Nucleating Effect of Carbon Nanoparticles and Their Influence on the Thermal and Chemical Stability of Polypropylene

The effect of carbon nanofibers (CNFs) and carbon nanotubes (CNTs) on the thermal and chemical stability of polypropylene (PP) when subjected to oxidation in a strong acid medium was studied. The effect of CNFs and CNTs on the crystalline morphology and the melting and crystallization temperatures was also studied. The thermal stability increased markedly; the decomposition temperature, for example, increased from 293∘C for pure PP to 312 and 320∘C for PP with CNFs and CNTs, respectively. The crystallization temperature increased perceptibly with the addition of CNTs or CNFs, from 107∘C for pure PP to 112 and 114∘C for PP with CNFs and CNTs, respectively. The oxidative degradation with nitric acid produced a reduction in molecular weight; however, this negative effect was less pronounced in the PP compositions with carbon nanoparticles. After 8 hours in nitric acid, this reduction was from 141,000 to 68,000 (for pure PP), to 75,000 (for PP-CNFs), and 79,500 (for PP-CNTs). X-ray diffraction showed that the alpha type crystallinity remains, irrespective of the nucleating agent. Finally, the intensity ratio between the (040) (at 16.7∘) and the (110) (at 13.9∘) reflections increased, which was taken as an indication of an increasing nucleating efficiency

Nucleating Effect of Carbon Nanoparticles and Their Influence on the Thermal and Chemical Stability of Polypropylene

The effect of carbon nanofibers (CNFs) and carbon nanotubes (CNTs) on the thermal and chemical stability of polypropylene (PP) when subjected to oxidation in a strong acid medium was studied. The effect of CNFs and CNTs on the crystalline morphology and the melting and crystallization temperatures was also studied. The thermal stability increased markedly; the decomposition temperature, for example, increased from 293 • C for pure PP to 312 and 320 • C for PP with CNFs and CNTs, respectively. The crystallization temperature increased perceptibly with the addition of CNTs or CNFs, from 107 • C for pure PP to 112 and 114 • C for PP with CNFs and CNTs, respectively. The oxidative degradation with nitric acid produced a reduction in molecular weight; however, this negative effect was less pronounced in the PP compositions with carbon nanoparticles. After 8 hours in nitric acid, this reduction was from 141,000 to 68,000 (for pure PP), to 75,000 (for PP-CNFs), and 79,500 (for PP-CNTs). X-ray diffraction showed that the alpha type crystallinity remains, irrespective of the nucleating agent. Finally, the intensity ratio between the (040) (at 16.7 • ) and the (110) (at 13.9 • ) reflections increased, which was taken as an indication of an increasing nucleating efficiency

The ALHAMBRA Project: A large area multi medium-band optical and NIR photometric survey

(ABRIDGED) We describe the first results of the ALHAMBRA survey which provides cosmic tomography of the evolution of the contents of the Universe over most of Cosmic history. Our approach employs 20 contiguous, equal-width, medium-band filters covering from 3500 to 9700 A, plus the JHKs bands, to observe an area of 4 sqdeg on the sky. The optical photometric system has been designed to maximize the number of objects with accurate classification by SED and redshift, and to be sensitive to relatively faint emission lines. The observations are being carried out with the Calar Alto 3.5m telescope using the cameras LAICA and O-2000. The first data confirm that we are reaching the expected magnitude limits of AB<~25 mag in the optical filters from the blue to 8300 A, and from AB=24.7 to 23.4 for the redder ones. The limit in the NIR is (Vega) K_s~20, H~21, J~22. We expect to obtain accurate redshift values, Delta z/(1+z) <~ 0.03 for about 5x10^5 galaxies with I<~25 (60% complete), and z_med=0.74. This accuracy, together with the homogeneity of the selection function, will allow for the study of the redshift evolution of the large scale structure, the galaxy population and its evolution with redshift, the identification of clusters of galaxies, and many other studies, without the need for any further follow-up. It will also provide targets for detailed studies with 10m-class telescopes. Given its area, spectral coverage and its depth, apart from those main goals, the ALHAMBRA-Survey will also produce valuable data for galactic studies.Comment: Accepted to the Astronomical Journal. 43 pages, 18 figures. The images have been reduced in resolution to adapt to standard file sizes. Readers can find the full-resolution version of the paper at the ALHAMBRA web site (http://www.iaa.es/alhambra) under the "Publications" lin

SPIDER VII - Revealing the Stellar Population Content of Massive Early-type Galaxies out to 8Re

