1,631 research outputs found
Synthesis and Characterization of CoMo/Al2O3-MgO-(X) catalysts doped with alkaline oxides (K, Li)
CoMo catalysts were prepared using Al2O3-MgO-(X) hybrid supports, where X = K2O or Li2O. The textural, structural and acid-base properties of these materials were characterized by several techniques. The catalysts were preliminarily evaluated in the hydrodesulfurization (HDS), hydrogenation (HYD) and hydrocracking (HCK) model reactions. The aims of this work are to identify the effect of the addition of an alkaline oxide (either K2O or Li2O) to the Lewis acid sites in the CoMo/Al2O3-MgO formulation; and on the other hand, to establish a relationship between the acidity and the catalytic performance (hydrogenation function). The results obtained from the pyridine thermodesorption analysis and the n-butyl amine titration techniques show that the incorporation of an alkaline oxide to the CoMo/Al2O3-MgO formulation causes a slight decrease in the total number of acid sites (TNAS) with respect to Al2O3 and the Al2O3-MgO hybrid supports. Both the enhanced textural and structural stability of the CoMo/Al2O3-MgO-(X) catalytic formulations, which could be probably attributed to the incorporation of Li or K cations to the MgO framework, stabilizing it, can also be observed. As for the catalytic performance, the CoMo/Al2O3-MgO-(X) catalysts containing either Li2O or K2O, show a decrease in both the HYD and HYC conversions; however, the formulation containing Li2O shows the best catalytic behavior due to both the low n-octane yield and the low hydrocracking activity
Wide-Field Survey of Emission-line Stars in IC 1396
We have made an extensive survey of emission-line stars in the IC 1396 HII
region to investigate the low-mass population of pre-main sequence (PMS) stars.
A total of 639 H-alpha emission-line stars were detected in an area of 4.2
deg^2 and their i'-photometry was measured. Their spatial distribution exhibits
several aggregates near the elephant trunk globule (Rim A) and bright-rimmed
clouds at the edge of the HII region (Rim B and SFO 37, 38, 39, 41), and near
HD 206267, which is the main exciting star of the HII region. Based on the
extinction estimated from the near-infrared (NIR) color-color diagram, we have
selected pre-main sequence star candidates associated with IC 1396. The age and
mass were derived from the extinction corrected color-magnitude diagram and
theoretical pre-main sequence tracks. Most of our PMS candidates have ages of <
3 Myr and masses of 0.2-0.6 Mo. Although it appears that only a few stars were
formed in the last 1 Myr in the east region of the exciting star, the age
difference among subregions in our surveyed area is not clear from the
statistical test. Our results may suggest that massive stars were born after
the continuous formation of low-mass stars for 10 Myr. The birth of the
exciting star could be the late stage of slow but contiguous star formation in
the natal molecular cloud. It may have triggered to form many low-mass stars at
the dense inhomogeneity in and around the HII region by a radiation-driven
implosion.Comment: 48 pages, 12 figures, 5 tables, accepted for publication in A
Mid-Infrared Variability of protostars in IC 1396A
We have used Spitzer/IRAC to conduct a photometric monitoring program of the
IC1396A dark globule in order to study the mid-IR (3.6 - 8 micron) variability
of the heavily embedded Young Stellar Objects (YSOs) present in that area. We
obtained light curves covering a 14 day timespan with a twice daily cadence for
69 YSOs, and continuous light curves with approximately 12 second cadence over
7 hours for 38 YSOs. Typical accuracies for our relative photometry were 1-2%
for the long timespan data and a few mmag, corresponding to less than 0.5%, for
the 7 hour continuous "staring-mode" data. More than half of the YSOs showed
detectable variability, with amplitudes from ~0.05 mag to ~0.2 mag. About
thirty percent of the YSOs showed quasi-sinusoidal light curve shapes with
apparent periods from 5-12 days and light curve amplitudes approximately
independent of wavelength over the IRAC bandpasses. We have constructed models
which simulate the time dependent spectral energy distributions of Class I and
I I YSOs in order to attempt to explain these light curves. Based on these
models, the apparently periodic light curves are best explained by YSO models
where one or two high latitude photospheric spots heat the inner wall of the
circumstellar disk, and where we view the disk at fairly large inclination
angle. Disk inhomogeneities, such as increasing the height where the accretion
funnel flows to the stellar hotspot, enhances the light curve modulations. The
other YSOs in our sample show a range of light curve shapes, some of which are
probably due to varying accretion rate or disk shadowing events. One star,
IC1396A-47, shows a 3.5 hour periodic light curve; this object may be a PMS
Delta Scuti star
A Possible Detection of Occultation by a Proto-planetary Clump in GM Cephei
GM Cep in the young (~4 Myr) open cluster Trumpler 37 has been known to be an
abrupt variable and to have a circumstellar disk with very active accretion.
