769 research outputs found
Synthesis, Electrical Conductivity, and Dielectric Behaviour of Polyaniline Doped with H2SO4; HCl and (HCl + NaNO2) Mixture
Acid doped Polyaniline (PANI) due to their increased electrical conductivity, are considered to be the most promising conducting filler materials. Hence, the present study, reports the synthesis of the PANI followed by acid doping, electrical conductivity and dielectric properties measurements of H2SO4; HCl and (Conc. HCl + NaNO2mixture) doped PANI. In order to know the effect of acetone washing on the electrical properties of acid doped PANI samples, the electrical properties of the non-acetone washed acid doped PANI samples are compared with that of their acetone washed counterparts. The PANI salt was prepared by conventional route using aniline hydrochloride and ammonium persulphate as an oxidant. PANI salt was subjected to 0.5M NaOH to form PANI base, which was further doped separately with H2SO4; HCl and (Conc. HCl + NaNO2mixture) respectively followed by acetone washing. A comparative electrical conductivity study between the acetone washed and unwashed PANI salt and H2SO4, HCl and Conc. HCl + NaNO2 mixture doped PANI were characterized by dielectric and impedance study
Extraction of Scandium (III) from acidic solutions using organo-phosphoric acid reagents: A comparative study
Comparative and synergistic solvent extraction of Sc(III) using two phosphoric acidic reagents such as di-(2-ethyhexyl) phosphoric acid and 2,4,4,tri-methyl,pentyl-phosphinic acid was investigated. Slope analysis method suggests a cation exchange reaction of Sc(III) with both extractants at a molar ratio of extractant: Sc(III) = 2.5:1 at equilibrium pH< 1.5. The plot of log D vs. log [Extractant] yield the slope (n) value as low as 1.2-1.3 and as high as n=7 at low and high extrcatant concentration level, respectively. Extraction isotherm study predicted the need of 2 stages at A: O=1:4 and A: O=1:3 using 0.1 M D2EHPA and 0.1 M Cyanex 272, respectively. Stripping of Sc (III) was carried out at varied NaOH concentration to ascertain the optimum stripping condition for effective enrichment of metal. The predicted stripping condition (2)-stages with A: O=1:3 and 1:4 for D2EHPA and Cyanex 272, respectively) obtained from Mc-Cabe Thiele plot was further validated by 6-cycles CCS study. An actual leach solution of Mg-Sc alloy bearing 1.0 g/L of Sc (III), 2.5 g/L of Mg and 0.2 M HCl was subjected for selective separation of Sc at the optimum condition. The counter current simulation (CCS) study for both extraction and stripping of actual solution resulted quantitative separation of Sc with âź12 fold enrichment. The organic phase before and after loading of Sc (III) along with the diluents was characterized by FTIR to ascertain the phase transportation of Sc (III)
On Neutrino Masses and a Low Breaking Scale of Left-Right Symmetry
In left-right symmetric models (LRSM) the light neutrino masses arise from
two sources: the seesaw mechanism and a VEV of an SU(2) triplet. If the
left-right symmetry breaking, , is low, v_R\lsim15\TeV, the
contributions to the light neutrino masses from both the seesaw mechanism and
the triplet Yukawa couplings are expected to be well above the experimental
bounds. We present a minimal LRSM with an additional U(1) symmetry in which the
masses induced by the two sources are below the eV scale and the two-fold
problem is solved. We further show that, if the U(1) symmetry is also
responsible for the lepton flavor structure, the model yields a small mixing
angle within the first two lepton generations.Comment: 18 pages references added published versio
Lepton Masses and Mixing in a Left-Right Symmetric Model with a TeV-scale Gravity
We construct a left-right symmetric (LRS) model in five dimensions which
accounts naturally for the lepton flavor parameters. The fifth dimension is
described by an orbifold, S_1/Z_2 times Z'_2, with a typical size of order
TeV^{-1}. The fundamental scale is of order 25 TeV which implies that the gauge
hierarchy problem is ameliorated. In addition the LRS breaking scale is of
order few TeV which implies that interactions beyond those of the standard
model are accessible to near future experiments. Leptons of different
representations are localized around different orbifold fixed points. This
explains, through the Arkani-Hamed-Schmaltz mechanism, the smallness of the tau
mass compared to the electroweak breaking scale. An additional U(1) horizontal
symmetry, broken by small parameters, yields the hierarchy in the charged
lepton masses, strong suppression of the light neutrino masses and accounts for
the mixing parameters. The model yields several unique predictions. In
particular, the branching ratio for the lepton flavor violating process mu^-
--> e^+ e^- e^- is comparable with its present experimental sensitivity.Comment: 21 pages, 1 figure, references added, discussion on the
predictiveness of the model in the generic non-universal case added, to
appear in PR
Impact of nanoparticles on amyloid β-induced Alzheimerâs disease, tuberculosis, leprosy and cancer: a systematic review
