Valorisation of 2,5-dimethylfuran over zeolite catalysts studied by on-line FTIR-MS gas phase analysis

The valorisation of 2,5-dimethylfuran (2,5-dmf) by catalytic fast pyrolysis (CFP) was studied by on-line FTIR-MS gas phase analysis. Zeolite beta, H-ZSM-5 and Cu-ZSM-5 were characterised and used as catalysts. The on-line analysis enables sufficient time resolution to follow subminute transient phenomena, e.g., the impact of catalyst pretreatment and time on stream (TOS) on the reaction selectivity. The results show, that the initial selectivity towards benzene, toluene and xylene (BTX) aromatics is high but decreases with TOS while the isomerisation rates of 2,5-dmf towards 2,4-dimethylfuran and cyclic ketones increase. This indicates the involvement of specific active sites for the different conversion processes. The formation of BTX compounds is linked to the availability of specific olefins, as supported by temperature programmed desorption experiments, which is indicative of aromatisation stemming directly from the olefin pool rather than via Diels-Alder reactions

Optical properties of solar absorbers : results on Round Robin and guidelines

ABSTRACT: The scope of the standard ISO 22975-3:2014 is the determination of the long term behavior and service life of selective solar absorbers for use in vented flat plate collectors used in typical solar domestic hot water systems or combisystems. With this scope, this standard can be the basis for the certification of solar absorbers in the framework of Solar Keymark European Certification Scheme. Measurements of optical properties are fundamental to support this certification. Six test laboratories participated in a Round Robin test for the measurement of solar absorptance and thermal emittance of different absorber coatings. The samples used were one PVD coating and two selective paint coatings all on aluminum substrates. The results were submitted anonymously and were analyzed according to standard ISO 13528:2015. The results obtained showed good agreement among the measurements made by the participants and allowed the preparation of guidelines to guarantee quality of the measurements of optical properties of solar absorbers. A proposal to include absorber coatings in the Solar Keymark certification scheme was prepared.info:eu-repo/semantics/acceptedVersio

The interstellar C18O/C17O ratio in the solar neighbourhood: The rho Oph cloud

Observations of up to ten carbon monoxide (CO and isotopomers) transitions are presented to study the interstellar C18O/C17O ratio towards 21 positions in the nearby (d~140pc) low-mass star forming cloud rho Oph. A map of the C18O J=1-0 distribution of parts of the cloud is also shown. An average 12C18O/12C17O isotopomeric ratio of 4.11 +/- 0.14, reflecting the 18O/17O isotope ratio, is derived from Large Velocity Gradient (LVG) calculations. From LTE column densities we derive a ratio of 4.17 +/-0.26. These calculations also show that the kinetic temperature decreases from about 30 K in the cloud envelope to about 10 K in the cloud cores. This decrease is accompanied by an increase of the average molecular hydrogen density from 10^4 cm-3 to >10^5 cm-3. Towards some lines of sight C18O optical depths reach values of order unity.Comment: 13 pages, 9 figures; accepted for publication in A&

Determination of the gas-to-dust ratio in nearby dense clouds using X-ray absorption measurements

We present a comparison of the gas and dust properties of the dense interstellar matter in six nearby star-forming regions (d<500 pc): rho Oph, Cha I, R CrA, IC 348, NGC 1333, and Orion. We measure from Chandra and XMM-Newton observations the X-ray absorption toward pre-main sequence stars (PMS) without accretion disks (i.e., Class III sources) to obtain the total hydrogen column density N_{H,X}. For these sources we take from the literature the corresponding dust extinction in the near-infrared, A_J, or when unavailable we derive it from SED fitting using the available DENIS, 2MASS, ISOCAM and other data. We then compare N_{H,X} and A_J for each object, up to unprecedently high extinction. For the rho Oph dark cloud with a relatively large sample of 20 bona-fide Class III sources, we probe the extinction up to A_J <~ 14 (A_V <~ 45), and find a best-fit linear relation N_{H,X}/A_J = 5.6 (+/- 0.4)x10^{21} cm^{-2} mag^{-1}, adopting standard ISM abundances. The other regions reveal a large dispersion in the N_{H,X}/A_J ratio for each source but for lack of adequate IR data these studies remain limited to moderate extinctions (A_J <~ 1.5 or A_V ~2 sigma) than the galactic value, derived using the standard extinction curve (R_V = 3.1). This result is consistent with the recent downwards revision of the metallicity of the Sun and stars in the solar vicinity. We find that the rho Oph dense cloud has the same metallicity than the local ISM when assuming that the galactic gas-to-dust ratio remains unchanged. The difference between galactic and local values of the gas-to-dust ratio can thus be attributed entirely to a difference in metallicity.Comment: 21 Pages including 12 figures. Accepted for publication in Astronomy and Astrophysic

