The Unusual Spitzer Spectrum of the Carbon Star IRAS 04496–6958: A Different Condensation Sequence in the LMC?

We present a new Spitzer Infrared Spectrograph (IRS) spectrum of the carbon star IRAS 04496-6958 in the Large Magellanic Cloud, which exhibits a fairly broad absorption feature at ~11 μm. This feature is consistent with SiC absorption, as seen in a few Galactic sources. Furthermore, the C2H2 (and other molecular) absorption bands are the deepest ever observed, indicative of a very high column density. While the Galactic sources with SiC absorption have cool colors (continuum temperature ≈300 K), IRAS 04496-6958 is much bluer, with a continuum temperature of ≈600 K. Based on the Galactic sample, SiC dust at this temperature should still display an emission feature at ~11 μm. If SiC is the cause of the absorption feature, it suggests a subtly different evolutionary path and a change to a different condensation sequence than assumed for Galactic carbon stars. An alternative explanation for this feature is molecular line absorption; however, currently available line lists are not sufficient to properly assess this hypothesis

Determining the forsterite abundance of the dust around Asymptotic Giant Branch stars

Aims. We present a diagnostic tool to determine the abundance of the crystalline silicate forsterite in AGB stars surrounded by a thick shell of silicate dust. Using six infrared spectra of high mass-loss oxygen rich AGB stars we obtain the forsterite abundance of their dust shells. Methods. We use a monte carlo radiative transfer code to calculate infrared spectra of dust enshrouded AGB stars. We vary the dust composition, mass-loss rate and outer radius. We focus on the strength of the 11.3 and the 33.6 \mu m forsterite bands, that probe the most recent (11.3 \mu m) and older (33.6 \mu m) mass-loss history of the star. Simple diagnostic diagrams are derived, allowing direct comparison to observed band strengths. Results. Our analysis shows that the 11.3 \mu m forsterite band is a robust indicator for the forsterite abundance of the current mass-loss period for AGB stars with an optically thick dust shell. The 33.6 \mu m band of forsterite is sensitive to changes in the density and the geometry of the emitting dust shell, and so a less robust indicator. Applying our method to six high mass-loss rate AGB stars shows that AGB stars can have forsterite abundances of 12% by mass and higher, which is more than the previously found maximum abundance of 5%.Comment: Accepted for publication in A&

Dust in the wind: Crystalline silicates, corundum and periclase in PG 2112+059

We have determined the mineralogical composition of dust in the Broad Absorption Line (BAL) quasar PG 2112+059 using mid-infrared spectroscopy obtained with the Spitzer Space Telescope. From spectral fitting of the solid state features, we find evidence for Mg-rich amorphous silicates with olivine stoichiometry, as well as the first detection of corundum (Al_2O_3) and periclase (MgO) in quasars. This mixed composition provides the first direct evidence for a clumpy density structure of the grain forming region. The silicates in total encompass 56.5% of the identified dust mass, while corundum takes up 38 wt.%. Depending on the choice of continuum, a range of mass fractions is observed for periclase ranging from 2.7% in the most conservative case to 9% in a less constrained continuum. In addition, we identify a feature at 11.2 micron as the crystalline silicate forsterite, with only a minor contribution from polycyclic aromatic hydrocarbons. The 5% crystalline silicate fraction requires high temperatures such as those found in the immediate quasar environment in order to counteract rapid destruction from cosmic rays.Comment: 2 figure

Spitzer detections of new dust components in the outflow of the Red Rectangle

We present Spitzer high spectral resolution IRS spectroscopy of three positions in the carbon-rich outflow of post-AGB star HD 44179, better known as the Red Rectangle. Surprisingly, the spectra show some strong unknown mid-infrared resonances, in the 13-20 micron range. The shape and position of these resonances varies with position in the nebula, and are not correlated with the PAH features. We conclude these features are due to oxygen-rich minerals, located in a region which is believed to be predominantly carbon-rich. We provide possible explanations for the presence of oxygen-rich dust in the carbon-rich outflows. Simple Mg-Fe-oxides are suggested as carriers of these unidentified features.Comment: accepted by ApJL; 5 pages; 4 figure

The variable mass loss of the AGB star WX Psc as traced by the CO J=1-0 through 7-6 lines and the dust emission

Low and intermediate mass stars lose a significant fraction of their mass through a dust-driven wind during the Asymptotic Giant Branch (AGB) phase. Recent studies show that winds from late-type stars are far from being smooth. Mass-loss variations occur on different time scales, from years to tens of thousands of years. The variations appear to be particularly prominent towards the end of the AGB evolution. The occurrence, amplitude and time scale of these variations are still not well understood. The goal of our study is to gain insight into the structure of the circumstellar envelope (CSE) of WX Psc and map the possible variability of the late-AGB mass-loss phenomenon. We have performed an in-depth analysis of the extreme infrared AGB star WX Psc by modeling (1) the CO J=1-0 through 7-6 rotational line profiles and the full spectral energy distribution (SED) ranging from 0.7 to 1300 micron. We hence are able to trace a geometrically extended region of the CSE. Both mass-loss diagnostics bear evidence of the occurrence of mass-loss modulations during the last ~2000 yr. In particular, WX Psc went through a high mass-loss phase (Mdot~5e-5 Msun/yr) some 800 yr ago. This phase lasted about 600 yr and was followed by a long period of low mass loss (Mdot~5e-8 Msun/yr). The present day mass-loss rate is estimated to be ~6e-6 Msun/yr. The AGB star WX Psc has undergone strong mass-loss rate variability on a time scale of several hundred years during the last few thousand years. These variations are traced in the strength and profile of the CO rotational lines and in the SED. We have consistently simulated the behaviour of both tracers using radiative transfer codes that allow for non-constant mass-loss rates.Comment: 12 pages, accepted for publication in A&

