207 research outputs found
Copper-Catalyzed Trifluoromethylation of Unactivated Olefins
Activating the inactive: A copper-catalyzed allylic trifluoromethylation of unactivated terminal olefins proceeds under mild conditions to produce linear allylic trifluoromethylated products with high E/Z selectivity (see scheme). The reaction can be applied to a range of substrates bearing numerous functional groups. Furthermore, the reaction is scalable and amenable to a benchtop setup.National Institutes of Health (U.S.) (GM46059)National Institutes of Health (U.S.) (Postdoctoral Fellowship F32GM093532)National Science Foundation (U.S.) (Grant ACHE-9808061)National Science Foundation (U.S.) (Grant DBI-9729592)National Institutes of Health (U.S.) (Grant 1S10RR13886-01
ChemInform Abstract: Reaction of Azo- and Azoxysulfones with Transition Metal Complexes. Part 2. Arylation of Olefins by Arylazo Aryl Sulfones Under Palladium(0) Catalysis.
ChemInform Abstract: REACTIONS OF TRIFLUOROMETHANESULFONYL AZIDE WITH AROMATIC COMPOUNDS
ChemInform Abstract: Novel Reaction of Arylazo Aryl and Arylazoxy Aryl Sulfones with Norbornene Catalyzed by a Palladium(0) Complex.
ChemInform Abstract: Highly Selective Radical Reactions Catalyzed by Ruthenium Complexes
ChemInform Abstract: Reactions of Azo and Azoxy Sulfones with Transition Metal Complexes. Part 5. Reactions of Arylazo Aryl Sulfones with α,β-Unsaturated Esters and Ketones Catalyzed by a Palladium(0) Complex.
ChemInform Abstract: Novel Halogenation of Thiophenes with Benzeneseleninyl Chloride and Aluminum Halide.
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