Response of Sunflower (Helianthus annuus L.) Leaf Surface Defenses to Exogenous Methyl Jasmonate

Helianthus annuus, the common sunflower, produces a complex array of secondary compounds that are secreted into glandular trichomes, specialized structures found on leaf surfaces and anther appendages of flowers. The primary components of these trichome secretions are sesquiterpene lactones (STL), a diverse class of compounds produced abundantly by the plant family Compositae and believed to contribute to plant defense against herbivory. We treated wild and cultivated H. annuus accessions with exogenous methyl jasmonate, a plant hormone that mediates plant defense against insect herbivores and certain classes of fungal pathogens. The wild sunflower produced a higher density of glandular trichomes on its leaves than the cultivar. Comparison of the profiles of glandular trichome extracts obtained by liquid chromatography–mass spectroscopy (LC-MS) showed that wild and cultivated H. annuus were qualitatively similar in surface chemistry, although differing in the relative size and proportion of various compounds detected. Despite observing consistent transcriptional responses to methyl jasmonate treatment, we detected no significant effect on glandular trichome density or LC-MS profile in cultivated or wild sunflower, with wild sunflower exhibiting a declining trend in overall STL production and foliar glandular trichome density of jasmonate-treated plants. These results suggest that glandular trichomes and associated compounds may act as constitutive defenses or require greater levels of stimulus for induction than the observed transcriptional responses to exogenous jasmonate. Reduced defense investment in domesticated lines is consistent with predicted tradeoffs caused by selection for increased yield; future research will focus on the development of genetic resources to explicitly test the ecological roles of glandular trichomes and associated effects on plant growth and fitness

Identification of 12 new susceptibility loci for different histotypes of epithelial ovarian cancer.

To identify common alleles associated with different histotypes of epithelial ovarian cancer (EOC), we pooled data from multiple genome-wide genotyping projects totaling 25,509 EOC cases and 40,941 controls. We identified nine new susceptibility loci for different EOC histotypes: six for serous EOC histotypes (3q28, 4q32.3, 8q21.11, 10q24.33, 18q11.2 and 22q12.1), two for mucinous EOC (3q22.3 and 9q31.1) and one for endometrioid EOC (5q12.3). We then performed meta-analysis on the results for high-grade serous ovarian cancer with the results from analysis of 31,448 BRCA1 and BRCA2 mutation carriers, including 3,887 mutation carriers with EOC. This identified three additional susceptibility loci at 2q13, 8q24.1 and 12q24.31. Integrated analyses of genes and regulatory biofeatures at each locus predicted candidate susceptibility genes, including OBFC1, a new candidate susceptibility gene for low-grade and borderline serous EOC

Using fluorescent probes and FRAP to investigate macromolecule diffusion in steam-exploded wood

Diffusion of fluorescently labeled dextran of varying molecular weight in wood pretreated by steam explosion was studied with a confocal microscope. The steam explosion experiments were conducted at relatively mild conditions relevant for materials biorefinery at a pressure of 14 bars for 10 min. The method of fluorescence recovery after photobleaching (FRAP) was used to perform diffusion measurements locally in the wood microstructure. It was found that the FRAP methodology can be used to observe differences in the diffusion coefficient based on localization in the microstructure, i.e., earlywood, latewood, and cell wall. Microscopic changes due to steam explosion were seen to increase diffusion of the smaller 3-kDa dextran diffusion probe in the earlywood, while the latewood structure was not affected in any significant way. Macroscopic changes to the structure in the form of ruptures due to the steam explosion pretreatment were observed to increase the rate of diffusion for the larger 40-kDa dextran probe