Ligand design and preparation, photophysical properties, and device performance of an encapsulated-type pseudo-tris(heteroleptic) iridium(iii) emitter

The organic molecule 2-(1-phenyl-1-(pyridin-2-yl)ethyl)-6-(3-(1-phenyl-1-(pyridin-2-yl)ethyl)phenyl)pyridine (H3L) has been designed, prepared, and employed to synthesize the encapsulated-type pseudo-tris(heteroleptic) iridium(III) derivative Ir(κ6-fac-C,C′,C″-fac-N,N′,N″-L). Its formation takes place as a result of the coordination of the heterocycles to the iridium center and the ortho-CH bond activation of the phenyl groups. Dimer [Ir(μ-Cl)(η4-COD)]2 is suitable for the preparation of this compound of class [Ir(9h)] (9h = 9-electron donor hexadentate ligand), but Ir(acac)3 is a more appropriate starting material. Reactions were carried out in 1-phenylethanol. In contrast to the latter, 2-ethoxyethanol promotes the metal carbonylation, inhibiting the full coordination of H3L. Complex Ir(κ6-fac-C,C′,C″-fac-N,N′,N″-L) is a phosphorescent emitter upon photoexcitation, which has been employed to fabricate four yellow emitting devices with 1931 CIE (x:y) ∼ (0.52:0.48) and a maximum wavelength at 576 nm. These devices display luminous efficacies, external quantum efficiencies, and power efficacies at 600 cd m–2, which lie in the ranges 21.4–31.3 cd A–1, 7.8–11.3%, and 10.2–14.1 lm W1–, respectively, depending on the device configuration

<i>Gaia</i> Data Release 1. Summary of the astrometric, photometric, and survey properties

Context. At about 1000 days after the launch of Gaia we present the first Gaia data release, Gaia DR1, consisting of astrometry and photometry for over 1 billion sources brighter than magnitude 20.7. Aims. A summary of Gaia DR1 is presented along with illustrations of the scientific quality of the data, followed by a discussion of the limitations due to the preliminary nature of this release. Methods. The raw data collected by Gaia during the first 14 months of the mission have been processed by the Gaia Data Processing and Analysis Consortium (DPAC) and turned into an astrometric and photometric catalogue. Results. Gaia DR1 consists of three components: a primary astrometric data set which contains the positions, parallaxes, and mean proper motions for about 2 million of the brightest stars in common with the HIPPARCOS and Tycho-2 catalogues – a realisation of the Tycho-Gaia Astrometric Solution (TGAS) – and a secondary astrometric data set containing the positions for an additional 1.1 billion sources. The second component is the photometric data set, consisting of mean G-band magnitudes for all sources. The G-band light curves and the characteristics of ∼3000 Cepheid and RR-Lyrae stars, observed at high cadence around the south ecliptic pole, form the third component. For the primary astrometric data set the typical uncertainty is about 0.3 mas for the positions and parallaxes, and about 1 mas yr−1 for the proper motions. A systematic component of ∼0.3 mas should be added to the parallax uncertainties. For the subset of ∼94 000 HIPPARCOS stars in the primary data set, the proper motions are much more precise at about 0.06 mas yr−1. For the secondary astrometric data set, the typical uncertainty of the positions is ∼10 mas. The median uncertainties on the mean G-band magnitudes range from the mmag level to ∼0.03 mag over the magnitude range 5 to 20.7. Conclusions. Gaia DR1 is an important milestone ahead of the next Gaia data release, which will feature five-parameter astrometry for all sources. Extensive validation shows that Gaia DR1 represents a major advance in the mapping of the heavens and the availability of basic stellar data that underpin observational astrophysics. Nevertheless, the very preliminary nature of this first Gaia data release does lead to a number of important limitations to the data quality which should be carefully considered before drawing conclusions from the data

Gaia Data Release 2: Calibration and mitigation of electronic offset effects in the data