Our monitoring observations in 2009-2011 revealed the star to show sporadic
flare events, each with brightening of < 0.5 mag lasting for days. These
brightening events, associated with a color change toward the blue, should
originate from an increased accretion activity. Moreover, the star also
underwent a brightness drop of ~1 mag lasting for about a month, during which
the star became bluer when fainter. Such brightness drops seem to have a
recurrence time scale of a year, as evidenced in our data and the photometric
behavior of GM Cep over a century. Between consecutive drops, the star
brightened gradually by about 1 mag and became blue at peak luminosity. We
propose that the drop is caused by obscuration of the central star by an
orbiting dust concentration. The UX Orionis type of activity in GM Cep
therefore exemplifies the disk inhomogeneity process in transition between
grain coagulation and planetesimal formation in a young circumstellar disk.Comment: In submission to the Astrophysical Journal, 4 figure
Changes in Oxidative Status Biomarkers in Saliva and Serum in the Equine Gastric Ulcer Syndrome and Colic of Intestinal Aetiology : a Pilot Study
Altres ajuts: Gobierno Regional Murcia, programa Séneca 19894/GERM/15Changes in the oxidative status of the blood of horses suffering from gastric ulcers and colic of intestinal aetiology (CIE) have been reported. However, saliva can also be a source of biomarkers of oxidative status. Therefore, this study aims to validate automated assays for the measurement of oxidative status biomarkers (ferric reducing ability of saliva/serum-FRAS/FRAP, cupric reducing antioxidant capacity-CUPRAC, the Trolox equivalent antioxidant capacity-TEAC, uric acid, and advanced oxidation protein products-AOPP) in the saliva and serum of horses, to assess their changes in the different ulcer gastric diseases (squamous-ESGD and glandular-EGGD) and CIE, and to evaluate their relationship with serum amyloid A (SAA), adenosine deaminase (ADA), and the systemic inflammatory response syndrome (SIRS) status. The assays showed a low imprecision and good linearity with enough sensitivity in both fluids. In EGGD, higher levels of FRAS, uric acid, and AOPP in saliva were observed compared to the healthy group, correlating with the salivary ADA levels. Horses with CIE showed increases in uric acid concentrations in serum associated with their SIRS status and outcome of the disease. In conclusion, analytes related to the oxidative status can be measured in the saliva and serum from horses by automated assays, and some of them can potentially be assessed as biomarkers in horses with gastric ulcers and CIE
The Long-Lived Disks in the Eta Chamaeleontis Cluster
We present IRS spectra and revised MIPS photometry for the 18 members of the
Eta Chamaeleontis cluster. Aged 8 Myr, the Eta Cha cluster is one of the few
nearby regions within the 5-10 Myr age range, during which the disk fraction
decreases dramatically and giant planet formation must come to an end. For the
15 low-mass members, we measure a disk fraction ~50%, high for their 8 Myr age,
and 4 of the 8 disks lack near-IR excesses, consistent with the empirical
definition of "transition'' disks. Most of the disks are comparable to
geometrically flat disks. The comparison with regions of different ages
suggests that at least some of the "transition" disks may represent the normal
type of disk around low-mass stars. Therefore, their flattened structure and
inner holes may be related to other factors (initial masses of the disk and the
star, environment, binarity), rather than to pure time evolution. We analyze
the silicate dust in the disk atmosphere, finding moderate crystalline
fractions (~10-30%) and typical grain sizes ~1-3 micron, without any
characteristic trend in the composition. These results are common to other
regions of different ages, suggesting that the initial grain processing occurs
very early in the disk lifetime (<1 Myr). Large grain sizes in the disk
atmosphere cannot be used as a proxy for age, but are likely related to higher
disk turbulence. The dust mineralogy varies between the 8-12micron and the
20-30 micron features, suggesting high temperature dust processing and little
radial mixing. Finally, the analysis of IR and optical data on the B9 star Eta
Cha reveals that it is probably surrounded by a young debris disk with a large
inner hole, instead of being a classical Be star.Comment: 35 pages, 6 tables, 8 figures; Accepted by Ap
Excess Higgs Production in Neutralino Decays
The ATLAS and CMS experiments have recently claimed discovery of a Higgs
boson-like particle at ~5 sigma confidence and are beginning to test the
Standard Model predictions for its production and decay. In a variety of
supersymmetric models, a neutralino NLSP can decay dominantly to the Higgs and
the LSP. In natural SUSY models, a light third generation squark decaying
through this chain can lead to large excess Higgs production while evading
existing BSM searches. Such models can be observed at the 8 TeV LHC in channels
exploiting the rare diphoton decays of the Higgs produced in the cascade decay.
