The Initial Study of Polyaniline with Manganese Oxides for Electrochemical Capacitors

AbstractConducting polymers have been found to be promising as electrode material in energy storage devices such as electrochemical capacitors due to they have good capacitance and relatively high charge/discharge rates, giving rise to higher energy and power density than carbon-based electrochemical capacitors. Furthermore, they have good chemical stability, high conductivity and are easy to manufacture. The excellent performance of conducting polymers is due to their pseudocapacitive charge storage mechanism. Polyaniline (PANI) is one of candidate of conducting polymer has been used as material in this field; however, there are some drawbacks to using conducting polymers as the electroactive material. Therefore, conducting polymers require presence of another material which has good mechanical and electrochemical behavior to address those problems. Manganese oxides have good electrochemical performance by themselves, and are therefore an excellent candidate for forming a composite with conducting polymers. Desirable characteristics of manganese oxides include that they are abundant, low cost, and have high specific capacitance. An initial study of the electrodeposition behavior of polyaniline-manganese oxides thin film was investigated using linear sweep voltammetry (LSV), chronoamperometry (CA), and cyclic voltammetry (CV). Based on the result of experiments, Mn-modified PANI thin films have been shown to be promising materials for electrochemical capacitors electrodes

Synthetic prions generated in vitro are similar to a newly identified subpopulation of PrPSc from sporadic Creutzfeldt-Jakob disease

In recent studies, the amyloid form of recombinant prion protein (PrP) encompassing residues 89–230 (rPrP 89-230) produced in vitro induced transmissible prion disease in mice. These studies showed that unlike “classical” PrPSc produced in vivo, the amyloid fibrils generated in vitro were more proteinase-K sensitive. Here we demonstrate that the amyloid form contains a proteinase K-resistant core composed only of residues 152/153–230 and 162–230. The PK-resistant fragments of the amyloid form are similar to those observed upon PK digestion of a minor subpopulation of PrPSc recently identified in patients with sporadic Creutzfeldt-Jakob disease (CJD). Remarkably, this core is sufficient for self-propagating activity in vitro and preserves a β-sheet-rich fibrillar structure. Full-length recombinant PrP 23-230, however, generates two subpopulations of amyloid in vitro: One is similar to the minor subpopulation of PrPSc, and the other to classical PrPSc. Since no cellular factors or templates were used for generation of the amyloid fibrils in vitro, we speculate that formation of the subpopulation of PrPSc with a short PK-resistant C-terminal region reflects an intrinsic property of PrP rather than the influence of cellular environments and/or cofactors. Our work significantly increases our understanding of the biochemical nature of prion infectious agents and provides a fundamental insight into the mechanisms of prions biogenesis

Biochar-based fertilizer: Supercharging root membrane potential and biomass yield of rice

Biochar-based compound fertilizers (BCF) and amendments have proven to enhance crop yields and modify soil properties (pH, nutrients, organic matter, structure etc.) and are now in commercial production in China. While there is a good understanding of the changes in soil properties following biochar addition, the interactions within the rhizosphere remain largely unstudied, with benefits to yield observed beyond the changes in soil properties alone. We investigated the rhizosphere interactions following the addition of an activated wheat straw BCF at an application rates of 0.25% (g·g−1 soil), which could potentially explain the increase of plant biomass (by 67%), herbage N (by 40%) and P (by 46%) uptake in the rice plants grown in the BCF-treated soil, compared to the rice plants grown in the soil with conventional fertilizer alone. Examination of the roots revealed that micron and submicron-sized biochar were embedded in the plaque layer. BCF increased soil Eh by 85 mV and increased the potential difference between the rhizosphere soil and the root membrane by 65 mV. This increased potential difference lowered the free energy required for root nutrient accumulation, potentially explaining greater plant nutrient content and biomass. We also demonstrate an increased abundance of plant-growth promoting bacteria and fungi in the rhizosphere. We suggest that the redox properties of the biochar cause major changes in electron status of rhizosphere soils that drive the observed agronomic benefits

Thermal stability of biochar and its effects on cadmium sorption capacity

In this study, the thermal stability of a wood shaving biochar (WS, 650 °C), a chicken litter biochar (CL, 550 °C) and an activated carbon (AC, 1100 °C) were evaluated by combustion at 375 °C for 24 h to remove the labile non-carbonized organic matter. Results showed that WS and CL biochars were not thermally stable and can lose most of the organic C during combustion. The combusted WS and CL biochars retained considerable amounts of negative charge and displayed higher sorption for Cd (from 5.46 to 68.9 mg/g for WS and from 48.5 to 60.9 mg/g for CL). The AC retained 76.5% of its original C and became more negatively chargely after combustion, but its sorption for Cd slightly decreased (from 18.5 to 14.9 mg/g). This study indicated that after potential burning in wildfires (200 - 500 °C), biochars could have higher sorption capacity for metals by remaining minerals

