CO emission in distant galaxies on and above the main sequence

We present the detection of multiple carbon monoxide CO line transitions with ALMA in a few tens of infrared-selected galaxies on and above the main sequence at z = 1.1−1.7. We reliably detected the emission of CO (5−4), CO (2−1), and CO (7−6)+[C I](3P2 − 3P1) in 50, 33, and 13 galaxies, respectively, and we complemented this information with available CO (4 − 3) and [C I](3P1 − 3P0) fluxes for part of the sample, and by modeling of the optical-to-millimeter spectral energy distribution. We retrieve a quasi-linear relation between LIR and CO (5 − 4) or CO (7 − 6) for main-sequence galaxies and starbursts, corroborating the hypothesis that these transitions can be used as star formation rate (SFR) tracers. We find the CO excitation to steadily increase as a function of the star formation efficiency, the mean intensity of the radiation field warming the dust (hUi), the surface density of SFR (ΣSFR), and, less distinctly, with the distance from the main sequence (∆MS). This adds to the tentative evidence for higher excitation of the CO+[C I] spectral line energy distribution (SLED) of starburst galaxies relative to that for main-sequence objects, where the dust opacities play a minor role in shaping the high-J CO transitions in our sample. However, the distinction between the average SLED of upper main-sequence and starburst galaxies is blurred, driven by a wide variety of intrinsic shapes. Large velocity gradient radiative transfer modeling demonstrates the existence of a highly excited component that elevates the CO SLED of high-redshift main-sequence and starbursting galaxies above the typical values observed in the disk of the Milky Way. This excited component is dense and it encloses ∼50% of the total molecular gas mass in main-sequence objects. We interpret the observed trends involving the CO excitation as to be mainly determined by a combination of large SFRs and compact sizes, as a large ΣSFR is naturally connected with enhanced dense molecular gas fractions and higher dust and gas temperatures, due to increasing ultraviolet radiation fields, cosmic ray rates, as well as dust and gas coupling. We release the full data compilation and the ancillary information to the community

Diquat Derivatives: Highly Active, Two-Dimensional Nonlinear Optical Chromophores with Potential Redox Switchability

In this article, we present a detailed study of structure−activity relationships in diquaternized 2,2′-bipyridyl (diquat) derivatives. Sixteen new chromophores have been synthesized, with variations in the amino electron donor substituents, π-conjugated bridge, and alkyl diquaternizing unit. Our aim is to combine very large, two-dimensional (2D) quadratic nonlinear optical (NLO) responses with reversible redox chemistry. The chromophores have been characterized as their PF_6^− salts by using various techniques including electronic absorption spectroscopy and cyclic voltammetry. Their visible absorption spectra are dominated by intense π → π^* intramolecular charge-transfer (ICT) bands, and all show two reversible diquat-based reductions. First hyperpolarizabilities β have been measured by using hyper-Rayleigh scattering with an 800 nm laser, and Stark spectroscopy of the ICT bands affords estimated static first hyperpolarizabilities β_0. The directly and indirectly derived β values are large and increase with the extent of π-conjugation and electron donor strength. Extending the quaternizing alkyl linkage always increases the ICT energy and decreases the E_(1/2) values for diquat reduction, but a compensating increase in the ICT intensity prevents significant decreases in Stark-based β_0 responses. Nine single-crystal X-ray structures have also been obtained. Time-dependent density functional theory clarifies the molecular electronic/optical properties, and finite field calculations agree with polarized HRS data in that the NLO responses of the disubstituted species are dominated by ‘off-diagonal’ β_(zyy) components. The most significant findings of these studies are: (i) β_0 values as much as 6 times that of the chromophore in the technologically important material (E)-4′-(dimethylamino)-N-methyl-4-stilbazolium tosylate; (ii) reversible electrochemistry that offers potential for redox-switching of optical properties over multiple states; (iii) strongly 2D NLO responses that may be exploited for novel practical applications; (iv) a new polar material, suitable for bulk NLO behavior

Evolution of Linear Absorption and Nonlinear Optical Properties in V-Shaped Ruthenium(II)-Based Chromophores

