Adsorption of 3-chloroaniline on potato skin in aqueous solution

The adsorption behaviour of aromatic amine 3-chloroaniline (3-CA) from aqueous solution on fresh potato skin was investigated. A series of batch experiments were conducted under different experimental conditions of contact time, 3-chloroaniline concentration, weight of potato skin, pH, temperature, and ionic strength using RP-HPLC analysis. Adsorption equilibrium of 3-chloroaniline at concentration of 10 µg/mL on 1 g weight of chopped potato skin was achieved in 24 hours. Using different varieties of potato skin showed that the adsorption of 3-CA on Nicola variety is higher compared to Sante and Maris Peer varieties. Adsorption on potato skin was found to be generally higher compared to cortex and pith tissues. Analysis of adsorption isotherm shows that equilibrium data was fitted to Freundlich model (R² = 0.977). Maximum adsorption capacities of 3-chloroaniline were found in the pH range from 3 to 9, whereas low adsorption quantities were found in high acidic and high basic solutions (pH 2 and pH 13, resp.). Adsorption capacity increased with an increase in temperature from 4°C to 30°C but decreased with further increase of temperature to 40°C. Testing the ionic strength showed that increasing the concentration of electrolyte reduces the adsorption efficiency. This study indicated that the fresh potato skin (without any treatment) is possible to use as a new adsorbent for removal of 3-chloroaniline from industrial waste water

Colouring of Pacific barkcloth: identification of the brown, red and yellow colourants used in the decoration of historic Pacific barkcloths

Barkcloth textiles made in the Pacific islands and collected by western explorers in the eighteenth and nineteenth centuries form part of many museum collections worldwide. Here high-performance liquid chromatography (HPLC) and X-ray fluorescence (XRF) were used on cloths that were highly coloured or pigmented specifically focussing on identifying the red, yellow and brown colorants. The cloths studied came from collections held at the Hunterian, University of Glasgow, the Economic Botany Collection, Royal Botanic Gardens Kew and the Centre for Textile Conservation and Technical Art History, University of Glasgow. HPLC analysis was carried out following a sequential extraction procedure to minimise changes to the colorants during extraction. A portable XRF was used so no invasive sampling was required. A small number of plant derived colorants were found, Morinda citrifolia, noni (morindin or morindone), Rubia tinctorum (madder), tree tannins and Curcuma longa (turmeric) plus an inorganic colorant, iron oxide. For 40 samples a single colorant was found while in the remaining 12 samples combinations of up to three colorants were found. Madder was found in only 2 samples on the same cloth. The morindone coloured samples were all red whereas morindin samples were both red and yellow. Morindin was used predominantly in combination with other colouring agents. A combination of iron ochre and organic colorant was found in 4 samples. These findings show that despite the numerous potential colorant sources for red, brown and yellow shades listed in the many accounts of historic barkcloth making, only five types of plant colourant and one inorganic pigment were found. There are a number of potential reasons for these findings. Some colours may have faded and so no longer appear coloured. It is also possible that, as some of these cloths were prepared specifically as gifts for visitors or for ceremonial uses, the makers used materials that they knew would retain their integrity over time. Perhaps, like artisans worldwide, experience had taught them that some colorants, although initially bright and vivid, faded over time

Tacrolimus versus Cyclosporine after Hematopoietic Cell Transplantation for Acquired Aplastic Anemia

AbstractCombinations of cyclosporine (CSP) with methotrexate (MTX) have been widely used for immunosuppression after allogeneic transplantation for acquired aplastic anemia. We compared outcomes with tacrolimus (TAC)+MTX versus CSP+MTX after transplantation from HLA-identical siblings (SIB) or unrelated donors (URD) in a retrospective cohort of 949 patients with severe aplastic anemia. Study endpoints included hematopoietic recovery, graft failure, acute graft-versus-host disease (GVHD), chronic GVHD, and mortality. TAC+MTX was used more frequently in older patients and, in recent years, in both SIB and URD groups. In multivariate analysis, TAC+MTX was associated with a lower risk of mortality in URD recipients and with slightly earlier absolute neutrophil count recovery in SIB recipients. Other outcomes did not differ statistically between the 2 regimens. No firm conclusions were reached regarding the relative merits of TAC+MTX versus CSP+MTX after hematopoietic cell transplantation for acquired aplastic anemia. Prospective studies would be needed to determine whether the use of TAC+MTX is associated with lower risk of mortality in URD recipients with acquired aplastic anemia

Search for leptophobic Z ' bosons decaying into four-lepton final states in proton-proton collisions at root s=8 TeV

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Search for R-parity violating supersymmetry with displaced vertices in proton-proton collisions at root s=8 TeV

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Search for massive resonances decaying in to WW,WZ or ZZ bosons in proton-proton collisions at root s=13 TeV

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Searches for invisible decays of the Higgs boson in pp collisions at root S=7, 8, and 13 TeV

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