Radial trends of stellar populations in galaxies provide a valuable tool to understand the mechanisms of galaxy growth. In this paper, we present the first comprehensive analysis of optical-optical and optical-NIR colours, as a function of galaxy mass, out to the halo region (8Re) of early-type galaxies (ETGs). We select a sample of 674 massive ETGs (M*>3x10^10MSun) from the SDSS-based SPIDER survey. By comparing with a large range of population synthesis models, we derive robust constraints on the radial trends in age and metallicity. Metallicity is unambiguously found to decrease outwards, with a measurable steepening of the slope in the outer regions (Re<R<8Re). The gradients in stellar age are found to be more sensitive to the models used, but in general, the outer regions of ETGs feature older populations compared to the cores. This trend is strongest for the most massive galaxies in our sample (M*>10^11MSun). Furthermore, when segregating with respect to large scale environment, the age gradient is more significant in ETGs residing in higher density regions. These results shed light on the processes leading from the formation of the central core to the growth of the stellar envelope of massive galaxies. The fact that the populations in the outer regions are older and more metal-poor than in the core suggests a process whereby the envelope of massive galaxies is made up of accreted small satellites (i.e. minor mergers) whose stars were born during the first stages of galaxy formation.Comment: 20 pages, 13 figures, 10 tables. Accepted for publication in MNRA

Extended narrow-line emission in the bright Seyfert 1.5 galaxy HE 2211-3903

Extended narrow-line regions (ENLRs) and extended emission-line regions (EELRs) have been the focus of integral field spectroscopy aiming at the inner kiloparsecs of nearby Seyfert galaxies as well as the larger environment of high redshift QSOs. Based on observations with the Wide Field Spectrograph WiFeS at the 2.3 m telescope of the Australian National University, we present spatially resolved emission-line diagnostics of the bright Seyfert 1.5 galaxy HE 2211-3903 which is drawn from a sample of the brightest Seyfert galaxies at z<0.06 with luminosities around the classical Seyfert/QSO demarcation. In addition to the previously known spiral arms of HE 2211-3903, the emission-line maps reveal a large scale ring with a radius of about 6 kpc which is connected to the active galactic nucleus (AGN) through a bar-like structure. The overall gas kinematics indicates a disk rotation pattern. The emission-line ratios show Seyfert-type, HII region-type, and composite classifications, while there is no strong evidence of LINER-type ratios. Shock ionization is likely to be negligible throughout the galaxy. The composite line ratios are explained via a mixing line between AGN and HII region photoionization. Composite line ratios are predominantly found in between the HII regions in the circum-nuclear region, the bar-like structure to the east of the nucleus, and the eastern half of the ring, suggesting AGN photoionization of the low-density interstellar medium in an ENLR on galaxy scales. The line ratios in the nucleus indicate N-enrichment, which is discussed in terms of chemical enrichment by Wolf-Rayet and Asymptotic Giant Branch stars during past and ongoing nuclear starburst activity.Comment: 16 pages, 14 figures, accepted for publication in The Astronomical Journa

CRIRES-POP: A library of high resolution spectra in the near-infrared

New instrumental capabilities and the wealth of astrophysical information extractable from the near-infrared wavelength region have led to a growing interest in the field of high resolution spectroscopy at 1-5 mu. We aim to provide a library of observed high-resolution and high signal-to-noise-ratio near-infrared spectra of stars of various types throughout the Hertzsprung-Russell diagram. This is needed for the exploration of spectral features in this wavelength range and for comparison of reference targets with observations and models. High quality spectra were obtained using the CRIRES near-infrared spectrograph at ESO's VLT covering the range from 0.97 to 5.3 mu at high spectral resolution. Accurate wavelength calibration and correction for of telluric lines were performed by fitting synthetic transmission spectra for the Earth's atmosphere to each spectrum individually. We describe the observational strategy and the current status and content of the library which includes 13 objects. The first examples of finally reduced spectra are presented. This publication will serve as a reference paper to introduce the library to the community and explore the extensive amount of material.Comment: accepted for publication in A&A; see also the project webpage http://www.univie.ac.at/crirespo

Identification of metal-poor stars using the artificial neural network

Context. Identification of metal-poor stars among field stars is extremely useful for studying the structure and evolution of the Galaxy and of external galaxies. Aims. We search for metal-poor stars using the artificial neural network (ANN) and extend its usage to determine absolute magnitudes. Methods. We have constructed a library of 167 medium-resolution stellar spectra (R ~ 1200) covering the stellar temperature range of 4200 to 8000 K, log g range of 0.5 to 5.0, and [Fe/H] range of −3.0 to +0.3 dex. This empirical spectral library was used to train ANNs, yielding an accuracy of 0.3 dex in [Fe/H] , 200 K in temperature, and 0.3 dex in log g. We found that the independent calibrations of near-solar metallicity stars and metal-poor stars decreases the errors in Teff and log g by nearly a factor of two. Results. We calculated Teff, log g, and [Fe/H] on a consistent scale for a large number of field stars and candidate metal-poor stars. We extended the application of this method to the calibration of absolute magnitudes using nearby stars with well-estimated parallaxes. A better calibration accuracy for MV could be obtained by training separate ANNs for cool, warm, and metal-poor stars. The current accuracy of MV calibration is ±0.3 mag. Conclusions. A list of newly identified metal-poor stars is presented. The MV calibration procedure developed here is reddening-independent and hence may serve as a powerful tool in studying galactic structure