Nanotechnology is an interdisciplinary domain of science, technology and engineering that deals with nano-sized materials/particles. Usually, the size of nanoparticles lies between 1 and 100 nm. Due to their small size and large surface area-to-volume ratio, nanoparticles exhibit high reactivity, greater stability and adsorption capacity. These important physicochemical properties attract scientific community to utilize them in biomedical field. Various types of nanoparticles (inorganic and organic) have broad applications in medical field ranging from imaging to gene therapy. These are also effective drug carriers. In recent times, nanoparticles are utilized to circumvent different treatment limitations. For example, the ability of nanoparticles to cross the bloodâbrain barrier and having a certain degree of specificity towards amyloid deposits makes themselves important candidates for the treatment of Alzheimerâs disease. Furthermore, nanotechnology has been used extensively to overcome several pertinent issues like drug-resistance phenomenon, side effects of conventional drugs and targeted drug delivery issue in leprosy, tuberculosis and cancer. Thus, in this review, the application of different nanoparticles for the treatment of these four important diseases (Alzheimerâs disease, tuberculosis, leprosy and cancer) as well as for the effective delivery of drugs used in these diseases has been presented systematically. Although nanoformulations have many advantages over traditional therapeutics for treating these diseases, nanotoxicity is a major concern that has been discussed subsequently. Lastly, we have presented the promising future prospective of nanoparticles as alternative therapeutics. In that section, we have discussed about the futuristic approach(es) that could provide promising candidate(s) for the treatment of these four diseases
Search for double beta decay of Zinc and Tungsten with the help of low-background ZnWO4 crystal scintillators
Double beta processes in 64-Zn, 70-Zn, 180-W, and 186-W have been searched
for with the help of large volume (0.1-0.7 kg) low background ZnWO4 crystal
scintillators at the Gran Sasso National Laboratories of the INFN. Total time
of measurements exceeds 10 thousands hours. New improved half-life limits on
double electron capture and electron capture with positron emission in 64-Zn
have been set, in particular (all the limits are at 90% C.L.): T1/2(0nu2EC)>
1.1e20 yr, T1/2(2nuECbeta+)>7.0e20 yr, and T1/2(0nuECbeta+)>4.3e20 yr. The
different modes of double beta processes in 70-Zn, 180-W, and 186-W have been
restricted at the level of 1e17-1e20 yr.Comment: 20 p., submitted to Phys. Rev.
Search for the Lepton Flavor Violation Processes and
The lepton flavor violation processes and are
searched for using a sample of 5.8 events collected with
the BESII detector. Zero and one candidate events, consistent with the
estimated background, are observed in and
decays, respectively. Upper limits on the branching ratios are determined to be
and at the 90% confidence level (C.L.).Comment: 9 pages, 2 figure
Inflation, cold dark matter, and the central density problem
A problem with high central densities in dark halos has arisen in the context
of LCDM cosmologies with scale-invariant initial power spectra. Although n=1 is
often justified by appealing to the inflation scenario, inflationary models
with mild deviations from scale-invariance are not uncommon and models with
significant running of the spectral index are plausible. Even mild deviations
from scale-invariance can be important because halo collapse times and
densities depend on the relative amount of small-scale power. We choose several
popular models of inflation and work out the ramifications for galaxy central
densities. For each model, we calculate its COBE-normalized power spectrum and
deduce the implied halo densities using a semi-analytic method calibrated
against N-body simulations. We compare our predictions to a sample of dark
matter-dominated galaxies using a non-parametric measure of the density. While
standard n=1, LCDM halos are overdense by a factor of 6, several of our example
inflation+CDM models predict halo densities well within the range preferred by
observations. We also show how the presence of massive (0.5 eV) neutrinos may
help to alleviate the central density problem even with n=1. We conclude that
galaxy central densities may not be as problematic for the CDM paradigm as is
sometimes assumed: rather than telling us something about the nature of the
dark matter, galaxy rotation curves may be telling us something about inflation
and/or neutrinos. An important test of this idea will be an eventual consensus
on the value of sigma_8, the rms overdensity on the scale 8 h^-1 Mpc. Our
successful models have values of sigma_8 approximately 0.75, which is within
the range of recent determinations. Finally, models with n>1 (or sigma_8 > 1)
are highly disfavored.Comment: 13 pages, 6 figures. Minor changes made to reflect referee's
Comments, error in Eq. (18) corrected, references updated and corrected,
conclusions unchanged. Version accepted for publication in Phys. Rev. D,
scheduled for 15 August 200
Limit on Tau Neutrino Mass from
From a data sample of 29058
decays observed in the CLEO detector we derive a 95% confidence upper limit on
the tau neutrino mass of 28 MeV.Comment: 17 pages postscript, also available through
http://w4.lns.cornell.edu/public/CLN
Search for a W' boson decaying to a bottom quark and a top quark in pp collisions at sqrt(s) = 7 TeV
Results are presented from a search for a W' boson using a dataset
corresponding to 5.0 inverse femtobarns of integrated luminosity collected
during 2011 by the CMS experiment at the LHC in pp collisions at sqrt(s)=7 TeV.
The W' boson is modeled as a heavy W boson, but different scenarios for the
couplings to fermions are considered, involving both left-handed and
right-handed chiral projections of the fermions, as well as an arbitrary
mixture of the two. The search is performed in the decay channel W' to t b,
leading to a final state signature with a single lepton (e, mu), missing
transverse energy, and jets, at least one of which is tagged as a b-jet. A W'
boson that couples to fermions with the same coupling constant as the W, but to
the right-handed rather than left-handed chiral projections, is excluded for
masses below 1.85 TeV at the 95% confidence level. For the first time using LHC
data, constraints on the W' gauge coupling for a set of left- and right-handed
coupling combinations have been placed. These results represent a significant
improvement over previously published limits.Comment: Submitted to Physics Letters B. Replaced with version publishe
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