Assessment of Woody Residual Biomass Generation Capacity in the Central Region of Portugal: Analysis of the Power Production Potential

Biomass is an alternative energy source with high potential to contribute to the global energy mix and to countries’ energetic independence. The case of Portugal is particularly relevant, given its biomass availability. Thus, the quantification of woody residual biomass is assumed to be urgent. To achieve the objective of quantifying residual woody biomass, various available data were used, namely the Land Cover and Soil Use Map (COS 2018), from which areas occupied by different categories were selected as being the most relevant. Then, based on coefficients previously established, the amounts of residual woody biomass were determined, namely for maritime pine forests, eucalyptus forests, scrubland, vineyards, olive groves, and orchards. Then, the potential for generating electricity was estimated. It was found that for the hypothetical scenario of the total conversion of the recently closed Pêgo coal power plant to biomass, the available amounts of residual woody biomass in the country would not be sufficient to ensure the operation. On the other hand, if the power plant only worked as a backup unit, the available quantities could ensure its operation and contribute to creating a value chain for residual woody biomass of forest and agricultural origin within a circular economy and sustainable development approachinfo:eu-repo/semantics/publishedVersio

Residual Biomass: A Comprehensive Review on the Importance, Uses and Potential in a Circular Bioeconomy Approach

ReviewThe paradigm shift towards sustainable growth is urgent, and biomass, which is the oldest energy source that humans have used since the discovery of fire, might play an important role. Biomass waste from forestry and agriculture is expected to fuel part of the increasing demand for biomass, and its valorization allows for more the efficient use of nutrients and resources. In this study, we carried out an extensive literature review on the valorization of residual agroforestry biomass since the 1970s to understand the leading research focuses on the subject over the last few decades, identify the most recent trends, and establish a possible solution path for the future of biomass. It was observed that most studies focused on biomass as being capable of replacing fossil energy sources. According to the literature, biomass has the most significant potential to meet requirements and ensure fuel supplies in the future. The developments of the last decades have significantly improved the conversion processes, leading to greener solutions, but there is still much to be studied and put into practice. Closing the loop into biomass waste recovery will be essential for a genuinely circular bioeconomyinfo:eu-repo/semantics/publishedVersio

Reducing Rural Fire Risk through the Development of a Sustainable Supply Chain Model for Residual Agroforestry Biomass Supported in aWeb Platform: A Case Study in Portugal Central Region with the Project BioAgroFloRes

In the European Mediterranean region, rural fires are a widely known problem that cause serious socio-economic losses and undesirable environmental consequences, including the loss of lives, infrastructures, cultural heritage, and ecosystem services such as carbon sequestration and the provisioning of raw materials. In the last decades, the collapse of the traditional rural socioeconomic systems that once characterized the Mediterranean region, along with land-use changes, have created conflicts and additional driving factors for rural fires. Within Europe, Portugal is the most affected country by rural fires. This work intends to demonstrate the importance of recovering and valorizing residual agroforestry biomass to reduce rural fire risk in Portugal, and thus contributing to a fire resilient landscape. From the results of the known causes of fires in Portugal, it becomes very clear that it is crucial to educate people to end risky behaviors, such as the burning of agroforestry leftovers that causes 27% of fires in Portugal each year. The valorization of the existing energy potential in the lignocellulosic biomass of agroforestry residues favors the reduction of the probability of rural fires, this being the focus of the project BioAgroFloRes—Sustainable Supply Chain Model for Residual Agroforestry Biomass supported in a Web Platform—introduced and explained hereinfo:eu-repo/semantics/publishedVersio

The Influence of Age on the Wood Properties of Paulownia tomentosa (Thunb.) Steud

Forests in Portugal are highly dependent on a short number of wood species, and new species with higher profitability are needed. The Paulownia species has generated great interest due to its fast-growing and relatively good wood properties. However, environmental factors have shown that Paulownia grows differently in each case. This study intends to determine the properties of young Paulownia trees from Portuguese plantations to determine the best age to cut the trees according to their use. The chemical composition (extractives in dichloromethane, ethanol and water, lignin, -cellulose, and hemicelluloses), heating value, elemental analysis (CHNO), inorganic elements and thermogravimetric analyses (TGA), and the most important mechanical and physical properties (density, MOE, bending strength, water absorption equilibrium, moisture content, and dimensional changes) were determined for 1-, 3-, and 5-year-old trees. The results show that, chemically, the extractives increased while hemicelluloses decreased with age, and no trend was found for lignin and -cellulose. The physical and mechanical properties increased with age, except for the MOE and bending strength. The 5-year-old samples presented the best features for pellet production, namely, calorific power, elemental composition CHNO and sulfur, and inorganic elementsinfo:eu-repo/semantics/publishedVersio

Theoretical search for Chevrel phase based thermoelectric materials

We investigate the thermoelectric properties of some semiconducting Chevrel phases. Band structure calculations are used to compute thermopowers and to estimate of the effects of alloying and disorder on carrier mobility. Alloying on the Mo site with transition metals like Re, Ru or Tc to reach a semiconducting composition causes large changes in the electronic structure at the Fermi level. Such alloys are expected to have low carrier mobilities. Filling with transition metals was also found to be incompatible with high thermoelectric performance based on the calculated electronic structures. Filling with Zn, Cu, and especially with Li was found to be favorable. The calculated electronic structures of these filled Chevrel phases are consistent with low scattering of carriers by defects associated with the filling. We expect good mobility and high thermopower in materials with the composition close to (Li,Cu)$_4$Mo$_6$Se$_8$, particularly when Li-rich, and recommend this system for experimental investigation.Comment: 4 two-column pages, 4 embedded ps figure

A Self-Consistent First-Principles Technique Having Linear Scaling

An algorithm for first-principles electronic structure calculations having a computational cost which scales linearly with the system size is presented. Our method exploits the real-space localization of the density matrix, and in this respect it is related to the technique of Li, Nunes and Vanderbilt. The density matrix is expressed in terms of localized support functions, and a matrix of variational parameters, L, having a finite spatial range. The total energy is minimized with respect to both the support functions and the elements of the L matrix. The method is variational, and becomes exact as the ranges of the support functions and the L matrix are increased. We have tested the method on crystalline silicon systems containing up to 216 atoms, and we discuss some of these results.Comment: 12 pages, REVTeX, 2 figure