Fitting the integrated Spectral Energy Distributions of Galaxies

Fitting the spectral energy distributions (SEDs) of galaxies is an almost universally used technique that has matured significantly in the last decade. Model predictions and fitting procedures have improved significantly over this time, attempting to keep up with the vastly increased volume and quality of available data. We review here the field of SED fitting, describing the modelling of ultraviolet to infrared galaxy SEDs, the creation of multiwavelength data sets, and the methods used to fit model SEDs to observed galaxy data sets. We touch upon the achievements and challenges in the major ingredients of SED fitting, with a special emphasis on describing the interplay between the quality of the available data, the quality of the available models, and the best fitting technique to use in order to obtain a realistic measurement as well as realistic uncertainties. We conclude that SED fitting can be used effectively to derive a range of physical properties of galaxies, such as redshift, stellar masses, star formation rates, dust masses, and metallicities, with care taken not to over-interpret the available data. Yet there still exist many issues such as estimating the age of the oldest stars in a galaxy, finer details ofdust properties and dust-star geometry, and the influences of poorly understood, luminous stellar types and phases. The challenge for the coming years will be to improve both the models and the observational data sets to resolve these uncertainties. The present review will be made available on an interactive, moderated web page (sedfitting.org), where the community can access and change the text. The intention is to expand the text and keep it up to date over the coming years.Comment: 54 pages, 26 figures, Accepted for publication in Astrophysics & Space Scienc

Measurement of the cross-section and charge asymmetry of WW bosons produced in proton-proton collisions at s=8\sqrt{s}=8 TeV with the ATLAS detector

This paper presents measurements of the $W^+ \rightarrow \mu^+\nu$ and $W^- \rightarrow \mu^-\nu$ cross-sections and the associated charge asymmetry as a function of the absolute pseudorapidity of the decay muon. The data were collected in proton--proton collisions at a centre-of-mass energy of 8 TeV with the ATLAS experiment at the LHC and correspond to a total integrated luminosity of 20.2~\mbox{fb^{-1}}. The precision of the cross-section measurements varies between 0.8% to 1.5% as a function of the pseudorapidity, excluding the 1.9% uncertainty on the integrated luminosity. The charge asymmetry is measured with an uncertainty between 0.002 and 0.003. The results are compared with predictions based on next-to-next-to-leading-order calculations with various parton distribution functions and have the sensitivity to discriminate between them.Comment: 38 pages in total, author list starting page 22, 5 figures, 4 tables, submitted to EPJC. All figures including auxiliary figures are available at https://atlas.web.cern.ch/Atlas/GROUPS/PHYSICS/PAPERS/STDM-2017-13

The population of OB supergiants in the starburst cluster Westerlund 1

Context. After leaving the main sequence, massive stars undergo complex evolution, a process that is still poorly understood. With a population of hundreds of OB stars, the starburst cluster Westerlund 1 offers an unparallelled environment to study their evolutionary tracks. Aims. We characterise a large sample of evolved OB stars in the cluster, with the aim of determining cluster parameters and place stars in an evolutionary sequence. Methods. We used the FORS2 instrument on the VLT to obtain intermediate-resolution spectroscopy over the range 5800-9000 Å of about a hundred stars selected as likely members of the cluster based on their photometry. We developed criteria for their spectral classification using only spectral features in the range observed. We discuss these criteria, useful for spectral classification of early-type stars in the GAIA spectral region, in the appendix. Using these criteria, we obtain spectral classifications, probably accurate to one subtype, for 57 objects, most of which had no previous classification or a generic classification. Results. We identify more than 50 objects as OB supergiants. We find almost 30 luminous early-B supergiants and a number of less luminous late-O supergiants. In addition, we find a few mid B supergiants with very high luminosity, some of them displaying signs of heavy mass loss. All these stars form a sequence compatible with theoretical evolutionary tracks. In addition, two early B supergiants also show indication of heavy mass loss and may represent the evolutionary phase immediately prior to the Wolf-Rayet stage. We investigate cluster properties using the spectral types and existing photometry. We find that the reddening law to the cluster does not deviate strongly from standard, even though extinction is quite variable, with an average value AV=10.8. Though evolutionary tracks for high-mass stars are subject to large uncertainties, our data support an age of ≳ 5 Myr and a distance d ≈5 kpc for Westerlund 1. Conclusions. The spectral types observed are compatible with a single burst of star formation (the age range is very unlikely to be >1 Myr). Westerlund 1 shows its potentiality as a laboratory for massive star evolution, which can be fulfilled by detailed study of the population presented here. </br