74 research outputs found
Probing the Structure-Performance Relationship of Lithium-Ion Battery Cathodes Using Pore-Networks Extracted from Three-Phase Tomograms
Pore-scale simulations of Li-ion battery electrodes were conducted using both pore-network modeling and direct numerical simulation. Ternary tomographic images of NMC811 cathodes were obtained and used to create the pore-scale computational domains. A novel network extraction method was developed to manage the extraction of N-phase networks which was used to extract all three phases of NMC-811 electrode along with their interconnections Pore network results compared favorably with direct numerical simulations (DNS) in terms of effective transport properties of each phase but were obtained in significantly less time. Simulations were then conducted with combined diffusion-reaction to simulate the limiting current behavior. It was found that when considering only ion and electron transport, the electrode structure could support current densities about 300 times higher than experimentally observed values. Additional case studies were conducted to illustrate the necessity of ternary images which allow separate consideration of carbon binder domain and active material. The results showed a 24.4% decrease in current density when the carbon binder was treated as a separate phase compared to lumping the CBD and active material into a single phase. The impact of nanoporosity in the carbon binder phase was also explored and found to enhance the reaction rate by 16.8% compared to solid binder. In addition, the developed technique used 58 times larger domain volume than DNS which opens up the possibility of modelling much larger tomographic data sets, enabling representative areas of typically inhomogeneous battery electrodes to be modelled accurately, and proposes a solution to the conflicting needs of high-resolution imaging and large volumes for image-based modelling. For the first time, three-phase pore network modelling of battery electrodes has been demonstrated and evaluated, opening the path towards a new modelling framework for lithium ion batteries.The described here was financially supported by the University of Engineering and Technology Lahore, Pakistan as well as the Natural Science and Engineering Research Council (NSERC) of Canada and in the UK by the Faraday Institution (EP/R042012/1 and EP/R042063/1). Pablo A. García-Salaberri thanks the support from the STFC Early Career Award (ST/R006873/1) during his stay at the Electrochemical Innovation La
Direct observations of electrochemically induced intergranular cracking in polycrystalline NMC811 particles
Establishing the nature of crack generation, formation, and propagation is paramount to understanding the degradation modes that govern decline in battery performance. Cracking has several possible origins; however, it can be classified in two general cases: mechanically induced, during manufacturing, or electrochemically induced, during operation. Accurate and repeatable tracking of operational cracking to sequentially image the same material as it undergoes cracking is highly challenging; observing these features requires the highest resolutions possible for 3D imaging techniques, necessitating very small sample geometry, while also achieving realistic electrochemical performance. Here, we present a technique in which particle cracking can be completely attributed to electrochemical stimulation via sequential ex situ imaging in a laboratory X-ray nano computed tomography (CT) instrument. This technique preserves the mechanical and electrochemical response of each particle without inducing damage in the particles except for the effects of high voltage. Significant cracking within the core of secondary particles was observed upon the electrochemical delithiation of NMC811, which propagated radially. As X-ray computed tomography allows for imaging of the particle cores, the particles were not required to be modified/milled, guaranteeing any synthesis induced strain in the particles was maintained during the whole technique, resulting in an observation that contrasts crystallographic data, suggesting a significant volume expansion of the secondary particles
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All-conjugated cationic copolythiophene "rod-rod" block copolyelectrolytes: Synthesis, optical properties and solvent-dependent assembly
The optical and thermal properties and solvent-dependent assembly of all-conjugated cationic copolythiophene block copolyelectrolytes are investigated.</p
The role of bi-polar plate design and the start-up protocol in the spatiotemporal dynamics during solid oxide fuel cell anode reduction
Start-up conditions largely dictate the performance longevity for solid oxide fuel cells (SOFCs). The SOFC anode is typically deposited as NiO-ceramic that is reduced to Ni-ceramic during start-up. Effective reduction is imperative to ensuring that the anode is electrochemically active and able to produce electronic and ionic current; the bi-polar plates (BPP) next to the anode allow the transport of current and gases, via land and channels, respectively. This study investigates a commercial SOFC stack that failed following a typical start-up procedure. The BPP design was found to substantially affect the spatiotemporal dynamics of the anode reduction; Raman spectroscopy detected electrochemically inactive NiO on the anode surface below the BPP land-contacts; X-ray computed tomography (CT) and scanning electron microscopy (SEM) identified associated contrasts in the electrode porosity, confirming the extension of heterogeneous features beyond the anode surface, towards the electrolyte-anode interface. Failure studies such as this are important for improving statistical confidence in commercial SOFCs and ultimately their competitiveness within the mass-market. Moreover, the spatiotemporal information presented here may aid in the development of novel BPP design and improved reduction protocol methods that minimize cell and stack strain, and thus maximize cell longevit
Modelling and experiments to identify high-risk failure scenarios for testing the safety of lithium-ion cells
Intentionally inducing worst-case thermal runaway scenarios in Li-ion cells on-demand is a definitive way to test
the efficacy of battery systems in safely mitigating the consequences of catastrophic failure. An internal shortcircuiting (ISC) device is implanted into three 18650 cell designs: one standard, one with a bottom vent, and one
with a thicker casing. Through an extensive study of 228 cells, the position at which thermal runaway initiates is
shown to greatly affect the tendency of cells to rupture and incur side-wall breaches at specific locations. The
risks associated with each failure mechanism and position of the ISC device are quantified using a custom
calorimeter that can decouple the heat from ejected and non-ejected contents. Causes of high-risk failure mechanisms, such as bursting and side-wall breaches, are elucidated using high-speed synchrotron X-ray imaging at
2000 frames per second and image-based 3D thermal runaway computational models, which together are used to
construct a comprehensive description of external risks based on internal structural and thermal phenomena.
