Effects of irrigation water qualities on biomass and sugar contents of sugar beet and sweet sorghum cultivars

Abstract: An experiment involving four qualities of irrigation water, two sugar beet and three sweet sorghum cultivars was conducted in a split plot design with four replications at Rudasht Drainage and Reclamation Experiment Station in 1999. The results showed salinity of water has an adverse effect on sugar beet and sweet sorghum biomass. Sweet sorghum cultivar SSV108 had the lowest biomass under all qualities of irrigation water. Sweet sorghum cultivar Rio had the maximum biomass with water qualities of 2, 5, and 8 dS m. . The effect of irrigation water quality was not significant for sugar characteristics such as brix, pol and purity. However, responses of cultivars on the above parameters were significant and sugar beet cultivars had higher brix, pol and purity and lower invert sugar and starch than sweet sorghum cultivars. In conclusion, sweet sorghum cultivars are not recommended to be irrigated with saline water of more than 8 dS m -1 for sugar production. Under such condition, they may be suitable to be grown for forage purposes

Cadmium, Lead and Arsenic Remediation in Urban Wastewater by Sorghum Bicolor L.

The use of wastewater and gray water for agribusiness is recently growing, and it is essential to investigate the risks associated with its use. Heavy metals in wastewater, even in small quantities, are among problems limiting the use of wastewater in agriculture. This is due to the high agglomeration coefficient in the environment, degradability and long shelf-life which cause the severity of toxicity and contamination of the soil during irrigation. In this regard, the  Phytoremediation technology can be advantageous due to its environmental compatibility and environmental refining power. In order to investigate the power of sweet sorghum, urban wastewater was used to irrigate the plant.  First, wastewater was analyzed in terms of 38 factors. By adding cadmium, lead and arsenic to wastewater, three treatments of 0.1, 1 and 10 mg/l of these metals were created in urban wastewater and for 12 weeks the respective pots were irrigated with appropriate replication. Samples of root, stem, leaf, seed, soil and drainage of pots were collected separately for analysis of acid digestion and grafting to the atomic absorption system and the results were compared by statistical methods. The results showed that accumulation of cadmium and lead in sorghum is more than ten times higher than that of arsenic. On the other hand, the absorption coefficient or ability of the plant to absorb the elements has decreased rapidly for cadmium and lead with increasing concentration in the soil. In the case of arsenic, the absorption coefficient increased with increasing concentration in the soil. Regarding the amount of material accumulation, the ability of all tissues in the accumulation of cadmium and lead was the same and in the case of arsenic, the root accumulated more than aerial parts. This study showed that the heavy metals accumulation pattern in sorghum, the final amount of accumulation, the absorption coefficient and its changes relative to the environmental concentration are different for various elements. According to the final concentration of accumulation and absorption coefficient, the sorghum plant is suitable for the purification of cadmium and lead from low concentration effluents which are commonly found in urban wastewater. This can prevent the accumulation of these pollutants in soil

Synthesis, structural and chemosensitivity studies of arena d6 metal complexes having N-phenyl-N'-(pyridyl/pyrimidyl) thiourea derivatives

The d6 metal complexes of thiourea derivatives were synthesized to investigate its cytotoxicity. Treatment of various N‐phenyl‐N ́ pyridyl/pyrimidyl thiourea ligands with half‐sandwich d6 metal precursors yielded a series of cationic com- plexes. Reactions of ligand (L1‐L3) with [(p‐cymene)RuCl2]2 and [Cp*MCl2]2 (M = Rh/Ir) led to the formation of a series of cationic complexes bearing gen- eral formula [(arene)M(L1)к2(N,S)Cl]+, [(arene)M(L2)к2(N,S)Cl]+ and [(arene) M(L3)к2(N,S)Cl]+ [arene = p‐cymene, M = Ru (1, 4, 7); Cp*, M = Rh (2, 5, 8); Cp*, Ir (3, 6, 9)]. These compounds were isolated as their chloride salts. X‐ray crystallographic studies of the complexes revealed the coordination of the ligands to the metal in a bidentate chelating N,S‐ manner. Further the cytotox- icity studies of the thiourea derivatives and its complexes evaluated against HCT‐116 (human colorectal cancer), MIA‐PaCa‐2 (human pancreatic cancer) and ARPE‐19 (non‐cancer retinal epithelium) cancer cell lines showed that the thiourea ligands displayed no activity. Upon complexation however, the metal compounds possesses cytotoxicity and whilst potency is less than cisplatin, several complexes exhibited greater selectivity for HCT‐116 or MIA‐ PaCa‐2 cells compared to ARPE‐19 cells than cisplatin in vitro. Rhodium complexes of thiourea derivatives were found to be more potent as compared to ruthenium and iridium complexes.<br/

Análisis sistémico de las externalidades del mercado de bioetanol

Trabajo de investigaciónEn Colombia a partir de la resolución 40108 de 2018, se aumentó el porcentaje de mezcla del combustibles llegando a un 10% (90% combustibles fósiles 10% biocombustibles), actualmente para suplir esta demanda, las productoras de bioetanol requieren emplear al 100% su capacidad instalada, mejorar sus prácticas de cultivo de caña de azúcar y hacer uso de nuevas hectáreas, por tanto, el presente trabajo de grado tiene como objetivo realizar un análisis sistémico de las externalidades del mercado de bioetanol.INTRODUCCIÓN 1. Formulación del trabajo 2. Marco referencial 3. Diagrama propuesto 4. Conclusiones generales BibliografiaPregradoEconomist

