Characterization of volatile compounds of Daucus crinitus Desf. Headspace Solid Phase Microextraction as alternative technique to Hydrodistillation

<p>Abstract</p> <p>Background</p> <p>Traditionally, the essential oil of aromatic herbs is obtained using hydrodistillation (HD). Because the emitted volatile fraction plays a fundamental role in a plant's life, various novel techniques have been developed for its extraction from plants. Among these, headspace solid phase microextraction (HS-SPME) can be used to obtain a rapid fingerprint of a plant's headspace. <it>Daucus crinitus </it>Desf. is a wild plant that grows along the west coast of Algeria. Only a single study has dealt with the chemical composition of the aerial part oils of Algerian <it>D. crinitus</it>, in which isochavicol isobutyrate (39.0%), octyl acetate (12.3%), and β-caryophyllene (5.4%) were identified. Using GC-RI and GC-MS analysis, the essential oils and the volatiles extracted from separated organs of <it>D. crinitus </it>Desf. were studied using HS-SPME.</p> <p>Results</p> <p>GC-RI and GC-MS analysis identified 72 and 79 components in oils extracted using HD and in the volatile fractions extracted using SPME, respectively. Two types of essential oils were produced by the plant: the root oils had aliphatic compounds as the main component (87.0%-90.1%), and the aerial part oils had phenylpropanoids as the main component (43.1%-88.6%). HS-SPME analysis showed a more precise distribution of compounds in the organs studied: oxygenated aliphatic compounds were well represented in the roots (44.3%-84.0%), hydrocarbon aliphatic compounds were in the leaves and stems (22.2%-87.9%), and phenylpropanoids were in the flowers and umbels (47.9%-64.2%). Moreover, HS-SPME allowed the occurrence of isochavicol (29.6 - 34.7%) as main component in <it>D. crinitus </it>leaves, but it was not detected in the oils, probably because of its solubility in water.</p> <p>Conclusions</p> <p>This study demonstrates that HD and HS-SPME modes could be complimentary extraction techniques in order to obtain the complete characterization of plant volatiles.</p

Set optimization - a rather short introduction

Recent developments in set optimization are surveyed and extended including various set relations as well as fundamental constructions of a convex analysis for set- and vector-valued functions, and duality for set optimization problems. Extensive sections with bibliographical comments summarize the state of the art. Applications to vector optimization and financial risk measures are discussed along with algorithmic approaches to set optimization problems

Levantamento de reconhecimento de alta intensidade dos solos das bacias hidrográficas dos rios Guapi-Macacu e Caceribu.

O presente estudo refere-se ao levantamento dos solos da bacia hidrográfica dos rios Guapi-Macacu e Caceribu, Estado do Rio de Janeiro, que abrange uma área aproximada de 2.072 km2, realizado em nível de reconhecimento de alta intensidade de acordo com as normas preconizadas pela Embrapa Solos, com a utilização de geotecnologias e técnicas de mapeamento digital. Consiste na caracterização dos solos visando contribuir para o planejamento do uso e ocupação das terras de forma racional e sustentável. Como material básico, utilizou-se cartas topográfica do IBGE na escala de 1:50.000, que foram empregadas para geração de um modelo digital de elevação (MDE), tendo ainda o apoio de imagens do sensor TM do satélite Landsat 5 de 2011 e imagens Alos de 2007. Os resultados apresentados neste relatório técnico, além de permitir uma visão geral sobre as principais características ambientais da área, contém todos os critérios utilizados para distinção e classificação dos solos e uma descrição das principais classes de solos da bacia estudada, cuja distribuição espacial é representada em um mapa na escala 1:50.000. Este mapa é constituído por 51 unidades de mapeamento, que compõem uma legenda de identificação dos solos, individualizados até o quinto nível categórico, seguido das fases de vegetação, relevo e, para solos pouco evoluídos, substrato geológico. As principais classes de solos identificadas foram: Argissolos Amarelos, Argissolos Vermelho e Argissolos Vermelho- Amarelos; Latossolos Amarelos, Latossolos Vermelhos e Latossolos Vermelho-Amarelos; Cambissolos Háplicos, Neossolos Litólicos e Neossolos Regolíticos; Luvissolos Crômicos; e Nitossolos Háplicos, que predominam nas áreas de relevo degradacionais, enquanto nas áreas de relevo de agradação (baixadas) ocorrem os Gleissolos Tiomórficos, Gleissolos Sálicos, Gleissolos Melânicos e Gleissolos Háplicos; Neossolos Flúvicos; Planossolos Háplicos; e Organossolos.bitstream/item/160857/1/BPD-257-Levantamento-Reconh-BH-Guapi-Macacu.pd

Measurement of the inclusive and fiducial tt ¯ production cross-sections in the lepton+jets channel in pp collisions at s √ =8 TeV with the ATLAS detector

The inclusive and fiducial tt ¯ production cross-sections are measured in the lepton+jets channel using 20.2 fb −1 of proton-proton collision data at a centre-of-mass energy of 8 TeV recorded with the ATLAS detector at the LHC. Major systematic uncertainties due to the modelling of the jet energy scale and b -tagging efficiency are constrained by separating selected events into three disjoint regions. In order to reduce systematic uncertainties in the most important background, the W+jets process is modelled using Z+jets events in a data-driven approach. The inclusive tt ¯ cross-section is measured with a precision of 5.7% to be σ inc (tt ¯ ) = 248.3 ± 0.7 (stat.) ± 13.4 (syst.) ± 4.7 (lumi.) pb, assuming a top-quark mass of 172.5 GeV. The result is in agreement with the Standard Model prediction. The cross-section is also measured in a phase space close to that of the selected data. The fiducial cross-section is σ fid (tt ¯ ) = 48.8 ± 0.1 (stat.) ± 2.0 (syst.) ± 0.9 (lumi.) pb with a precision of 4.5%

Plantes envahissantes de Corse : une possible valorisation par la production d’huiles essentielles.

International audienc

Direct Identification of \u3b1-Bisabolol Enantiomers in an Essential Oil Using a Combined Ion Mobility-Mass Spectrometry/Quantum Chemistry Approach

Enantiomer-specific identification of chiral molecules in natural extracts is a challenging task, as many routine analytical techniques fail to provide selectivity in multicomponent mixtures. Here we describe an alternative approach, based on the combination of ion mobility-mass spectrometry (IM-MS) and quantum chemistry (QM), for the direct enantiomers differentiation in crude essential oils. The identification of \u3b1-bisabolol enantiomers contained in the raw essential oil (EO) from the Corsican Xanthium italicum fruits is reported as a proof-of-concept. Accordingly, IM-MS experiments performed in Ag+-doped methanol revealed the presence of both (+)- and (-)-\u3b1-bisabolol in the EO, while molecular simulations provided the structures of the two \u3b1-bisabolol enantiomer silver(I) adducts