908 research outputs found
Acid/base-triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenes.
Electronic circular dichroism and circularly polarized luminescence acid/base switching activity has been demonstrated in helicene-bipyridine proligand 1âa and in its ârolloverâ cycloplatinated derivative 2âa. Whereas proligand 1âa displays a strong bathochromic shift (>160â
nm) of the nonpolarized and circularly polarized luminescence upon protonation, complex 2âa displays slightly stronger emission. This strikingly different behavior between singlet emission in the organic helicene and triplet emission in the organometallic derivative has been rationalized by using quantum-chemical calculations. The very large bathochromic shift of the emission observed upon protonation of azahelicene-bipyridine 1âa has been attributed to the decrease in aromaticity (promoting a charge-transfer-type transition rather than a ÏâÏ* transition) as well as an increase in the HOMOâLUMO character of the transition and stabilization of the LUMO level upon protonation
Infering Air Quality from Traffic Data using Transferable Neural Network Models
This work presents a neural network based model for inferring air quality from traffic measurements.
It is important to obtain information on air quality in urban environments in order to meet legislative and policy requirements. Measurement equipment tends to be expensive to purchase and maintain. Therefore, a model based approach capable of accurate determination of pollution levels is highly beneficial.
The objective of this study was to develop a neural network model to accurately infer pollution levels from existing data sources in Leicester, UK.
Neural Networks are models made of several highly interconnected processing elements. These elements process information by their dynamic state response to inputs. Problems which were not solvable by traditional algorithmic approaches frequently can be solved using neural networks.
This paper shows that using a simple neural network with traffic and meteorological data as inputs, the air quality can be estimated with a good level of generalisation and in near real-time.
By applying these models to links rather than nodes, this methodology can directly be used to inform traffic engineers and direct traffic management decisions towards enhancing local air quality and traffic management simultaneously.Universidad de MĂĄlaga. Campus de Excelencia Internacional AndalucĂa Tech
A Robust Approach for Multivariate Binary Vectors Clustering and Feature Selection
International audienceGiven a set of binary vectors drawn from a ÂŻnite multiple Bernoulli mixture model, an important problem is to determine which vectors are outliers and which features are relevant. The goal of this paper is to propose a model for binary vectors clustering that accommo- dates outliers and allows simultaneously the incorporation of a feature selection methodology into the clustering process. We derive an EM al- gorithm to ÂŻt the proposed model. Through simulation studies and a set of experiments involving handwritten digit recognition and visual scenes categorization, we demonstrate the usefulness and eÂźectiveness of our method
New result for the neutron -asymmetry parameter from UCNA
The neutron -decay asymmetry parameter defines the correlation
between the spin of the neutron and the momentum of the emitted electron, which
determines , the ratio of the axial-vector to
vector weak coupling constants. The UCNA Experiment, located at the Ultracold
Neutron facility at the Los Alamos Neutron Science Center, is the first to
measure such a correlation coefficient using ultracold neutrons (UCN).
Following improvements to the systematic uncertainties and increased
statistics, we report the new result which yields . Combination with the previous UCNA result and
accounting for correlated systematic uncertainties produces
and .Comment: 9 pages, 7 figures, updated to as-published versio
Final results for the neutron ÎČ-asymmetry parameter Aâ from the UCNA experiment
The UCNA experiment was designed to measure the neutron ÎČ-asymmetry parameter A0 using polarized ultracold neutrons (UCN). UCN produced via downscattering in solid deuterium were polarized via transport through a 7âT magnetic field, and then directed to a 1âT solenoidal electron spectrometer, where the decay electrons were detected in electron detector packages located on the two ends of the spectrometer. A value for A0 was then extracted from the asymmetry in the numbers of counts in the two detector packages. We summarize all of the results from the UCNA experiment, obtained during run periods in 2007, 2008â2009, 2010, and 2011â2013, which ultimately culminated in a 0.67% precision result for Aâ
Search for neutron dark decay: nâââÏâ+âeâșeâ»
