Post-combustion carbon dioxide capture using electrochemically mediated amine regeneration

Electrochemically mediated amine regeneration is a new post-combustion capture technology with the potential to exploit the excellent removal efficiencies of thermal amine scrubbers while reducing parasitic energy losses and capital costs. The improvements result from the use of an electrochemical stripping cycle, in lieu of the traditional thermal swing, to facilitate CO[subscript 2] desorption and amine regeneration; metal cations generated at an anode react with the amines, displacing the CO[subscript 2], which is then flashed off, and the amines are regenerated by subsequent reduction of the metal cations in a cathode cell. The advantages of such a process include higher CO[subscript 2] desorption pressures, smaller absorbers, and lower energy demands. Several example chemistries using different polyamines and copper are presented. Experimental results indicate an open-circuit efficiency of 54% (15 kJ per mole CO[subscript 2]) is achievable at the tested conditions and models predict that 69% efficiency is possible at higher temperatures and pressures. A bench scale system produced 1.6 mL min[superscript −1] CO[subscript 2] while operating at 0.4 volts and 42% Faradaic efficiency; this corresponds to a work of less than 100 kJ per mole.United States. Advanced Research Projects Agency-Energy (Grant DE-AR0000083

Looking at A 0535+26 at low luminosities with NuSTAR

We report on two NuSTAR observations of the HMXB A 0535+26 taken toward the end of its normal 2015 outburst at very low $3-50$ keV luminosities of ${\sim}1.4\times10^{36}$ erg/s and ${\sim}5\times10^{35}$ erg/s which are complemented by 9 Swift observations. The data clearly confirm indications seen in earlier data that the source's spectral shape softens as it becomes fainter. The smooth, exponential rollover at high energies present in the first observation evolves to a much more abrupt steepening of the spectrum at $20-30$ keV. The continuum evolution can be well described with emission from a magnetized accretion column, modeled using the compmag model modified by an additional Gaussian emission component for the fainter observation. Between the two observations, the optical depth changes from $0.75\pm0.04$ to $0.56^{+0.01}_{-0.04}$, the electron temperature remains constant, and there is an indication that the column decreases in radius. Since the energy resolved pulse profiles remain virtually unchanged in shape between the two observations, the emission properties of the accretion column, however, reflect the same accretion regime. This conclusion is also confirmed by our result that the energy of the cyclotron resonant scattering feature (CRSF) at ${\sim}45$ keV is independent of the luminosity, implying that the magnetic field in the region in which the observed radiation is produced is the same in both observations. Finally, we also constrain the evolution of the continuum parameters with rotational phase of the neutron star. The width of the CRSF could only be constrained for the brighter observation. Based on Monte-Carlo simulations of CRSF formation in single accretion columns, its pulse phase dependence supports a simplified fan beam emission pattern. The evolution of the CRSF width is very similar to that of the CRSF depth, which is in disagreement with expectations.Comment: 14 pages, 11 figures, 3 tables, accepted for publication in A&

The HELLAS2XMM Survey. XII. The infrared/sub-millimeter view of an X-ray selected Type 2 quasar at z=2

We present multi-wavelength observations (from optical to sub-millimeter, including Spitzer and SCUBA) of H2XMMJ 003357.2-120038 (also GD158_19), an X-ray selected, luminous narrow-line (Type 2) quasar at z=1.957 selected from the HELLAS2XMM survey. Its broad-band properties can be reasonably well modeled assuming three components: a stellar component to account for the optical and near-IR emission, an AGN component (i.e., dust heated by an accreting active nucleus), dominant in the mid-IR, with an optical depth at 9.7 micron along the line of sight (close to the equatorial plane of the obscuring matter) of tau(9.7)=1 and a full covering angle of the reprocessing matter (torus) of 140 degrees, and a far-IR starburst component (i.e., dust heated by star formation) to reproduce the wide bump observed longward of 70 micron. The derived star-formation rate is about 1500 solar masses per year. The overall modeling indicates that GD158_19 is a high-redshift X-ray luminous, obscured quasar with coeval powerful AGN activity and intense star formation. It is probably caught before the process of expelling the obscuring gas has started, thus quenching the star formation.Comment: 7 pages, 3 figures, 1 table, accepted for publication by MNRA

Dank

Dieser Band vereint Reden, die anlässlich der Verleihung der Bruno Snell-Plakette an den Historiker Prof. Fritz Stern gehalten wurden.This volume brings together speeches made on the occasion of the presentation of the Bruno Snell plaque to the historian Prof. Fritz Stern