The shape and composition of interstellar silicate grains

We investigate the composition and shape distribution of silicate dust grains in the interstellar medium. The effect of the amount of magnesium in the silicate lattice is studied. We fit the spectral shape of the interstellar 10 mu extinction feature as observed towards the galactic center. We use very irregularly shaped coated and non-coated porous Gaussian Random Field particles as well as a statistical approach to model shape effects. For the dust materials we use amorphous and crystalline silicates with various composition and SiC. The results of our analysis of the 10 mu feature are used to compute the shape of the 20 mu silicate feature and to compare this with observations. By using realistic particle shapes we are, for the first time, able to derive the magnesium fraction in interstellar silicates. We find that the interstellar silicates are highly magnesium rich (Mg/(Fe+Mg)>0.9) and that the stoichiometry lies between pyroxene and olivine type silicates. This composition is not consistent with that of the glassy material found in GEMS in interplanetary dust particles indicating that these are, in general, not unprocessed remnants from the interstellar medium. Also, we find a significant fraction of SiC (~3%). We discuss the implications of our results for the formation and evolutionary history of cometary and circumstellar dust. We argue that the fact that crystalline silicates in cometary and circumstellar grains are almost purely magnesium silicates is a natural consequence of our findings that the amorphous silicates from which they were formed were already magnesium rich.Comment: Accepted for publication in A&

Observations of chemical differentiation in clumpy molecular clouds

We have extensively mapped a sample of dense molecular clouds (L1512, TMC-1C, L1262, Per 7, L1389, L1251E) in lines of HC3N, CH3OH, SO and C^{18}O. We demonstrate that a high degree of chemical differentiation is present in all of the observed clouds. We analyse the molecular maps for each cloud, demonstrating a systematic chemical differentiation across the sample, which we relate to the evolutionary state of the cloud. We relate our observations to the cloud physical, kinematical and evolutionary properties, and also compare them to the predictions of simple chemical models. The implications of this work for understanding the origin of the clumpy structures and chemical differentiation observed in dense clouds are discussed.Comment: 20 pages, 7 figures. Higher quality figures appear in the published journal articl

Evolution of the Most Luminous Dusty Galaxies

A summary of mid-infrared continuum luminosities arising from dust is given for very luminous galaxies, Lir > 10^12 solar luminosities, with 0.005 < z < 3.2 containing active galactic nuclei (AGN), including 115 obscured AGN and 60 unobscured (type 1) AGN. All sources have been observed with the Spitzer Infrared Spectrograph. Obscured AGN are defined as having optical depth > 0.7 in the 9.7 um silicate absorption feature and unobscured AGN show silicate in emission. Luminosity vLv(8 um) is found to scale as (1+z)^2.6 to z = 2.8, and luminosities vLv(8 um) are approximately 3 times greater for the most luminous unobscured AGN. Total infrared luminosities for the most luminous obscured AGN, Lir(AGN_obscured) in solar luminosities, scale as log Lir(AGN_obscured) = 12.3+-0.25 + 2.6(+-0.3)log(1+z), and for the most luminous unobscured AGN, scale as log Lir(AGN1) = 12.6+-0.15 + 2.6(+-0.3)log(1+z), indicating that the most luminous AGN are about 10 times more luminous than the most luminous starbursts. Results are consistent with obscured and unobscured AGN having the same total luminosities with differences arising only from orientation, such that the obscured AGN are observed through very dusty clouds which extinct about 50% of the intrinsic luminosity at 8 um. Both obscured and unobscured AGN should be detected to z ~ 6 by Spitzer surveys with fv(24 um) > 0.3 mJy, even without luminosity evolution for z > 2.5. By contrast, the most luminous starbursts cannot be detected for z > 3, even if luminosity evolution continues beyond z = 2.5.Comment: Includes corrected Figure 3, as publishe

A close look into the carbon disk at the core of the planetary nebula CPD-568032

We present high spatial resolution observations of the dusty core of the Planetary Nebula with Wolf-Rayet central star CPD-568032. These observations were taken with the mid-infrared interferometer VLTI/MIDI in imaging mode providing a typical 300 mas resolution and in interferometric mode using UT2-UT3 47m baseline providing a typical spatial resolution of 20 mas. The visible HST images exhibit a complex multilobal geometry dominated by faint lobes. The farthest structures are located at 7" from the star. The mid-IR environment of CPD-568032 is dominated by a compact source, barely resolved by a single UT telescope in a 8.7 micron filter. The infrared core is almost fully resolved with the three 40-45m projected baselines ranging from -5 to 51 degree but smooth oscillating fringes at low level have been detected in spectrally dispersed visibilities. This clear signal is interpreted in terms of a ring structure which would define the bright inner rim of the equatorial disk. Geometric models allowed us to derive the main geometrical parameters of the disk. For instance, a reasonably good fit is reached with an achromatic and elliptical truncated Gaussian with a radius of 97+/-11 AU, an inclination of 28+/-7 degree and a PA for the major axis at 345+/-7 degree. Furthermore, we performed some radiative transfer modeling aimed at further constraining the geometry and mass content of the disk, by taking into account the MIDI dispersed visibilities, spectra, and the large aperture SED of the source. These models show that the disk is mostly optically thin in the N band and highly flared.Comment: Paper accepted in A&