Numerical analysis of influencing factors on wave load for an amphibious aircraft

Numerical method of wave load for an amphibious aircraft is carried out in this paper, and its effectiveness is verified by comparing with towing tank model test. It shows that at the same wavelength and speed, the aircraft’s wave load is positively correlated with the change of wave height, but with the increase of wavelength, the difference shows a gradually decrease. And wave load is positively correlated with the speed, the greater the speed, the greater the wave load is. The wave load decreases with the increase of the wavelength. The peak load generally occurs in the short wave state of 1.2 times the length of the fuselage. With the increase of the wavelength, the aircraft load gradually decreases

Subsurface A-site vacancy activates lattice oxygen in perovskite ferrites for methane anaerobic oxidation to syngas

Abstract Tuning the oxygen activity in perovskite oxides (ABO3) is promising to surmount the trade-off between activity and selectivity in redox reactions. However, this remains challenging due to the limited understanding in its activation mechanism. Herein, we propose the discovery that generating subsurface A-site cation (Lasub.) vacancy beneath surface Fe-O layer greatly improved the oxygen activity in LaFeO3, rendering enhanced methane conversion that is 2.9-fold higher than stoichiometric LaFeO3 while maintaining high syngas selectivity of 98% in anaerobic oxidation. Experimental and theoretical studies reveal that absence of Lasub.-O interaction lowered the electron density over oxygen and improved the oxygen mobility, which reduced the barrier for C-H bond cleavage and promoted the oxidation of C-atom, substantially boosting methane-to-syngas conversion. This discovery highlights the importance of A-site cations in modulating electronic state of oxygen, which is fundamentally different from the traditional scheme that mainly credits the redox activity to B-site cations and can pave a new avenue for designing prospective redox catalysts