In this article, we describe a series of complexes with electron-rich cis-{Ru^(II)(NH_3)_4}^(2+) centers coordinated to two pyridyl ligands bearing N-methyl/arylpyridinium electron-acceptor groups. These V-shaped dipolar species are new, extended members of a class of chromophores first reported by us (Coe, B. J. et al. J. Am. Chem. Soc. 2005, 127, 4845−4859). They have been isolated as their PF_6− salts and characterized by using various techniques including ^1H NMR and electronic absorption spectroscopies and cyclic voltammetry. Reversible Ru^(III/II) waves show that the new complexes are potentially redox-switchable chromophores. Single crystal X-ray structures have been obtained for four complex salts; three of these crystallize noncentrosymmetrically, but with the individual molecular dipoles aligned largely antiparallel. Very large molecular first hyperpolarizabilities β have been determined by using hyper-Rayleigh scattering (HRS) with an 800 nm laser and also via Stark (electroabsorption) spectroscopic studies on the intense, visible d → π^* metal-to-ligand charge-transfer (MLCT) and π → π^* intraligand charge-transfer (ILCT) bands. The latter measurements afford total nonresonant β_0 responses as high as ca. 600 × 10^(−30) esu. These pseudo-C_(2v) chromophores show two substantial components of the β tensor, β_(zzz) and β_(zyy), although the relative significance of these varies with the physical method applied. According to HRS, β_(zzz) dominates in all cases, whereas the Stark analyses indicate that β_(zyy) is dominant in the shorter chromophores, but β_(zzz) and β_(zyy) are similar for the extended species. In contrast, finite field calculations predict that β_(zyy) is always the major component. Time-dependent density functional theory calculations predict increasing ILCT character for the nominally MLCT transitions and accompanying blue-shifts of the visible absorptions, as the ligand π-systems are extended. Such unusual behavior has also been observed with related 1D complexes (Coe, B. J. et al. J. Am. Chem. Soc. 2004, 126, 3880−3891)

Elliptical Galaxies and Bulges of Disk Galaxies: Summary of Progress and Outstanding Issues

This is the summary chapter of a review book on galaxy bulges. Bulge properties and formation histories are more varied than those of ellipticals. I emphasize two advances: 1 - "Classical bulges" are observationally indistinguishable from ellipticals, and like them, are thought to form by major galaxy mergers. "Disky pseudobulges" are diskier and more actively star-forming (except in S0s) than are ellipticals. Theys are products of the slow ("secular") evolution of galaxy disks: bars and other nonaxisymmetries move disk gas toward the center, where it starbursts and builds relatively flat, rapidly rotating components. This secular evolution is a new area of galaxy evolution work that complements hierarchical clustering. 2 - Disks of high-redshift galaxies are unstable to the formation of mass clumps that sink to the center and merge - an alternative channel for the formation of classical bulges. I review successes and unsolved problems in the formation of bulges+ellipticals and their coevolution (or not) with supermassive black holes. I present an observer's perspective on simulations of dark matter galaxy formation including baryons. I review how our picture of the quenching of star formation is becoming general and secure at redshifts z < 1. The biggest challenge is to produce realistic bulges+ellipticals and disks that overlap over a factor of 10**3 in mass but that differ from each other as observed over that whole range. Second, how does hierarchical clustering make so many giant, bulgeless galaxies in field but not cluster environments? I argue that we rely too much on AGN and star-formation feedback to solve these challenges.Comment: 46 pages, 10 postscript figures, accepted for publication in Galactic Bulges, ed. E. Laurikainen, R. F. Peletier, & D. A. Gadotti (New York: Springer), in press (2015

