Historical black carbon deposition in the Canadian High Arctic: a >250-year long ice-core record from Devon Island

Black carbon aerosol (BC), which is emitted from natural and anthropogenic sources (e.g., wildfires, coal burning), can contribute to magnify climate warming at high latitudes by darkening snow- and ice-covered surfaces, and subsequently lowering their albedo. Therefore, modeling the atmospheric transport and deposition of BC to the Arctic is important, and historical archives of BC accumulation in polar ice can help to validate such modeling efforts. Here we present a >250-year ice-core record of refractory BC (rBC) deposition on Devon ice cap, Canada, spanning the years from 1735 to 1992. This is the first such record ever developed from the Canadian Arctic. The estimated mean deposition flux of rBC on Devon ice cap for 1963-1990 is 0.2mg m-2a-1, which is at the low end of estimates from Greenland ice cores obtained using the same analytical method ( g1/4 0.1-4mg m-2a-1). The Devon ice cap rBC record also differs from the Greenland records in that it shows only a modest increase in rBC deposition during the 20th century. In the Greenland records a pronounced rise in rBC is observed from the 1880s to the 1910s, which is largely attributed to midlatitude coal burning emissions. The deposition of contaminants such as sulfate and lead increased on Devon ice cap in the 20th century but no concomitant rise in rBC is recorded in the ice. Part of the difference with Greenland could be due to local factors such as melt-freeze cycles on Devon ice cap that may limit the detection sensitivity of rBC analyses in melt-impacted core samples, and wind scouring of winter snow at the coring site. Air back-trajectory analyses also suggest that Devon ice cap receives BC from more distant North American and Eurasian sources than Greenland, and aerosol mixing and removal during long-range transport over the Arctic Ocean likely masks some of the specific BC source-receptor relationships. Findings from this study suggest that there could be a large variability in BC aerosol deposition across the Arctic region arising from different transport patterns. This variability needs to be accounted for when estimating the large-scale albedo lowering effect of BC deposition on Arctic snow/ice

Exploring the mycobacteriophage metaproteome: Phage genomics as an educational platform

Bacteriophages are the most abundant forms of life in the biosphere and carry genomes characterized by high genetic diversity and mosaic architectures. The complete sequences of 30 mycobacteriophage genomes show them collectively to encode 101 tRNAs, three tmRNAs, and 3,357 proteins belonging to 1,536 "phamilies" of related sequences, and a statistical analysis predicts that these represent approximately 50% of the total number of phamilies in the mycobacteriophage population. These phamilies contain 2.19 proteins on average; more than half (774) of them contain just a single protein sequence. Only six phamilies have representatives in more than half of the 30 genomes, and only three - encoding tape-measure proteins, lysins, and minor tail proteins - are present in all 30 phages, although these phamilies are themselves highly modular, such that no single amino acid sequence element is present in all 30 mycobacteriophage genomes. Of the 1,536 phamilies, only 230 (15%) have amino acid sequence similarity to previously reported proteins, reflecting the enormous genetic diversity of the entire phage population. The abundance and diversity of phages, the simplicity of phage isolation, and the relatively small size of phage genomes support bacteriophage isolation and comparative genomic analysis as a highly suitable platform for discovery-based education. © 2006 Hatfull et al

Use of green solvents as pre-treatment of dissolving pulp to decrease CS2 consumption from viscose production

Choline chloride-based deep eutectic solvents are widely used in biomass processing. In this work, four different green solvent mixtures were used as pre-treatment of acid sulphite dissolving pulp with the hypothesis of increasing the possibilities to produce viscose fibres and decreasing the use of the harmful and toxic carbon disulphide in the process. The experiments were performed at two different pulp to solvent mass ratios. Pulp quality parameters were also measured to determine the suitability of the pretreatment: a-cellulose, viscosity, lignin and pentosan content. In addition, X-ray diffraction analysis of pulps at the best solid to liquid ratio was performed to obtain the influence of the crystallinity index. Best results were obtained with the use of lactic acid, with reactivity values close to 94%, giving a reduction of CS2 usage of 15.83%. Furthermore, a linear relationship between the crystallinity index calculated by the XRD and reactivity with a regression factor of 0.87 was found

One-Dimensional Nanostructures and Devices of II–V Group Semiconductors

The II–V group semiconductors, with narrow band gaps, are important materials with many applications in infrared detectors, lasers, solar cells, ultrasonic multipliers, and Hall generators. Since the first report on trumpet-like Zn3P2nanowires, one-dimensional (1-D) nanostructures of II–V group semiconductors have attracted great research attention recently because these special 1-D nanostructures may find applications in fabricating new electronic and optoelectronic nanoscale devices. This article covers the 1-D II–V semiconducting nanostructures that have been synthesized till now, focusing on nanotubes, nanowires, nanobelts, and special nanostructures like heterostructured nanowires. Novel electronic and optoelectronic devices built on 1-D II–V semiconducting nanostructures will also be discussed, which include metal–insulator-semiconductor field-effect transistors, metal-semiconductor field-effect transistors, andp–nheterojunction photodiode. We intent to provide the readers a brief account of these exciting research activities

Nonheritable Cellular Variability Accelerates the Evolutionary Processes of Cancer

Heritable genetic or epigenetic changes in cells are thought to drive tumor development, metastasis, and drug resistance. This essay discusses the possibility that nonheritable phenotypic variability contributes to the evolution of cancer, suggesting new approaches to treatment

Accuracy of Energy Prediction Methodologies

In the current market, the specific annual energy yield (kWh/kWp) of a PV system is gaining in importance due to its direct link to the financial returns for possible investors who typically demand an accuracy of 5% in this prediction. This paper focuses on the energy prediction of photovoltaic modules themselves, as there have been significant advances achieved with module technologies which affect the device physics in a way that might force the revisiting of device modelling. The paper reports the results of a round robin based evaluation of European modelling methodologies. The results indicate that the error in predicting energy yield for the same module at different locations was within 5% for most of the methodologies. However, this error increased significantly if the nominal nameplate rating is used in the characterization stage. For similar modules at the same location the uncertainties were much larger due to module-module variations

Deep Eutectic Solvents (DESs) and their applications [forthcoming]

Deep Eutectic Solvents (DESs) and Their Application

Basal debris entrainment and transport in glaciers of southwestern Bylot Island, Canadian Arctic

ABSTRACT. Glaciers on southwestern Bylot Island in the Canadian Arctic flow from an alpine setting in high-grade crystalline Archean terrane, on to coastal lowlands underlain by clastic sedimentary strata of Cretaceous to Tertiary age.  We have used the contrasting mineralogy of the substrate as a tool to study subglacialentrainment and transport of debris in two large piedmont glaciers on Bylot Island. High chlorite/ and mica-illite/smectite ratios indicate that most basal debris is derived from crystalline rocks underlying the upper reaches of the glaciers. The subglacial accretion of Cretaceous-Tertiary sediments appears restricted to the lowermost part ofthe basal zone and is most noticeable near the glaciers' termini. lce associated with discrete silty-sandy debris layers is characterized by an isotopic signature indicative of refreezing of meltwater at the glacier sole. The compositional, textural and isotopic characteristics of basal sediment and ice lead us to conclude that subglacial entrainment through basal ice accretion occurs in both the upper and marginal parts of the glacier