What we talk about when we talk about "global mindset": managerial cognition in multinational corporations
Recent developments in the global economy and in multinational corporations have placed significant emphasis on the cognitive orientations of managers, giving rise to a number of concepts such as “global mindset” that are presumed to be associated with the effective management of multinational corporations (MNCs). This paper reviews the literature on global mindset and clarifies some of the conceptual confusion surrounding the construct. We identify common themes across writers, suggesting that the majority of studies fall into one of three research perspectives: cultural, strategic, and multidimensional. We also identify two constructs from the social sciences that underlie the perspectives found in the literature: cosmopolitanism and cognitive complexity and use these two constructs to develop an integrative theoretical framework of global mindset. We then provide a critical assessment of the field of global mindset and suggest directions for future theoretical and empirical research
Atomistic modelling of scattering data in the Collaborative Computational Project for Small Angle Scattering (CCP-SAS)
The capabilities of current computer simulations provide a unique opportunity to model small-angle scattering (SAS) data at the atomistic level, and to include other structural constraints ranging from molecular and atomistic energetics to crystallography, electron microscopy and NMR. This extends the capabilities of solution scattering and provides deeper insights into the physics and chemistry of the systems studied. Realizing this potential, however, requires integrating the experimental data with a new generation of modelling software. To achieve this, the CCP-SAS collaboration (http://www.ccpsas.org/) is developing open-source, high-throughput and user-friendly software for the atomistic and coarse-grained molecular modelling of scattering data. Robust state-of-the-art molecular simulation engines and molecular dynamics and Monte Carlo force fields provide constraints to the solution structure inferred from the small-angle scattering data, which incorporates the known physical chemistry of the system. The implementation of this software suite involves a tiered approach in which GenApp provides the deployment infrastructure for running applications on both standard and high-performance computing hardware, and SASSIE provides a workflow framework into which modules can be plugged to prepare structures, carry out simulations, calculate theoretical scattering data and compare results with experimental data. GenApp produces the accessible web-based front end termed SASSIE-web, and GenApp and SASSIE also make community SAS codes available. Applications are illustrated by case studies: (i) inter-domain flexibility in two- to six-domain proteins as exemplified by HIV-1 Gag, MASP and ubiquitin; (ii) the hinge conformation in human IgG2 and IgA1 antibodies; (iii) the complex formed between a hexameric protein Hfq and mRNA; and (iv) synthetic 'bottlebrush' polymers
The Physics of the B Factories
This work is on the Physics of the B Factories. Part A of this book contains a brief description of the SLAC and KEK B Factories as well as their detectors, BaBar and Belle, and data taking related issues. Part B discusses tools and methods used by the experiments in order to obtain results. The results themselves can be found in Part C
Multi-length scale microstructural design of micro-tubular Solid Oxide Fuel Cells for optimised power density and mechanical robustness
In this study, we aim to parametrically reveal the dependence of electrochemical performance on a variety of microstructural characteristics at multi-length scale in a micro-tubular solid oxide fuel cell to shed light on the advanced electrode design. Numerical Direct Simulation Monte Carlo method is used on the tomographically-reconstructed 3D microstructure of the anode to characterise the tortuosity factors as a function of the porosity and pore diameter accounting for the Knudsen flow. These are subsequently incorporated in the mass transport in 2D electrochemical simulations. Results show that the Knudsen tortuosity factor is two times larger than that estimated by the continuum physics. High substrate porosity and pore size show unnoticeable effect in facilitating the mass transport provided that the micro-channels span over 60% of the radial thickness. The width and radial distribution of the micro-channels have little influence on the mass transport, but the compactness greatly affects the global performance. Optimal designs are identified as i) 80% micro-channel length and 27% substrate porosity to reach maximum power density (1.18 W cm-2) with lowered mechanical strength, or ii) 60% micro-channels length and 27% porosity to obtain a more balanced performance (0.96 W cm-2) with better long term structural integrity
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