Biochar and its importance on nutrient dynamics in soil and plant

Biochar, an environmentally friendly soil conditioner, is produced using several thermochemical processes. It has unique characteristics like high surface area, porosity, and surface charges. This paper reviews the fertilizer value of biochar, and its effects on soil properties, and nutrient use efficiency of crops. Biochar serves as an important source of plant nutrients, especially nitrogen in biochar produced from manures and wastes at low temperature (≤ 400 °C). The phosphorus, potassium, and other nutrient contents are higher in manure/waste biochars than those in crop residues and woody biochars. The nutrient contents and pH of biochar are positively correlated with pyrolysis temperature, except for nitrogen content. Biochar improves the nutrient retention capacity of soil, which depends on porosity and surface charge of biochar. Biochar increases nitrogen retention in soil by reducing leaching and gaseous loss, and also increases phosphorus availability by decreasing the leaching process in soil. However, for potassium and other nutrients, biochar shows inconsistent (positive and negative) impacts on soil. After addition of biochar, porosity, aggregate stability, and amount of water held in soil increase and bulk density decreases. Mostly, biochar increases soil pH and, thus, influences nutrient availability for plants. Biochar also alters soil biological properties by increasing microbial populations, enzyme activity, soil respiration, and microbial biomass. Finally, nutrient use efficiency and nutrient uptake improve with the application of biochar to soil. Thus, biochar can be a potential nutrient reservoir for plants and a good amendment to improve soil properties

Signal sequence insufficiency contributes to neurodegeneration caused by transmembrane prion protein

Improving the efficiency of PrP translocation into the ER decreases levels of transmembrane bound protein and rescues mice from prion disease

Disruption of long-term effusive-explosive activity at Santiaguito, Guatemala

Rapid transitions in eruptive activity during lava dome eruptions pose significant challenges for monitoring and hazard assessment. A comprehensive understanding of the dynamic evolution of active lava dome systems requires extensive sets of multi-parametric datasets to fully constrain and understand shifts in eruptive behavior, but few such datasets have been compiled. The Santiaguito lava dome complex, Guatemala, is a remarkable example of an open-vent volcanic system where continuous eruptive activity has typically been characterized by cycles of effusion and frequent, small to moderate, gas-and-ash explosions. During 2015–2016 the volcano experienced a rapid intensification of activity including large vulcanian explosions, frequently accompanied by pyroclastic density currents. Here we present a chronology of the eruptive activity at Santiaguito from November 2014–May 2017, compiled from field observations (visual and thermal) and activity reports. We also present seismic and acoustic infrasound data collected during the same period, the longest and largest dataset collected at Santiaguito to date. Three major phases of eruptive activity took place during the study period. The first phase was consistent with the long-term eruptive behavior reported at Santiaguito by previous studies: lava effusion simultaneous with small (<1 km plume height), regular (25–200 min intervals), gas-and-ash explosions. The second phase from July 2015 to September 2016 was defined by large (<5–7 km plume height) vulcanian explosions at irregular intervals and often accompanied by pyroclastic density currents. The third phase was marked by a return to effusive activity in October 2016 interspersed by small, gas-rich explosions. Over 6,000 explosive events were recorded by seismic and infrasound during the study period and clearly delineate the three phases of activity at the volcano. Furthermore, we present the first documented geophysical evidence of explosion blast waves and volcano-tectonic earthquake swarms at Santiaguito. An important implication of our observations is that negative trends in explosion rates at silicic lava dome eruptions cannot be used alone as an indicator of future weaker activity and reduced hazard. This case study of Santiaguito will serve as a useful foundation for future studies of long-lived lava dome eruptions featuring rapid transitions between effusive and explosive activity

Enter Mercury, Sleeping: Delivering Prayers on the Early Modern Stage

This is the author accepted manuscript. The final version is available from CUP via the DOI in this recor

The expanded octarepeat domain selectively binds prions and disrupts homomeric prion protein interactions

Insertion of additional octarepeats into the prion protein gene has been genetically linked to familial Creutzfeldt Jakob disease and hence to de novo generation of infectious prions. The pivotal event during prion formation is the conversion of the normal prion protein (Pr