Thermo-Catalytic Reforming of waste biomass for alternative fuels production in a framework of decarbonisation

In Europe, the production of alternative biofuels represents a very relevant economic and innovative target, as several European directives and regulations are enacted to secure support for the sustainable development throughout the transport sector. To satisfy the continuity of biofuels production avoiding the risks of technological failures or feedstocks shortage, the use of wastes and second-generation biomass represents a promising solution in terms of availability, economic convenience and environmental impact on overall emissions. In fact, they can be produced worldwide without competing with other industrial uses (e.g. food industry, livestock bedding, horticulture etc.) or having possible negative impacts on environment and biodiversity. The real diversifier for the competitiveness as well as the feasibility of biofuels production is the technology. Among several thermochemical conversion systems, the patented Thermo-Catalytic Reforming (TCR©) represents a flexible and reliable technology, capable to convert a wide range of advanced feedstocks in value-added products and fuels (i.e. char, oil and syngas). In this research, waste carbon fibres (CF) and solid grade laminate (SGL) have been investigated in a 2 kg/h lab-scale TCR reactor at the University of Birmingham. They are widely used in the industrial sectors and in many applications such as construction material, furniture, electronics as well as in vehicles, aerospace industry, sporting goods and medical field, thus contributing to high volumes of waste at end of life. Globally, about 130 million of tons of kraft paper is annually produced and partly destined to SGL production and the global demand of carbon fibres in 2022 is equal to 127,000 tons. To evaluate the suitability of TCR technology for SGL and CF, the characterisation of both feedstocks was accomplished, and it was concluded SGL and CF can be processed via TCR. The main energy carriers (char, oil and syngas) were generated under pyrolysis temperatures of 500°C for SGL and 600°C for CF and reforming temperature of 650°C for SGL and 680°C for CF, respectively. The different temperatures were set according to the preliminary investigation carried out on TGA for both feedstocks. The SGL oil showed good properties and its HHV reached a value of 32.72 MJ/kg. However, a successive upgrading was required to meet specifications for its use as drop in fuels. On the contrary, the CF oil production was negligible, even if its calorific value was 30 MJ/kg. The syngas produced from the treatment of SGL and CF was rich in hydrogen (about 20-40 vol%). Lastly, char revealed a calorific value of 25.94 MJ/kg and 20 MJ/kg for SGL and CF, respectively, thus exhibiting potential as a fuel as well as a catalyst in the gasification process. Overall, TCR of SGL and CF represents a novelty and it can be a promising route for the valorisation of this type of wastes. Finally, a techno-economic analysis for a commercial TCR3000 plant suggests that the technology is affordable and suitable to be commercialised

Thermo-catalytic reforming (TCR) of waste solid grade laminate

Thermo-catalytic reforming (TCR) is defined as intermediate pyrolysis at moderate temperatures and heating rates with subsequent reforming at elevated temperatures using biochar as a catalyst. TCR experiments were carried out to pyrolyze and subsequently reform Solid Grade Laminate (SGL) waste. SGL is a Kraft paper-derived product and as it is widely used in many applications, high volumes of waste laminate must be disposed of at end of life. To assess TCR for SGL waste treatment, the characterisation of the initial feedstock was accomplished, and it concluded that SGL is suitable to be processed via TCR. The main energy carrier products (char, oil and syngas) were generated by TCR in a 2 kg/h pilot-scale reactor under a pyrolysis temperature of 500 °C and reforming temperature of 650 °C, respectively. The mass balance analysis demonstrated that 50 wt% of the initial feedstock was comprehensively converted to syngas, 28 wt% to char and 22 wt% to a liquid fraction containing both water (17 wt%) and organics (5 wt%). The oil showed good properties as its HHV reached a value of 32.72 MJ/kg, with low oxygen and sulphur contents. However further processing is required for the fuels to be within suitable limits for use as drop-in fuels for vehicles. The syngas was found to be rich in hydrogen especially when pyrolysis temperature reaches its maximum. Lastly, char revealed a calorific value of 25.94 MJ/kg and was of a stable form of carbon, exhibiting potential as a feedstock for gasification or as a carbon capture and storage medium. TCR of SGL represents novelty as this feedstock has not been tested before in a pyrolysis/reforming system and it is a promising route in an optic of circularity. In waste valorisation, TCR oil has a great opportunity to be used as a fuel or blended with other conventional fuels, thus supporting the shift towards more sustainable mobility

Athletes and Coaches through the COVID-19 Pandemic: A Qualitative View of Goal Management

Since the end of 2019 and throughout 2020, the world has been devastated by the COVID-19 pandemic. The sports world suddenly had to deal with a massive reorganization of events with important implications for the physical and psychological preparation of athletes and coaches. The purpose of this study was to explore how these changes impacted coaches’ and athletes’ goal-setting strategies and their experience of goal adjustment. As part of a wider mixed-method project involving 2162 coaches and 1354 athletes, an online qualitative survey was used, and data collected were analyzed using reflexive thematic analysis. Findings highlighted three overarching themes, in response to goal adjustment: “Moving on toward new goals”, “Letting go of goals”, and “Trying to hold on”, with several themes and sub-themes identifying different nuances of athletes’ and coaches’ experiences. The implications of such findings for the mental preparation of high-level athletes are discussed in two ways. Firstly, in light of existing literature on goal setting from an applied perspective; secondly, in the broader perspective of the sports culture and the application of our themes to other challenging moments that sports professionals might encounter