Sweet Sorghum Planting Effects on Stalk Yield and Sugar Quality in Semi-Arid Tropical Environment

Sweet sorghum [Sorghum bicolor (L.) Moench] has potential as a bioenergy crop for producing food, fiber, and fermentable sugar. Unlike dryland grain sorghum, little information is available on the influence of staggered planting and genotypes, especially in semiarid tropical environments. The objectives of the present study were (i) to quantify the effects of planting time and genotype on stalk and biomass yields, juice sugar quality, and (ii) to identify the most productive genotypes and planting windows for sustainable feedstock supply. Four commercial sweet sorghum genotypes (SSV84, SSV74, CSV19SS, and CSH22SS) were planted on five planting dates (1 June, 16 June, 1 July, 16 July, and 1 August) during the rainy (June–October) season of 2008 and 2009 in Hyderabad (17°27´ N, 78°28´ E), India. Planting in early and mid-June produced significantly (P ≤ 0.05) higher fresh stalk yield and grain yield than later planting dates. Commercial hybrid CSH22SS produced significantly more stalk, grain, sugar, and ethanol yield over genotypes SSV84 or SSV74. Based on the stalk yield, juice sugar quality, sugar, and ethanol yields, the optimum planting dates for sweet sorghum in semiarid tropical climate is early June to early July. Planting sweet sorghum during this time allows more feedstock to be harvested and hence extends the period for sugar mill operation by about 1 mo, that is, from the first to the last week of October

Hypoxia Sensitive Metal β-Ketoiminate Complexes Showing Induced Single Strand DNA Breaks and Cancer Cell Death by Apoptosis

A series of ruthenium and iridium complexes have been synthesised and characterised with 20 novel crystal structures discussed. The library of β-ketoiminate complexes has been shown to be active against MCF-7 (human breast carcino-ma), HT-29 (human colon carcinoma), A2780 (human ovarian carcinoma) and A2780cis (cisplatin resistant human ovarian carcinoma) cell lines, with selected complexes being more than three times as active as cisplatin against the A2780cis cell line. Complexes have also been shown to be highly active under hypoxic conditions, with the activities of some complexes increasing with a decrease in O2 concentration. The enzyme thioredoxin reductase is over-expressed in cancer cells and complexes reported herein have the advantage of inhibiting this enzyme, with IC50 values measured in the nanomolar range. The anti-cancer activity of these complexes was further investigated to determine whether activity is due to effects on cellular growth or cell survival. The complexes were found to induce significant cancer cell death by apoptosis with levels induced correlating closely with activity in chemosensitivity studies. As a possible cause of cell death, the ability of the complexes to induce damage to cellular DNA was also assessed. The complexes failed to induce double strand DNA break or DNA crosslinking but induced significant levels of single DNA strand breaks indi-cating a different mechanism of action to cisplatin

Contrasting anticancer activity of half-sandwich iridium(III) complexes bearing functionally diverse 2-phenylpyridine ligands

We report the synthesis, characterization, and antiproliferative activity of 15 iridium(III) half-sandwich complexes of the type [(η5-Cp*)Ir(2-(R′-phenyl)-R-pyridine)Cl] bearing either an electron-donating (−OH, −CH2OH, −CH3) or electron-withdrawing (−F, −CHO, −NO2) group at various positions on the 2-phenylpyridine (2-PhPy) chelating ligand giving rise to six sets of structural isomers. The X-ray crystal structures of [(η5-Cp*)Ir(2-(2′-fluorophenyl)pyridine)Cl] (1) and [(η5-Cp*)Ir(2-(4′-fluorophenyl)pyridine)Cl] (2) exhibit the expected “piano-stool” configuration. DFT calculations showed that substituents caused only localized effects on the electrostatic potential surface of the chelating 2-PhPy ligand of the complexes. Hydrolysis of all complexes is rapid, but readily reversed by addition of NaCl. The complexes show preferential binding to 9-ethylguanine over 9-methyladenine and are active catalysts for the oxidation of NADH to NAD+. Antiproliferative activity experiments in A2780 ovarian, MCF-7 breast, A549 lung, and HCT116 colon cancer cell lines showed IC50 values ranging from 1 to 89 μM, with the most potent complex, [(η5-Cp*)Ir(2-(2′-methylphenyl)pyridine)Cl] (13) (A2780 IC50 = 1.18 μM), being 10× more active than the parent, [(η5-Cp*)Ir(2-phenylpyridine)Cl], and 2× more active than [(η5-CpxPh)Ir(2-phenylpyridine)Cl]. Intriguingly, contrasting biological activities are observed between structural isomers despite exhibiting similar chemical reactivity. For pairs of structural isomers both the nature and position of the functional group can affect the hydrophobicity of the complex. An increase in hydrophobicity resulted in enhanced cellular-iridium accumulation in A2780 ovarian cells, which generally gave rise to an increase in potency. The structural isomers [(η5-Cp*)Ir(2-(4′-fluorophenyl)pyridine)Cl] (2) and [(η5-Cp*)Ir(2-phenyl-5-fluoropyridine)Cl] (4) preferentially localized in the cytosol > membrane and particulate > nucleus > cytoskeleton. This work highlights the strong dependence of biological behavior on the nature and position of the substituent on the chelating ligand and shows how this class of organometallic anticancer complexes can be fine-tuned to increase their potency without using extended cyclopentadienyl systems