The 24 Micron Source Counts in Deep Spitzer Surveys

Galaxy source counts in the infrared provide strong constraints on the evolution of the bolometric energy output from distant galaxy populations. We present the results from deep 24 micron imaging from Spitzer surveys, which include approximately 50,000 sources to an 80% completeness of 60 uJy. The 24 micron counts rapidly rise at near-Euclidean rates down to 5 mJy, increase with a super-Euclidean rate between 0.4 - 4 mJy, and converge below 0.3 mJy. The 24 micron counts exceed expectations from non-evolving models by a factor >10 at 0.1 mJy. The peak in the differential number counts corresponds to a population of faint sources that is not expected from predictions based on 15 micron counts from ISO. We argue that this implies the existence of a previously undetected population of infrared-luminous galaxies at z ~ 1-3. Integrating the counts to 60 uJy, we derive a lower limit on the 24 micron background intensity of 1.9 +/- 0.6 nW m-2 sr-1 of which the majority (~ 60%) stems from sources fainter than 0.4 mJy. Extrapolating to fainter flux densities, sources below 60 uJy contribute 0.8 {+0.9/-0.4} nW m-2 sr-1 to the background, which provides an estimate of the total 24 micron background of 2.7 {+1.1/-0.7} nW m-2 sr-1.Comment: Accepted to the ApJS (Spitzer special issue); 5 pages, 3 color figures, uses emulateapj clas

Clustering of the AKARI NEP deep field 24<i>μ</i>m selected galaxies

Aims. We present a method of selection of 24 μm galaxies from the AKARI north ecliptic pole (NEP) deep field down to 150 μJy and measurements of their two-point correlation function. We aim to associate various 24 μm selected galaxy populations with present day galaxies and to investigate the impact of their environment on the direction of their subsequent evolution. Methods. We discuss using of Support Vector Machines (SVM) algorithm applied to infrared photometric data to perform star-galaxy separation, in which we achieve an accuracy higher than 80%. The photometric redshift information, obtained through the CIGALE code, is used to explore the redshift dependence of the correlation function parameter (r0) as well as the linear bias evolution. This parameter relates galaxy distribution to the one of the underlying dark matter. We connect the investigated sources to their potential local descendants through a simplified model of the clustering evolution without interactions. Results. We observe two different populations of star-forming galaxies, at zmed ∼ 0.25, zmed ∼ 0.9. Measurements of total infrared luminosities (LTIR) show that the sample at zmed ∼ 0.25 is composed mostly of local star-forming galaxies, while the sample at zmed ∼ 0.9 is composed of luminous infrared galaxies (LIRGs) with LTIR ∼ 1011.62 L⨀. We find that dark halo mass is not necessarily correlated with the LTIR: for subsamples with LTIR = 1011.15 L⨀ at zmed ∼ 0.7 we observe a higher clustering length (r0 = 6.21 ± 0.78 [h−1Mpc]) than for a subsample with mean LTIR = 1011.84 L⨀ at zmed ∼ 1.1 (r0 = 5.86 ± 0.69 h−1Mpc). We find that galaxies at zmed ∼ 0.9 can be ancestors of present day L∗ early type galaxies, which exhibit a very high r0 ∼ 8h−1 Mpc.</p

The evolution of quiescent galaxies at high redshift (z > 1.4)

We have studied the evolution of high redshift quiescent galaxies over an effective area of ~1.7 deg^2 in the COSMOS field. Galaxies have been divided according to their star-formation activity and the evolution of the different populations has been investigated in detail. We have studied an IRAC (mag_3.6 < 22.0) selected sample of ~18000 galaxies at z > 1.4 with multi-wavelength coverage. We have derived accurate photometric redshifts (sigma=0.06) and other important physical parameters through a SED-fitting procedure. We have divided our sample into actively star-forming, intermediate and quiescent galaxies depending on their specific star formation rate. We have computed the galaxy stellar mass function of the total sample and the different populations at z=1.4-3.0. We have studied the properties of high redshift quiescent galaxies finding that they are old (1-4 Gyr), massive (log(M/M_sun)~10.65), weakly star forming stellar populations with low dust extinction (E(B-V) < 0.15) and small e-folding time scales (tau ~ 0.1-0.3 Gyr). We observe a significant evolution of the quiescent stellar mass function from 2.5 < z < 3.0 to 1.4 < z < 1.6, increasing by ~ 1 dex in this redshift interval. We find that z ~ 1.5 is an epoch of transition of the GSMF. The fraction of star-forming galaxies decreases from 60% to 20% from z ~ 2.5-3.0 to z ~ 1.4-1.6 for log(M/M_sun) > 11, while the quiescent population increases from 10% to 50% at the same redshift and mass intervals. We compare the fraction of quiescent galaxies derived with that predicted by theoretical models and find that the Kitzbichler & White (2007) model is the one that better reproduces the data. Finally, we calculate the stellar mass density of the star-forming and quiescent populations finding that there is already a significant number of quiescent galaxies at z > 2.5 (rho~6.0 MsunMpc^-3).Comment: 17 pages, 20 figures, 5 tables. Accepted for publication in MNRA

