Hot extrusion followed by a hot ecap consolidation combined technique in the production of Boron Carbide (B4C) reinforced with aluminium chips (AA6061) composite

A new and promising MMC approach to the reduction of pollution, greenhouse effects, and emissions is to develop a technology related to materials composite forming. Hot extrusion followed by hot ECAP is a combination of solid-state recycling method (direct recycling) that consists of chip preparations, cold compaction, and hot extrusion, followed by the ECAP process. The developed process is used to consolidate the chips for direct chip recycling purposes without the remelting phase. In this study, finished or semi-finished products from B4C-reinforced particles and AA6061 aluminium chips were produced. The samples made by hot extrusion were compared with samples obtained from hot extrusion followed by the hot ECAP process in terms of mechanical properties. Additional plastic deformation by hot ECAP after hot extrusion significantly increased the mechanical properties of the MMC compared with the samples obtained from the hot extrusion only. The density and microstructure of the samples were also determined

Development of Hot Equal Channel Angular Processing (ECAP) consolidation technique in the production of Boron Carbide(B4C)-Reinforced Aluminium Chip (AA6061)-based composite

The production of metal matrix composites (MMCs) through recycled materials is a cost-saving process. However, the improvement of the mechanical and physical properties is another challenge to be concerned. In this study, recycled aluminium 6061 (AA6061) chips reinforced with different volumetric fractions of boron carbide (B4C) were produced through hot equal channel angular processing (ECAP). Response surface methodology (RSM) was carried out to investigate the dependent response (compressive strength) with independent parameters such as different volumetric fractions (5-15%) of added contents of B4C and preheating temperature (450 – 550°C). Also, the number of passes were examined to check the effect on the mechanical and physical properties of the developed recycled AA6061/B4C composite. The results show that maximum compressive strength and hardness of recycled AA6061/B4C were 59.2 MPa and 69 HV respectively at 5% of B4C contents. Likewise, the density and number of pores increased, which were confirmed through scanning electron microscope (SEM) and atomic force microscopes (AFM) analysis. However, the number of passes enhanced the mechanical and physical properties of the recycled AA6061/B4C composite. Therefore, the maximum compressive strength and hardness achieved were 158 MPa and 74.95 HV for the 4th pass. Moreover, the physical properties of recycled AA6061/B4C composite become denser of 2.62 g/cm3 at the 1st pass and 2.67 g/cm3 for the 4th pass. Thus, it can be concluded that the B4C volumetric fraction and number of passes have a significant effect on recycled AA6061 chips

The effect of solid-State processes and heat treatment on the properties of AA7075 aluminum waste recycling nanocomposite

Direct solid-states, such as hot extrusion and equal channel angular pressing (ECAP), are alternative and efficient solid-state processes for use in recycling aluminium scrap. These processes utilise less energy and are eco-friendly. Ceramic particles such as ZrO2 are suggested as alternatives in the production of metal composites. This study investigated and optimised the effects of various parameters of reinforced ZrO2 nanoparticles on the mechanical and physical properties via response surface methodology (RSM). These parameters were the volume fraction (VF), preheating temperature (T), and preheating time (t). The effects of these parameters were examined before and after the heat treatment condition and ECAP. Each parameter was evaluated at varying magnitudes, i.e., 450, 500, and 550 °C for T, 1, 2, and 3 h for t, and 1, 3, and 5% for VF. The effect that process variables had on responses was elucidated using the factorial design with centre point analysis. T and VF were crucial for attaining the optimum ultimate tensile strength (UTS) and microhardness. Reducing VF increased the mechanical properties to 1 vol% of oxide. The maximum hardness of 95 HV was attained at 550 °C, 1.6 h, and 1 vol% ZrO2 with a density of 2.85 g/cm3 and tensile strength of 487 MPa. UTS, density, and microhardness were enhanced by 14%, 1%, and 9.5%, respectively. Additionally, the hot extrusion parameters and ECAP followed by heat treatment strengthened the microhardness by 64% and density by 3%. Compression pressure and extrusion stress produced in these stages were sufficient to eliminate voids that increased the mechanical properties

Response Surface Methodology (RSM) implementation in zro particles reinforced aluminium chips by Hot Equal Channel Pressing (ECAP)

