OPTIMIZED MODIFICATION OF CROSSLINKED PVA BY GRAFTING FOR APPLICATION IN BIOMEDICAL FIELD AS HYDROGEL

ABSTRACT PVA (Polyvinyl alcohol) is one of the most widely used industrial vinyl polymer. It is biodegradable in its unmodified form but when it is modified by crosslinking and grafting techniques then its thermal stability was found to be increased but degradability decreases.In this study, PVA was crosslinked by using benzoyl peroxide solution and grafting of acryl monomers in different conditions to get maximum yield of modified polymer. Parameters of Temperature, time, amount of crosslinking agent were optimized. Time of about 1 hr at heating temperature of 80°C with 0.5 % benzoyl peroxide was found to be optimum for getting better yield of grafted modified polymer. Crosslinked and grafted PVA have shown greater stability but biodegradability was found to be decreased. So formed modified PVA may find application in Biomedical field like hydrogel formation as it has also shown good absorption behavior and sweeling properties. KEYWORDS: Polyvinyl alcohol, Crosslinking, Grafting, Biodegradability, Optimized conditions

Canonical Quantization of Spherically Symmetric Dust Collapse

Quantum gravity effects are likely to play a crucial role in determining the outcome of gravitational collapse during its final stages. In this contribution we will outline a canonical quantization of the LeMaitre-Tolman-Bondi models, which describe the collapse of spherical, inhomogeneous, non-rotating dust. Although there are many models of gravitational collapse, this particular class of models stands out for its simplicity and the fact that both black holes and naked singularity end states may be realized on the classical level, depending on the initial conditions. We will obtain the appropriate Wheeler-DeWitt equation and then solve it exactly, after regularization on a spatial lattice. The solutions describe Hawking radiation and provide an elegant microcanonical description of black hole entropy, but they raise other questions, most importantly concerning the nature of gravity's fundamental degrees of freedom.Comment: 19 pages no figures. Contribution to a festschrift in honor of Joshua N. Goldber

A Statistical Study on Photospheric Magnetic Nonpotentiality of Active Regions and Its Relationship with Flares during Solar Cycles 22-23

A statistical study is carried out on the photospheric magnetic nonpotentiality in solar active regions and its relationship with associated flares. We select 2173 photospheric vector magnetograms from 1106 active regions observed by the Solar Magnetic Field Telescope at Huairou Solar Observing Station, National Astronomical Observatories of China, in the period of 1988-2008, which covers most of the 22nd and 23rd solar cycles. We have computed the mean planar magnetic shear angle (\bar{\Delta\phi}), mean shear angle of the vector magnetic field (\bar{\Delta\psi}), mean absolute vertical current density (\bar{|J_{z}|}), mean absolute current helicity density (\bar{|h_{c}|}), absolute twist parameter (|\alpha_{av}|), mean free magnetic energy density (\bar{\rho_{free}}), effective distance of the longitudinal magnetic field (d_{E}), and modified effective distance (d_{Em}) of each photospheric vector magnetogram. Parameters \bar{|h_{c}|}, \bar{\rho_{free}}, and d_{Em} show higher correlation with the evolution of the solar cycle. The Pearson linear correlation coefficients between these three parameters and the yearly mean sunspot number are all larger than 0.59. Parameters \bar{\Delta\phi}, \bar{\Delta\psi}, \bar{|J_{z}|}, |\alpha_{av}|, and d_{E} show only weak correlations with the solar cycle, though the nonpotentiality and the complexity of active regions are greater in the activity maximum periods than in the minimum periods. All of the eight parameters show positive correlations with the flare productivity of active regions, and the combination of different nonpotentiality parameters may be effective in predicting the flaring probability of active regions.Comment: 20 pages, 5 figures, 4 tables, accepted for publication in Solar Physic

Search for direct production of charginos and neutralinos in events with three leptons and missing transverse momentum in √s = 7 TeV pp collisions with the ATLAS detector

A search for the direct production of charginos and neutralinos in final states with three electrons or muons and missing transverse momentum is presented. The analysis is based on 4.7 fb−1 of proton–proton collision data delivered by the Large Hadron Collider and recorded with the ATLAS detector. Observations are consistent with Standard Model expectations in three signal regions that are either depleted or enriched in Z-boson decays. Upper limits at 95% confidence level are set in R-parity conserving phenomenological minimal supersymmetric models and in simplified models, significantly extending previous results

Jet size dependence of single jet suppression in lead-lead collisions at sqrt(s(NN)) = 2.76 TeV with the ATLAS detector at the LHC

Measurements of inclusive jet suppression in heavy ion collisions at the LHC provide direct sensitivity to the physics of jet quenching. In a sample of lead-lead collisions at sqrt(s) = 2.76 TeV corresponding to an integrated luminosity of approximately 7 inverse microbarns, ATLAS has measured jets with a calorimeter over the pseudorapidity interval |eta| < 2.1 and over the transverse momentum range 38 < pT < 210 GeV. Jets were reconstructed using the anti-kt algorithm with values for the distance parameter that determines the nominal jet radius of R = 0.2, 0.3, 0.4 and 0.5. The centrality dependence of the jet yield is characterized by the jet "central-to-peripheral ratio," Rcp. Jet production is found to be suppressed by approximately a factor of two in the 10% most central collisions relative to peripheral collisions. Rcp varies smoothly with centrality as characterized by the number of participating nucleons. The observed suppression is only weakly dependent on jet radius and transverse momentum. These results provide the first direct measurement of inclusive jet suppression in heavy ion collisions and complement previous measurements of dijet transverse energy imbalance at the LHC.Comment: 15 pages plus author list (30 pages total), 8 figures, 2 tables, submitted to Physics Letters B. All figures including auxiliary figures are available at http://atlas.web.cern.ch/Atlas/GROUPS/PHYSICS/PAPERS/HION-2011-02