GOODS-Herschel: star formation, dust attenuation, and the FIR-radio correlation on the main sequence of star-forming galaxies up to z=4

We use deep panchromatic data sets in the GOODS-N field, from GALEX to the deepest Herschel far-infrared (FIR) and VLA radio continuum imaging, to explore the evolution of star-formation activity and dust attenuation properties of star-forming galaxies to z sime 4, using mass-complete samples. Our main results can be summarized as follows: (i) the slope of the star-formation rate–M* correlation is consistent with being constant sime0.8 up to z sime 1.5, while its normalization keeps increasing with redshift; (ii) for the first time we are able to explore the FIR–radio correlation for a mass-selected sample of star-forming galaxies: the correlation does not evolve up to z sime 4; (iii) we confirm that galaxy stellar mass is a robust proxy for UV dust attenuation in star-forming galaxies, with more massive galaxies being more dust attenuated. Strikingly, we find that this attenuation relation evolves very weakly with redshift, with the amount of dust attenuation increasing by less than 0.3 mag over the redshift range [0.5–4] for a fixed stellar mass; (iv) the correlation between dust attenuation and the UV spectral slope evolves with redshift, with the median UV slope becoming bluer with redshift. By z sime 3, typical UV slopes are inconsistent, given the measured dust attenuations, with the predictions of commonly used empirical laws. (v) Finally, building on existing results, we show that gas reddening is marginally larger (by a factor of around 1.3) than the stellar reddening at all redshifts probed. Our results support a scenario where the ISM conditions of typical star-forming galaxies evolve with redshift, such that at z ≥ 1.5 Main Sequence galaxies have ISM conditions moving closer to those of local starbursts

Black hole accretion and host galaxies of obscured quasars in XMM-COSMOS

We explore the connection between black hole growth at the center of obscured quasars selected from the XMM-COSMOS survey and the physical properties of their host galaxies. We study a bolometric regime ( 8 x 10^45 erg/s) where several theoretical models invoke major galaxy mergers as the main fueling channel for black hole accretion. We confirm that obscured quasars mainly reside in massive galaxies (Mstar>10^10 Msun) and that the fraction of galaxies hosting such powerful quasars monotonically increases with the stellar mass. We stress the limitation of the use of rest-frame color-magnitude diagrams as a diagnostic tool for studying galaxy evolution and inferring the influence that AGN activity can have on such a process. We instead use the correlation between star-formation rate and stellar mass found for star-forming galaxies to discuss the physical properties of the hosts. We find that at z ~1, ~62% of Type-2 QSOs hosts are actively forming stars and that their rates are comparable to those measured for normal star-forming galaxies. The fraction of star-forming hosts increases with redshift: ~71% at z ~2, and 100% at z ~3. We also find that the the evolution from z ~1 to z ~3 of the specific star-formation rate of the Type-2 QSO hosts is in excellent agreement with that measured for star-forming galaxies. From the morphological analysis, we conclude that most of the objects are bulge-dominated galaxies, and that only a few of them exhibit signs of recent mergers or disks. Finally, bulge-dominated galaxies tend to host Type-2 QSOs with low Eddington ratios (lambda<0.1), while disk-dominated or merging galaxies have at their centers BHs accreting at high Eddington ratios (lambda > 0.1).Comment: Accepted by A&A. 20 pages, 16 figures, 2 tables. A version with higher resolution figures and SED fits of Appendix A is available at http://www.eso.org/~vmainier/QSO2/qso2.pd