In January, 2018, Fornal and Grinstein proposed that a previously unobserved neutron decay branch to a dark matter particle (Ï) could account for the discrepancy in the neutron lifetime observed in two different types of experiments. One of the possible final states discussed includes a single Ï along with an eâșeâ» pair. We use data from the UCNA (Ultracold Neutron Asymmetry) experiment to set limits on this decay channel. Coincident electron-like events are detected with ⌠4Ï acceptance using a pair of detectors that observe a volume of stored Ultracold Neutrons (UCNs). We use the timing information of coincidence events to select candidate dark sector particle decays by applying a timing calibration and selecting events within a physically-forbidden timing region for conventional n â p + eâ» + ÎœÌ
_e decays. The summed kinetic energy (E_(eâșeâ»)) from such events is reconstructed and used to set limits, as a function of the Ï mass, on the branching fraction for this decay channel
Multiple populations in globular clusters. Lessons learned from the Milky Way globular clusters
Recent progress in studies of globular clusters has shown that they are not
simple stellar populations, being rather made of multiple generations. Evidence
stems both from photometry and spectroscopy. A new paradigm is then arising for
the formation of massive star clusters, which includes several episodes of star
formation. While this provides an explanation for several features of globular
clusters, including the second parameter problem, it also opens new
perspectives about the relation between globular clusters and the halo of our
Galaxy, and by extension of all populations with a high specific frequency of
globular clusters, such as, e.g., giant elliptical galaxies. We review progress
in this area, focusing on the most recent studies. Several points remain to be
properly understood, in particular those concerning the nature of the polluters
producing the abundance pattern in the clusters and the typical timescale, the
range of cluster masses where this phenomenon is active, and the relation
between globular clusters and other satellites of our Galaxy.Comment: In press (The Astronomy and Astrophysics Review
Symmetry and Topology in Superconductors - Odd-frequency pairing and edge states -
Superconductivity is a phenomenon where the macroscopic quantum coherence
appears due to the pairing of electrons. This offers a fascinating arena to
study the physics of broken gauge symmetry. However, the important symmetries
in superconductors are not only the gauge invariance. Especially, the symmetry
properties of the pairing, i.e., the parity and spin-singlet/spin-triplet,
determine the physical properties of the superconducting state. Recently it has
been recognized that there is the important third symmetry of the pair
amplitude, i.e., even or odd parity with respect to the frequency. The
conventional uniform superconducting states correspond to the even-frequency
pairing, but the recent finding is that the odd-frequency pair amplitude arises
in the spatially non-uniform situation quite ubiquitously. Especially, this is
the case in the Andreev bound state (ABS) appearing at the surface/interface of
the sample. The other important recent development is on the nontrivial
topological aspects of superconductors. As the band insulators are classified
by topological indices into (i) conventional insulator, (ii) quantum Hall
insulator, and (iii) topological insulator, also are the gapped
superconductors. The influence of the nontrivial topology of the bulk states
appears as the edge or surface of the sample. In the superconductors, this
leads to the formation of zero energy ABS (ZEABS). Therefore, the ABSs of the
superconductors are the place where the symmetry and topology meet each other
which offer the stage of rich physics. In this review, we discuss the physics
of ABS from the viewpoint of the odd-frequency pairing, the topological
bulk-edge correspondence, and the interplay of these two issues. It is
described how the symmetry of the pairing and topological indices determines
the absence/presence of the ZEABS, its energy dispersion, and properties as the
Majorana fermions.Comment: 91 pages, 38 figures, Review article, references adde
Observation of associated near-side and away-side long-range correlations in âsNN=5.02ââTeV proton-lead collisions with the ATLAS detector
Two-particle correlations in relative azimuthal angle (ÎÏ) and pseudorapidity (Îη) are measured in âsNN=5.02ââTeV p+Pb collisions using the ATLAS detector at the LHC. The measurements are performed using approximately 1ââÎŒb-1 of data as a function of transverse momentum (pT) and the transverse energy (ÎŁETPb) summed over 3.1<η<4.9 in the direction of the Pb beam. The correlation function, constructed from charged particles, exhibits a long-range (2<|Îη|<5) ânear-sideâ (ÎÏâŒ0) correlation that grows rapidly with increasing ÎŁETPb. A long-range âaway-sideâ (ÎÏâŒÏ) correlation, obtained by subtracting the expected contributions from recoiling dijets and other sources estimated using events with small ÎŁETPb, is found to match the near-side correlation in magnitude, shape (in Îη and ÎÏ) and ÎŁETPb dependence. The resultant ÎÏ correlation is approximately symmetric about Ï/2, and is consistent with a dominant cosâĄ2ÎÏ modulation for all ÎŁETPb ranges and particle pT
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