Unveiling the oldest and most massive galaxies at very high redshift

(Abridged) This work explores the existence of high redshift massive galaxies unveiled with Spitzer+IRAC, but missed by conventional selection techniques based on optical and near-infrared observations. To this end, we use the multi-wavelength imaging data available for the GOODS-South field, and select a flux-limited sample from the IRAC 3.6um image to m(AB)<23.26. We confine our study to the galaxies undetected by the optical HST+ACS imaging and close to the detection limit of the K-band image (K>23.5 AB). Our selection unveiled 20 galaxies on which we performed a detailed photometric analysis. For each galaxy, we built an SED based on optical-to-8um photometry to estimate the photo-z and to derive the main galaxies physical properties. The majority of the sample sources show degenerate/bimodal solutions for the photometric redshifts (Abridged). These can either be heavily dust-enshrouded (Av~2-4) starbursts at 210^12 Lsun, or massive post-starburst galaxies in the redshift interval 4<z<9 with stellar masses of 10^11 Msun. One galaxy, the only source in our sample with both an X-ray and a 24um detection, might be an extremely massive object at z~8 detected during a post-starburst phase with concomitant QSO activity (although a lower-z solution is not excluded). Our investigation of Spitzer-selected galaxies with very red SEDs and completely undetected in the optical reveals a potential population of massive galaxies at z>4 which appear to include significant AGN emissions. These sources may be the oldest stellar systems at z~4. These, previously unrecognized, optically obscured objects might provide an important contribution to the massive-end (M>10^11 sun) of the high-z stellar mass function and they would almost double it (Abridged).Comment: Accepted for publication in Astronomy and Astrophysic

Tracing the cosmic growth of supermassive black holes to z~3 with Herschel

We study a sample of Herschel selected galaxies within the Great Observatories Origins Deep Survey-South and the Cosmic Evolution Survey fields in the framework of the Photodetector Array Camera and Spectrometer (PACS) Evolutionary Probe project. Starting from the rich multiwavelength photometric data sets available in both fields, we perform a broad-band spectral energy distribution decomposition to disentangle the possible active galactic nucleus (AGN) contribution from that related to the host galaxy. We find that 37 per cent of the Herschel-selected sample shows signatures of nuclear activity at the 99 per cent confidence level. The probability of revealing AGN activity increases for bright (L 1−1000 > 10 11 L ? ) star-forming galaxies at z > 0.3, becoming about 80 per cent for the brightest (L 1−1000 > 10 12 L ? ) Infrared (IR) galaxies at z≥1. Finally, we reconstruct the AGN bolometric luminosity function and the supermassive black hole growth rate across cosmic time up to z ∼ 3 from a far-IR perspective. This work shows general agreement with most of the panchromatic estimates from the literature, with the global black hole growth peaking at z ∼ 2 and reproducing the observed local black hole mass density with consistent values of the radiative efficiency Erad (∼0.07)

The \u3cem\u3eChlamydomonas\u3c/em\u3e Genome Reveals the Evolution of Key Animal and Plant Functions

Chlamydomonas reinhardtii is a unicellular green alga whose lineage diverged from land plants over 1 billion years ago. It is a model system for studying chloroplast-based photosynthesis, as well as the structure, assembly, and function of eukaryotic flagella (cilia), which were inherited from the common ancestor of plants and animals, but lost in land plants. We sequenced the ∼120-megabase nuclear genome of Chlamydomonas and performed comparative phylogenomic analyses, identifying genes encoding uncharacterized proteins that are likely associated with the function and biogenesis of chloroplasts or eukaryotic flagella. Analyses of the Chlamydomonas genome advance our understanding of the ancestral eukaryotic cell, reveal previously unknown genes associated with photosynthetic and flagellar functions, and establish links between ciliopathy and the composition and function of flagella

Obscured and powerful AGN and starburst activities at z~3.5

We report the discovery of two sources at z=3.867 and z=3.427 that exhibit powerful starburst and AGN activities. They benefit from data from radio to X rays from the CFHTLS-D1/SWIRE/XMDS surveys. Follow-up optical and near-infrared spectroscopy, and millimeter IRAM/MAMBO observations are also available. We performed an analysis of their spectral energy distributions to understand the origin of their emission and constrain their luminosities. A comparison with other composite systems at similar redshifts from the literature is also presented. The AGN and starburst bolometric luminosities are ~10^13 Lsun. The AGN emission dominates at X ray, optical, mid-infrared wavelengths, and probably in the radio. The starburst emission dominates in the far-infrared. The estimated star formation rates range from 500 to 3000Msun/yr. The AGN near-infrared and X ray emissions are heavily obscured in both sources with an estimated dust extinction Av>4, and Compton-thick gas column densities. The two sources are the most obscured and most luminous AGNs detected at millimeter wavelengths currently known. The sources presented in this work are heavily obscured QSOs, but their properties are not fully explained by the standard AGN unification model. In one source, the ultraviolet and optical spectra suggest the presence of outflowing gas and shocks, and both sources show emission from hot dust, most likely in the vicinity of the nucleus. Evidence of moderate AGN-driven radio activity is found in both sources. The two sources lie on the local M_BH-M_bulge relation. To remain on this relation, their star formation rate has to decrease. Our results support evolutionary models that invoke radio feedback as star formation quenching mechanism, and suggest that such a mechanism might play a major role also in powerful AGNs.Comment: Accepted for publication in Astronomy & Astrophysics (12 pages; 6 figures); replaced version includes minor language editing and revised reference