In recent years, the interest on solid-state recycling of aluminum chips increases over the years due to the less energy consumption of the process. This research studies the quantitative effects of preheating temperature and volume fraction of Zirconium Dioxide when it is reinforced to the Aluminum alloy AA6061 on its mechanical properties. The parameters of the experiment are preheating temperature and volume fraction of ZrO . Temperature are varied between 450 and 550 ℃ according to the boundary parameters. The volume fraction of ZrO consists of 5, 10 and 15% of the reinforcement. Increasing the volume fraction of ZrO correlates with the increase of mechanical and physical properties. Design of Experimental with factorial design was implemented to analyse the magnitude of response on the mechanical properties from the variable of parameters. The preheating temperature was revealed to be the most significant factor affecting the yield strength and the microhardness of the composite followed by the volume fraction of ZrO . It is revealed that the most optimum temperature is 550 ℃ and the optimum percentage of volume fraction is 9.28%. Both highest microhardness and yield strength were obtained from these optimum temperatures. Scanning Electron Microscope (SEM) revealed on how elongation in Zirconia chips is affected by the amount of ZrO reinforcement. Energy Dispersive Spectroscopy (EDS) analysis performed revealed on the arbitrary weight out of total weight for every element in the composite such as Al, Zr, O and Si

Antimicrobial resistance among migrants in Europe: a systematic review and meta-analysis

BACKGROUND: Rates of antimicrobial resistance (AMR) are rising globally and there is concern that increased migration is contributing to the burden of antibiotic resistance in Europe. However, the effect of migration on the burden of AMR in Europe has not yet been comprehensively examined. Therefore, we did a systematic review and meta-analysis to identify and synthesise data for AMR carriage or infection in migrants to Europe to examine differences in patterns of AMR across migrant groups and in different settings. METHODS: For this systematic review and meta-analysis, we searched MEDLINE, Embase, PubMed, and Scopus with no language restrictions from Jan 1, 2000, to Jan 18, 2017, for primary data from observational studies reporting antibacterial resistance in common bacterial pathogens among migrants to 21 European Union-15 and European Economic Area countries. To be eligible for inclusion, studies had to report data on carriage or infection with laboratory-confirmed antibiotic-resistant organisms in migrant populations. We extracted data from eligible studies and assessed quality using piloted, standardised forms. We did not examine drug resistance in tuberculosis and excluded articles solely reporting on this parameter. We also excluded articles in which migrant status was determined by ethnicity, country of birth of participants' parents, or was not defined, and articles in which data were not disaggregated by migrant status. Outcomes were carriage of or infection with antibiotic-resistant organisms. We used random-effects models to calculate the pooled prevalence of each outcome. The study protocol is registered with PROSPERO, number CRD42016043681. FINDINGS: We identified 2274 articles, of which 23 observational studies reporting on antibiotic resistance in 2319 migrants were included. The pooled prevalence of any AMR carriage or AMR infection in migrants was 25·4% (95% CI 19·1-31·8; I2 =98%), including meticillin-resistant Staphylococcus aureus (7·8%, 4·8-10·7; I2 =92%) and antibiotic-resistant Gram-negative bacteria (27·2%, 17·6-36·8; I2 =94%). The pooled prevalence of any AMR carriage or infection was higher in refugees and asylum seekers (33·0%, 18·3-47·6; I2 =98%) than in other migrant groups (6·6%, 1·8-11·3; I2 =92%). The pooled prevalence of antibiotic-resistant organisms was slightly higher in high-migrant community settings (33·1%, 11·1-55·1; I2 =96%) than in migrants in hospitals (24·3%, 16·1-32·6; I2 =98%). We did not find evidence of high rates of transmission of AMR from migrant to host populations. INTERPRETATION: Migrants are exposed to conditions favouring the emergence of drug resistance during transit and in host countries in Europe. Increased antibiotic resistance among refugees and asylum seekers and in high-migrant community settings (such as refugee camps and detention facilities) highlights the need for improved living conditions, access to health care, and initiatives to facilitate detection of and appropriate high-quality treatment for antibiotic-resistant infections during transit and in host countries. Protocols for the prevention and control of infection and for antibiotic surveillance need to be integrated in all aspects of health care, which should be accessible for all migrant groups, and should target determinants of AMR before, during, and after migration. FUNDING: UK National Institute for Health Research Imperial Biomedical Research Centre, Imperial College Healthcare Charity, the Wellcome Trust, and UK National Institute for Health Research Health Protection Research Unit in Healthcare-associated Infections and Antimictobial Resistance at Imperial College London

