Microstructure and reconstitution of freeze-dried gum Arabic at a range of concentrations and primary drying temperatures

Freeze-drying is an energy intensive unit operation used for the production of dehydrated foods, such as instant coffee and dried fruits, and results in high sensorial, nutritional and reconstitution properties of the final products. Understanding the relationships between operating conditions and product quality is essential to design processes that are energy efficient, whilst producing high quality dried foods. In this work, the properties (microstructure and reconstitution) of freeze-dried gum arabic samples (with initial concentrations ranging between 20 and 60% solids by weight) were evaluated. The materials were dried at three different primary drying shelf temperatures, Ts (- 20, - 30 and - 40 ◦C). Sample temperatures recorded throughout freeze-drying were close to the pre-set Ts, with the exception of the 60% initial concentration system, where the sample was hotter than the shelf by 10–15 ◦C, in particular on increasing Ts. This was attributed to a combination of local temperature and pressure conditions that may have resulted in partial melting of the material. For the 20–50% systems, the properties of the freeze-dried materials were mainly affected by the initial concentration of the system, with increasing initial concentration generally resulting in lower porosities (ranging between 20 and 40%) and higher reconstitution times (ranging between 0.5 and 10min for 95% reconstitution). Pores were generally needle-shaped and <200 μm. Large (200–1800 μm), circular pores were observed in high initial concentration systems, and they were dominant in the microstructure of the freeze-dried 60% sample. The presence of these large bubbles was linked to the partial melting of the material, which enabled its expansion and puffing. For the 60% system, primary drying temperature had a profound effect on the properties of the freeze-dried solid, with samples dried at higher temperature showing higher porosity (e.g. 60–70% for Ts = -¬¬ 20◦C) and faster reconstitution rates (e.g. 3min for 95% reconstitution at Ts = - 20◦C). Overall, this study demonstrates the significance of formulation and shelf temperature on the porous structure of freeze-dried samples, which directly influences product performance

The effect of temperature on adhesion forces between surfaces and model foods containing whey protein and sugar

The formation of fouling deposit from foods and food components is a severe problem in food processing and leads to frequent cleaning. The design of surfaces that resist fouling may decrease the need for cleaning and thus increase efficiency. Atomic force microscopy has been used to measure adhesion forces between stainless steel (SS) and fluoro-coated glass (FCG) microparticles and the model food deposits (i) whey protein (WPC), (ii) sweetened condensed milk, and (iii) caramel. Measurements were performed over a range of processing temperatures between 30 and 90 oC and at contact times up to 60 s. There is a significant increase in adhesion force of both types of microparticle to WPC at 90 oC for all contact times. For confectionary deposits adhesion to SS was similar. Adhesion of confectionary deposits to FCG at 30 oC revealed a decrease in adhesion compared to SS; at higher temperatures the adhesion forces were similar

Matching the nano- to the meso-scale: measuring deposit–surface interactions with atomic force microscopy and micromanipulation

Many researchers have studied the effects of changing the surface on fouling and cleaning. In biofouling the 'Baier curve' is a well-known result which relates adhesion to surface energy, and papers on the effect of changing surface energy to food fouling can be found more than 40 years ago. Recently the use of modified surfaces, at least at a research level, has been widespread. Here two different ways of studying surface-deposit interactions have been compared. Atomic force microscopy (AFM) is a method for probing interactions at a molecular level, and can measure (for example) the interaction between substrate and surfaces at a nm-scale. At a μm-mm level, we have developed a micromanipulation tool that can measure the force required to remove the deposit; the measure incorporates both surface and bulk deformation effects. The two methods have been compared by studying a range of model soils: toothpaste, as an example of a soil that can be removed by fluid flow alone, and confectionery soils. Removal has been studied from glass, stainless steel and fluorinated surfaces as examples of the sort of surfaces that can be found in practice. AFM measurements were made by using functionalized tips in force mode. The two types of probe give similar results, although the rheology of the soil affects the measurement from the micromanipulation probe under some circumstances. The data suggests that either method could be used to test candidate surfaces

Crystallisation in concentrated systems:a modelling approach

AbstractWater crystallisation in concentrated systems has been studied using a combination of mathematical modelling and experimental work. Two different freezing models have been employed to describe primary and secondary mechanisms (i.e. non-seeded and seed-induced processes, respectively) in sucrose solutions up to 60% (w/w). Differential Scanning Calorimetry (DSC) has been employed to characterise the phase change of the binary water–sucrose system in primary processes, and the kinetic and thermodynamic parameters obtained were coupled to the heat transfer equation to obtain the product temperature distribution. A recently developed method has been also employed to measure crystal growth rates in seed-induced crystallisation systems. Simulated results for the secondary crystallisation mechanism were able to reproduce experimentally observed trends for growth rates. An evaluation of the energy consumption during freezing/crystallisation processes has been carried out to assess each mechanism performance (crystallisation will occur at temperatures approximately 20°C higher in seeded processes) considering different process conditions and product formulations (i.e. solids and air fractions)

Gravitational radiation from gamma-ray bursts as observational opportunities for LIGO and VIRGO

Gamma-ray bursts are believed to originate in core-collapse of massive stars. This produces an active nucleus containing a rapidly rotating Kerr black hole surrounded by a uniformly magnetized torus represented by two counter-oriented current rings. We quantify black hole spin-interactions with the torus and charged particles along open magnetic flux-tubes subtended by the event horizon. A major output of Egw=4e53 erg is radiated in gravitational waves of frequency fgw=500 Hz by a quadrupole mass-moment in the torus. Consistent with GRB-SNe, we find (i) Ts=90s (tens of s, Kouveliotou et al. 1993), (ii) aspherical SNe of kinetic energy Esn=2e51 erg (2e51 erg in SN1998bw, Hoeflich et al. 1999) and (iii) GRB-energies Egamma=2e50 erg (3e50erg in Frail et al. 2001). GRB-SNe occur perhaps about once a year within D=100Mpc. Correlating LIGO/Virgo detectors enables searches for nearby events and their spectral closure density 6e-9 around 250Hz in the stochastic background radiation in gravitational waves. At current sensitivity, LIGO-Hanford may place an upper bound around 150MSolar in GRB030329. Detection of Egw thus provides a method for identifying Kerr black holes by calorimetry.Comment: to appear in PRD, 49