Identifying a diphoton resonance in association with missing energy, a lepton,
or b-tagged jets is a promising search strategy for discovery of these models,
and would immediately signal new physics involving production of a Higgs boson.
We also discuss the possibility that excess Higgs production in these SUSY
decays can be responsible for enhancements of up to 50% over the SM prediction
for the observed rate in the existing inclusive diphoton searches, a scenario
which would likely by the end of the 8 TeV run be accompanied by excesses in
the diphoton + lepton/MET and SUSY multi-lepton/b searches and a potential
discovery in a diphoton + 2b search.Comment: 42 pages, 19 figure
Search for the standard model Higgs boson in the H to ZZ to 2l 2nu channel in pp collisions at sqrt(s) = 7 TeV
A search for the standard model Higgs boson in the H to ZZ to 2l 2nu decay
channel, where l = e or mu, in pp collisions at a center-of-mass energy of 7
TeV is presented. The data were collected at the LHC, with the CMS detector,
and correspond to an integrated luminosity of 4.6 inverse femtobarns. No
significant excess is observed above the background expectation, and upper
limits are set on the Higgs boson production cross section. The presence of the
standard model Higgs boson with a mass in the 270-440 GeV range is excluded at
95% confidence level.Comment: Submitted to JHE
Search for anomalous t t-bar production in the highly-boosted all-hadronic final state
A search is presented for a massive particle, generically referred to as a
Z', decaying into a t t-bar pair. The search focuses on Z' resonances that are
sufficiently massive to produce highly Lorentz-boosted top quarks, which yield
collimated decay products that are partially or fully merged into single jets.
The analysis uses new methods to analyze jet substructure, providing
suppression of the non-top multijet backgrounds. The analysis is based on a
data sample of proton-proton collisions at a center-of-mass energy of 7 TeV,
corresponding to an integrated luminosity of 5 inverse femtobarns. Upper limits
in the range of 1 pb are set on the product of the production cross section and
branching fraction for a topcolor Z' modeled for several widths, as well as for
a Randall--Sundrum Kaluza--Klein gluon. In addition, the results constrain any
enhancement in t t-bar production beyond expectations of the standard model for
t t-bar invariant masses larger than 1 TeV.Comment: Submitted to the Journal of High Energy Physics; this version
includes a minor typo correction that will be submitted as an erratu
Measurement of the t t-bar production cross section in the dilepton channel in pp collisions at sqrt(s) = 7 TeV
The t t-bar production cross section (sigma[t t-bar]) is measured in
proton-proton collisions at sqrt(s) = 7 TeV in data collected by the CMS
experiment, corresponding to an integrated luminosity of 2.3 inverse
femtobarns. The measurement is performed in events with two leptons (electrons
or muons) in the final state, at least two jets identified as jets originating
from b quarks, and the presence of an imbalance in transverse momentum. The
measured value of sigma[t t-bar] for a top-quark mass of 172.5 GeV is 161.9 +/-
2.5 (stat.) +5.1/-5.0 (syst.) +/- 3.6(lumi.) pb, consistent with the prediction
of the standard model.Comment: Replaced with published version. Included journal reference and DO
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