Surgical site infection after gastrointestinal surgery in high-income, middle-income, and low-income countries: a prospective, international, multicentre cohort study

Background: Surgical site infection (SSI) is one of the most common infections associated with health care, but its importance as a global health priority is not fully understood. We quantified the burden of SSI after gastrointestinal surgery in countries in all parts of the world. Methods: This international, prospective, multicentre cohort study included consecutive patients undergoing elective or emergency gastrointestinal resection within 2-week time periods at any health-care facility in any country. Countries with participating centres were stratified into high-income, middle-income, and low-income groups according to the UN's Human Development Index (HDI). Data variables from the GlobalSurg 1 study and other studies that have been found to affect the likelihood of SSI were entered into risk adjustment models. The primary outcome measure was the 30-day SSI incidence (defined by US Centers for Disease Control and Prevention criteria for superficial and deep incisional SSI). Relationships with explanatory variables were examined using Bayesian multilevel logistic regression models. This trial is registered with ClinicalTrials.gov, number NCT02662231. Findings: Between Jan 4, 2016, and July 31, 2016, 13 265 records were submitted for analysis. 12 539 patients from 343 hospitals in 66 countries were included. 7339 (58·5%) patient were from high-HDI countries (193 hospitals in 30 countries), 3918 (31·2%) patients were from middle-HDI countries (82 hospitals in 18 countries), and 1282 (10·2%) patients were from low-HDI countries (68 hospitals in 18 countries). In total, 1538 (12·3%) patients had SSI within 30 days of surgery. The incidence of SSI varied between countries with high (691 [9·4%] of 7339 patients), middle (549 [14·0%] of 3918 patients), and low (298 [23·2%] of 1282) HDI (p < 0·001). The highest SSI incidence in each HDI group was after dirty surgery (102 [17·8%] of 574 patients in high-HDI countries; 74 [31·4%] of 236 patients in middle-HDI countries; 72 [39·8%] of 181 patients in low-HDI countries). Following risk factor adjustment, patients in low-HDI countries were at greatest risk of SSI (adjusted odds ratio 1·60, 95% credible interval 1·05–2·37; p=0·030). 132 (21·6%) of 610 patients with an SSI and a microbiology culture result had an infection that was resistant to the prophylactic antibiotic used. Resistant infections were detected in 49 (16·6%) of 295 patients in high-HDI countries, in 37 (19·8%) of 187 patients in middle-HDI countries, and in 46 (35·9%) of 128 patients in low-HDI countries (p < 0·001). Interpretation: Countries with a low HDI carry a disproportionately greater burden of SSI than countries with a middle or high HDI and might have higher rates of antibiotic resistance. In view of WHO recommendations on SSI prevention that highlight the absence of high-quality interventional research, urgent, pragmatic, randomised trials based in LMICs are needed to assess measures aiming to reduce this preventable complication

Mechanical and physical properties of micro alumina reinforced direct recycled AA6061 chips based matrix by hot extrusion process

Direct hot extrusion is an alternative process for recycling aluminium without melting the scrap. It utilizes low energy and is environmental friendly. This study shows the effects of preheating temperature (PHT), preheating time (PHti) and addition of volume fraction (VF) of micro alumina on the microhardness (MH), density and microstructure of the extruded profiles. Three values of PHT (450, 500, 550 °C), PHti (1, 2, 3 hours) and VF (5, 10, 15 %) were considered respectively. The full factorial design with center point analysis was used to demonstrate the effect of process variables on responses. A total of 19 experimental runs were performed through the hot extrusion process. The results show that the preheating temperature is the most important factor to be controlled in order to obtain the optimum MH and density, while preheating time and volume fraction trailed behind the former. It can be concluded that microhardness increases with the increase in PHT and decrease in PHti and VF. On the contrary, an increase in density was observed with a decrease in PHT, PHti and VF apiece. The impact of hot extrusion parameters on the average grain sizes and microstructural analysis of the recycled samples were equally investigated and discussed