Comparison of advanced gravitational-wave detectors

We compare two advanced designs for gravitational-wave antennas in terms of their ability to detect two possible gravitational wave sources. Spherical, resonant mass antennas and interferometers incorporating resonant sideband extraction (RSE) were modeled using experimentally measurable parameters. The signal-to-noise ratio of each detector for a binary neutron star system and a rapidly rotating stellar core were calculated. For a range of plausible parameters we found that the advanced LIGO interferometer incorporating RSE gave higher signal-to-noise ratios than a spherical detector resonant at the same frequency for both sources. Spheres were found to be sensitive to these sources at distances beyond our galaxy. Interferometers were sensitive to these sources at far enough distances that several events per year would be expected

Gamma-Ray Bursts: The Underlying Model

A pedagogical derivation is presented of the ``fireball'' model of gamma-ray bursts, according to which the observable effects are due to the dissipation of the kinetic energy of a relativistically expanding wind, a ``fireball.'' The main open questions are emphasized, and key afterglow observations, that provide support for this model, are briefly discussed. The relativistic outflow is, most likely, driven by the accretion of a fraction of a solar mass onto a newly born (few) solar mass black hole. The observed radiation is produced once the plasma has expanded to a scale much larger than that of the underlying ``engine,'' and is therefore largely independent of the details of the progenitor, whose gravitational collapse leads to fireball formation. Several progenitor scenarios, and the prospects for discrimination among them using future observations, are discussed. The production in gamma- ray burst fireballs of high energy protons and neutrinos, and the implications of burst neutrino detection by kilometer-scale telescopes under construction, are briefly discussed.Comment: In "Supernovae and Gamma Ray Bursters", ed. K. W. Weiler, Lecture Notes in Physics, Springer-Verlag (in press); 26 pages, 2 figure

Predictive testing of minors for Huntington's disease: The UK and Netherlands experiences

A consistent feature of predictive testing guidelines for Huntington's disease (HD) is the recommendation not to undertake predictive tests on those < 18 years. Exceptions are made but the extent of, and reasons for, deviation from the guidelines are unknown. The UK Huntington's Prediction Consortium has collected data annually on predictive tests undertaken from the 23 UK genetic centers. DNA analysis for HD in the Netherlands is centralized in the Laboratory for Diagnostic Genome Analysis in Leiden. In the UK, 60 tests were performed on minors between 1994 and 2015 representing 0.63% of the total number of tests performed. In the Netherlands, 23 tests were performed on minors between 1997 and 2016. The majority of the tests were performed on those aged 16 and 17 years for both countries (23% and 57% for the UK, and 26% and 57% for the Netherlands). Data on the reasons for testing were identified for 36 UK and 22 Netherlands cases and included: close to the age of 18 years, pregnancy, currently in local authority care and likely to have less support available after 18 years, person never having the capacity to consent and other miscellaneous reasons. This study documents the extent of HD testing of minors in the UK and the Netherlands and suggests that, in general, the recommendation is being followed. We provide some empirical evidence as to reasons why clinicians have departed from the recommendation. We do not advise changing the recommendation but suggest that testing of minors continues to be monitored

A First Search for coincident Gravitational Waves and High Energy Neutrinos using LIGO, Virgo and ANTARES data from 2007

We present the results of the first search for gravitational wave bursts associated with high energy neutrinos. Together, these messengers could reveal new, hidden sources that are not observed by conventional photon astronomy, particularly at high energy. Our search uses neutrinos detected by the underwater neutrino telescope ANTARES in its 5 line configuration during the period January - September 2007, which coincided with the fifth and first science runs of LIGO and Virgo, respectively. The LIGO-Virgo data were analysed for candidate gravitational-wave signals coincident in time and direction with the neutrino events. No significant coincident events were observed. We place limits on the density of joint high energy neutrino - gravitational wave emission events in the local universe, and compare them with densities of merger and core-collapse events.Comment: 19 pages, 8 figures, science summary page at http://www.ligo.org/science/Publication-S5LV_ANTARES/index.php. Public access area to figures, tables at https://dcc.ligo.org/cgi-bin/DocDB/ShowDocument?docid=p120000

SN1987A and the properties of neutrino burst

We reanalyze the neutrino events from SN1987A in IMB and Kamiokande-II (KII) detectors, and compare them with the expectations from simple theoretical models of the neutrino emission. In both detectors the angular distributions are peaked in the forward direction, and the average cosines are 2 sigma above the expected values. Furthermore, the average energy in KII is low if compared with the expectations; but, as we show, the assumption that a few (probably one) events at KII have been caused by elastic scattering is not in contrast with the 'standard' picture of the collapse and yields a more satisfactory distributions in angle and (marginally) in energy. The observations give useful information on the astrophysical parameters of the collapse: in our evaluations, the mean energy of electron antineutrinos is =12-16 MeV, the total energy radiated around (2-3)*1.E53 erg, and there is a hint for a relatively large radiation of non-electronic neutrino species. These properties of the neutrino burst are not in disagreement with those suggested by the current theoretical paradigm, but the data leave wide space to non-standard pictures, especially when neutrino oscillations are included.Comment: 14 pages, 5 figure