planes, and concentrated where these features intersect. The bubble streams were intermittent, which posed difficulties in quantifying total emitted CO2. Counterintuitively, the number of bubble streams and CO2 flux was greatest from shale dominated rather than the sandstone dominated features, which forms the regional aquifer. Shallow processes must be increasing the shale permeability, thus influencing the CO2 flow pathway and emission locations. CO2 seepage is not limited to the pool; leakage was detected in subaerial rock exposures, at the intersection of bedding and orthogonal fractures. These insights show the range of spatial scales of the geological features that control CO2 flow. Microscale features and near surface processes can have significant effect on the style and location and rates of CO2 leakage. The intermittency of the bubble streams highlights challenges around characterising and monitoring CO2 stores where seepage is spatially and temporally variable. CCS monitoring programmes must therefore be informed by understanding of shallow crustal processes and not simply the processes and pathways governing CO2 fluid flow at depth. Understanding how the CO2 fluids leaked by deep pathways might be affected by shallow processes will inform the design of appropriate monitoring tools and monitoring locations

Looking for leakage or monitoring for public assurance?

Monitoring is a regulatory requirement for all carbon dioxide capture and geological storage (CCS) projects to verify containment of injected carbon dioxide (CO2) within a licensed geological storage complex. Carbon markets require CO2 storage to be verified. The public wants assurances CCS projects will not cause any harm to themselves, the environment or other natural resources. In the unlikely event that CO2 leaks from a storage complex, and into groundwater, to the surface, atmosphere or ocean, then monitoring methods will be required to locate, assess and quantify the leak, and to inform the community about the risks and impacts on health, safety and the environment. This paper considers strategies to improve the efficiency of monitoring the large surface area overlying onshore storage complexes. We provide a synthesis of findings from monitoring for CO2 leakage at geological storage sites both natural and engineered, and from monitoring controlled releases of CO2 at four shallow release facilities – ZERT (USA), Ginninderra (Australia), Ressacada (Brazil) and CO2 field lab (Norway)

The Ginninderra CH4 and CO2 release experiment: An evaluation of gas detection and quantification techniques

A methane (CH4) and carbon dioxide (CO2) release experiment was held from April to June 2015 at the Ginninderra Controlled Release Facility in Canberra, Australia. The experiment provided an opportunity to compare different emission quantification techniques against a simulated CH4 and CO2 point source release, where the actual release rates were unknown to the participants. Eight quantification techniques were assessed: three tracer ratio techniques (two mobile); backwards Lagrangian stochastic modelling; forwards Lagrangian stochastic modelling; Lagrangian stochastic (LS) footprint modelling; atmospheric tomography using point and using integrated line sensors. The majority of CH4 estimates were within 20% of the actual CH4 release rate (5.8 g/min), with the tracer ratio technique providing the closest estimate to both the CH4 and CO2 release rates (100 g/min). Once the release rate was known, the majority of revised estimates were within 10% of the actual release rate. The study illustrates the power of measuring the emission rate using multiple simultaneous methods and obtaining an ensemble median or mean. An ensemble approach to estimating the CH4 emission rate proved successful with the ensemble median estimate within 16% for the actual release rate for the blind release experiment and within 2% once the release rate was known. The release also provided an opportunity to assess the effectiveness of stationary and mobile ground and aerial CH4 detection technologies. Sensor detection limits and sampling rates were found to be significant limitations for CH4 and CO2 detection. A hyperspectral imager\u27s capacity to image the CH4 release from 100 m, and a Boreal CH4 laser sensor\u27s ability to track moving targets suggest the future possibility to map gas plumes using a single laser and mobile aerial reflector

A (not so) shallow controlled CO2 release experiment in a fault zone

The CSIRO In-Situ Laboratory Project (ISL) is located in Western Australia and has two main objectives related to monitoring leaks from a CO2 storage complex by controlled-release experiments: 1) improving the monitorability of gaseous CO2 accumulations at intermediate depth, and 2) assessing the impact of faults on CO2 migration. A first test at the In-situ Lab has evaluated the ability to monitor and detect unwanted leakage of CO2 from a storage complex in a major fault zone. The ISL consists of three instrumented wells up to 400 m deep: 1) Harvey-2 used primarily for gaseous CO2 injection, 2) ISL OB-1, a fibreglass geophysical monitoring well with behind-casing instrumentation, and 3) a shallow (27 m) groundwater well for fluid sampling. A controlled-release test injected 38 tonnes of CO2 between 336-342 m depth in February 2019, and the gas was monitored by a wide range of downhole and surface monitoring technologies. CO2 reached the ISL OB-1 monitoring well (7 m away) after approximately 1.5 days and an injection volume of 5 tonnes. Evidence of arrival was determined by distributed temperature sensing and the CO2 plume was detected also by borehole seismic after injection of as little as 7 tonnes. Observations suggest that the fault zone did not alter the CO2 migration along bedding at the scale and depth of the experiment. No vertical CO2 migration was detected beyond the perforated injection interval; no notable changes were observed in groundwater quality or soil gas chemistry during and post injection. The early detection of significantly less than 38 tonnes of CO2 injected into the shallow subsurface demonstrates rapid and sensitive monitorability of potential leaks in the overburden of a commercial-scale storage project, prior to reaching shallow groundwater, soil zones or the atmosphere. The ISL is a unique and enduring research facility at which monitoring technologies will be further developed and tested for increasing public and regulator confidence in the ability to detect potential CO2 leakage at shallow to intermediate depth

The FLUXNET2015 dataset and the ONEFlux processing pipeline for eddy covariance data

The FLUXNET2015 dataset provides ecosystem-scale data on CO2, water, and energy exchange between the biosphere and the atmosphere, and other meteorological and biological measurements, from 212 sites around the globe (over 1500 site-years, up to and including year 2014). These sites, independently managed and operated, voluntarily contributed their data to create global datasets. Data were quality controlled and processed using uniform methods, to improve consistency and intercomparability across sites. The dataset is already being used in a number of applications, including ecophysiology studies, remote sensing studies, and development of ecosystem and Earth system models. FLUXNET2015 includes derived-data products, such as gap-filled time series, ecosystem respiration and photosynthetic uptake estimates, estimation of uncertainties, and metadata about the measurements, presented for the first time in this paper. In addition, 206 of these sites are for the first time distributed under a Creative Commons (CC-BY 4.0) license. This paper details this enhanced dataset and the processing methods, now made available as open-source codes, making the dataset more accessible, transparent, and reproducible.Peer reviewe