The effects of CuO and SiO2 on aluminum AA6061 hybrid nanocomposite as reinforcements: a concise review

Hybrid composites are obtained by embedding multiple micro and nano reinforcements into the matrix materials. These hybrid composites are helpful to obtain the useful properties of matrix and reinforcement materials. Aluminum matrix is one the most common matrix materials due to its excellent thermal and electrical properties. This review covers various aspects of nanoparticle-reinforced Al hybrid composites. Solid-state recycling of Al only consumes around 5% of the energy utilized in the conventional extraction and recycling methods. This review revolves around the induction of silica and copper oxide nanoparticles into the solid-state recycled Al matrix material to form the hybrid composite. These nanoparticles enhance stiffness, toughness, and high temperature stability for Al hybrid composites. A detailed analysis was carried out for AA6061-grade Al matrix materials along with the silica and copper oxide nanoparticles. The present work focused on the effects of nano silica and nano copper oxide particle reinforcements on Al-based composite manufactured via hot extrusion process. The composite fabrication through solid-state recycling is discussed in detail. A detailed analysis for the effects of volume fraction and wt.% of CuO and SiO2 reinforcement particles was carried out by various characterization techniques. A detailed comparison in terms of mechanical performance of Al-based composites with the addition of nano silica and nano copper oxide particles is presented here to investigate the efficiency and performance of these particles

Effect of processing conditions on the fracture behavior of Al-5Zn�1.5Mg-1.0Mn-0.35Cu alloy fabricated from recycled beverage cans (RBCs) for bumper beam applications

The literature is a deficit of the effect of fractographic and microstructural analyses on the yield strength (δ ) of experimental 7xxx alloy fabricated from Recycled Beverage Cans (RBCs). This paper aims at correlate between fractography, microstructures, chemical compositions, and δy with respect to heat treatment (HT) parameters. Both intergranular and intergranular fractures were found predominantly ductile with micro dimples. Prolonged ageing time increased the thickness of boundaries and precipitated free zones (PFZs). Micro-voids and flake-like patterns indicated the formation of secondary phases. Maximum δy of 129 MPa and elongation of 16.3 % were observed in an alloy annealed (o) at 413 °C, artificial aged (T6) at 145 °C, for 6 h. Thus, modifications of HT process has significantly influenced the δy and microstructure of the alloy fabricated from RBCs. Future studies should concentrate on investigating the effect of variations in the wt. % Zn on the mechanical properties

Effects of Lewis Basicity and Acidity on σ-Hole Interactions in Carbon-Bearing Complexes: A Comparative Ab Initio Study

The effects of Lewis basicity and acidity on σ-hole interactions were investigated using two sets of carbon-containing complexes. In Set I, the effect of Lewis basicity was studied by substituting the X3/X atom(s) of the NC-C6H2-X3 and NCX Lewis bases (LB) with F, Cl, Br, or I. In Set II, the W-C-F3 and F-C-X3 (where X and W = F, Cl, Br, and I) molecules were utilized as Lewis acid (LA) centers. Concerning the Lewis basicity effect, higher negative interaction energies (Eint) were observed for the F-C-F3∙∙∙NC-C6H2-X3 complexes compared with the F-C-F3∙∙∙NCX analogs. Moreover, significant Eint was recorded for Set I complexes, along with decreasing the electron-withdrawing power of the X3/X atom(s). Among Set I complexes, the highest negative Eint was ascribed to the F-C-F3∙∙∙NC-C6H2-I3 complex with a value of −1.23 kcal/mol. For Set II complexes, Eint values of F-C-X3 bearing complexes were noted within the −1.05 to −2.08 kcal/mol scope, while they ranged from −0.82 to −1.20 kcal/mol for the W-C-F3 analogs. However, Vs,max quantities exhibited higher values in the case of W-C-F3 molecules compared with F-C-X3; preferable negative Eint were ascribed to the F-C-X3 bearing complexes. These findings were delineated as a consequence of the promoted contributions of the X3 substituents. Dispersion forces (Edisp) were identified as the dominant forces for these interactions. The obtained results provide a foundation for fields such as crystal engineering and supramolecular chemistry studies that focus on understanding the characteristics of carbon-bearing complexes