Adherence issues related to sublingual immunotherapy as perceived by allergists

Objectives: Sublingual immunotherapy (SLIT) is a viable alternative to subcutaneous immunotherapy to treat allergic rhinitis and asthma, and is widely used in clinical practice in many European countries. The clinical efficacy of SLIT has been established in a number of clinical trials and meta-analyses. However, because SLIT is self-administered by patients without medical supervision, the degree of patient adherence with treatment is still a concern. The objective of this study was to evaluate the perception by allergists of issues related to SLIT adherence. Methods: We performed a questionnaire-based survey of 296 Italian allergists, based on the adherence issues known from previous studies. The perception of importance of each item was assessed by a VAS scale ranging from 0 to 10. Results: Patient perception of clinical efficacy was considered the most important factor (ranked 1 by 54% of allergists), followed by the possibility of reimbursement (ranked 1 by 34%), and by the absence of side effects (ranked 1 by 21%). Patient education, regular follow-up, and ease of use of SLIT were ranked first by less than 20% of allergists. Conclusion: These findings indicate that clinical efficacy, cost, and side effects are perceived as the major issues influencing patient adherence to SLIT, and that further improvement of adherence is likely to be achieved by improving the patient information provided by prescribers. © 2010 Scurati et al, publisher and licensee Dove Medical Press Ltd

Optimasi Portofolio Resiko Menggunakan Model Markowitz MVO Dikaitkan dengan Keterbatasan Manusia dalam Memprediksi Masa Depan dalam Perspektif Al-Qur`an

Risk portfolio on modern finance has become increasingly technical, requiring the use of sophisticated mathematical tools in both research and practice. Since companies cannot insure themselves completely against risk, as human incompetence in predicting the future precisely that written in Al-Quran surah Luqman verse 34, they have to manage it to yield an optimal portfolio. The objective here is to minimize the variance among all portfolios, or alternatively, to maximize expected return among all portfolios that has at least a certain expected return. Furthermore, this study focuses on optimizing risk portfolio so called Markowitz MVO (Mean-Variance Optimization). Some theoretical frameworks for analysis are arithmetic mean, geometric mean, variance, covariance, linear programming, and quadratic programming. Moreover, finding a minimum variance portfolio produces a convex quadratic programming, that is minimizing the objective function ðð¥with constraintsð ð 𥠥 ðandð´ð¥ = ð. The outcome of this research is the solution of optimal risk portofolio in some investments that could be finished smoothly using MATLAB R2007b software together with its graphic analysis

Differential cross section measurements for the production of a W boson in association with jets in proton–proton collisions at √s = 7 TeV

Measurements are reported of differential cross sections for the production of a W boson, which decays into a muon and a neutrino, in association with jets, as a function of several variables, including the transverse momenta (pT) and pseudorapidities of the four leading jets, the scalar sum of jet transverse momenta (HT), and the difference in azimuthal angle between the directions of each jet and the muon. The data sample of pp collisions at a centre-of-mass energy of 7 TeV was collected with the CMS detector at the LHC and corresponds to an integrated luminosity of 5.0 fb[superscript −1]. The measured cross sections are compared to predictions from Monte Carlo generators, MadGraph + pythia and sherpa, and to next-to-leading-order calculations from BlackHat + sherpa. The differential cross sections are found to be in agreement with the predictions, apart from the pT distributions of the leading jets at high pT values, the distributions of the HT at high-HT and low jet multiplicity, and the distribution of the difference in azimuthal angle between the leading jet and the muon at low values.United States. Dept. of EnergyNational Science Foundation (U.S.)Alfred P. Sloan Foundatio

Penilaian Kinerja Keuangan Koperasi di Kabupaten Pelalawan

This paper describe development and financial performance of cooperative in District Pelalawan among 2007 - 2008. Studies on primary and secondary cooperative in 12 sub-districts. Method in this stady use performance measuring of productivity, efficiency, growth, liquidity, and solvability of cooperative. Productivity of cooperative in Pelalawan was highly but efficiency still low. Profit and income were highly, even liquidity of cooperative very high, and solvability was good

Juxtaposing BTE and ATE – on the role of the European insurance industry in funding civil litigation

One of the ways in which legal services are financed, and indeed shaped, is through private insurance arrangement. Two contrasting types of legal expenses insurance contracts (LEI) seem to dominate in Europe: before the event (BTE) and after the event (ATE) legal expenses insurance. Notwithstanding institutional differences between different legal systems, BTE and ATE insurance arrangements may be instrumental if government policy is geared towards strengthening a market-oriented system of financing access to justice for individuals and business. At the same time, emphasizing the role of a private industry as a keeper of the gates to justice raises issues of accountability and transparency, not readily reconcilable with demands of competition. Moreover, multiple actors (clients, lawyers, courts, insurers) are involved, causing behavioural dynamics which are not easily predicted or influenced. Against this background, this paper looks into BTE and ATE arrangements by analysing the particularities of BTE and ATE arrangements currently available in some European jurisdictions and by painting a picture of their respective markets and legal contexts. This allows for some reflection on the performance of BTE and ATE providers as both financiers and keepers. Two issues emerge from the analysis that are worthy of some further reflection. Firstly, there is the problematic long-term sustainability of some ATE products. Secondly, the challenges faced by policymakers that would like to nudge consumers into voluntarily taking out BTE LEI