The European Space Agency Gaia satellite was launched into orbit around L2 in December 2013. This ambitious mission has strict requirements on residual systematic errors resulting from instrumental corrections in order to meet a design goal of sub-10 microarcsecond astrometry. During the design and build phase of the science instruments, various critical calibrations were studied in detail to ensure that this goal could be met in orbit. In particular, it was determined that the video-chain offsets on the analogue side of the analogue-to-digital conversion electronics exhibited instabilities that could not be mitigated fully by modifications to the flight hardware. We provide a detailed description of the behaviour of the electronic offset levels on microsecond timescales, identifying various systematic effects that are known collectively as offset non-uniformities. The effects manifest themselves as transient perturbations on the gross zero-point electronic offset level that is routinely monitored as part of the overall calibration process. Using in-orbit special calibration sequences along with simple parametric models, we show how the effects can be calibrated, and how these calibrations are applied to the science data. While the calibration part of the process is relatively straightforward, the application of the calibrations during science data processing requires a detailed on-ground reconstruction of the readout timing of each charge-coupled device (CCD) sample on each device in order to predict correctly the highly time-dependent nature of the corrections. We demonstrate the effectiveness of our offset non-uniformity models in mitigating the effects in Gaia data. We demonstrate for all CCDs and operating instrument and modes on board Gaia that the video-chain noise-limited performance is recovered in the vast majority of science samples

Spectrophotometry of the Khonsu region on the comet 67P/Churyumov-Gerasimenko using OSIRIS instrument images

Our work focuses on the spectrophotometric analysis of selected terrain and bright patches in the Khonsu region on the comet 67P/Churyumov-Gerasimenko. Despite the variety of geological features, their spectrophotometric properties appear to indicate a similar composition. It is noticeable that the smooth areas in Khonsu possess similar spectrophotometric behaviour to some other regions of the comet. We observed bright patches on Khonsu with an estimation of &gt; 40 per cent of normal albedo and suggest that they are associated with H2O ice. One of the studied bright patches has been observed to exist on the surface for more than 5 months without a major decay of its size, implying the existence of potential sub-surface icy layers. Its location may be correlated with a cometary outburst during the perihelion passage of the comet in 2015 August, and we interpret it to have triggered the surface modifications necessary to unearth the stratified icy layers beneath the surface. A boulder analysis on Khonsu leads to a power-law index of -3.1 +0.2/-0.3 suggesting a boulder formation, shaped by varying geological processes for different morphological units

Exposed bright features on the comet 67P/Churyumov-Gerasimenko: Distribution and evolution

Context. Since its arrival at the comet 67P/Churyumov-Gerasimenko in August 2014, the Rosetta spacecraft followed the comet as it went past the perihelion and beyond until September 2016. During this time there were many scientific instruments operating on board Rosetta to study the comet and its evolution in unprecedented detail. In this context, our study focusses on the distribution and evolution of exposed bright features that have been observed by OSIRIS, which is the scientific imaging instrument aboard Rosetta. Aims. We envisage investigating various morphologies of exposed bright features and the mechanisms that triggered their appearance. Methods. We co-registered multi-filter observations of OSIRIS images that are available in reflectance. The Lommel-Seeliger disk function was used to correct for the illumination conditions and the resulting colour cubes were used to perform spectrophotometric analyses on regions of interest. Results. We present a catalogue of 57 exposed bright features observed on the nucleus of the comet, all of which are attributed to the presence of H2O ice on the comet. Furthermore, we categorise these patches under four different morphologies and present geometric albedos for each category. Conclusions. Although the nucleus of 67P/Churyumov-Gerasimenko appears to be dark in general, there are localised H2O ice sources on the comet. Cometary activity escalates towards the perihelion passage and reveals such volatile ices. We propose that isolated H2O ice patches found in smooth terrains in regions, such as Imhotep, Bes, and Hapi, result from frost as an aftermath of the cessation of the diurnal water cycle on the comet as it recedes from perihelion. Upon the comet's return to perihelion, such patches are revealed when sublimation-driven erosion removes the thin dust layers that got deposited earlier. More powerful activity sources such as cometary outbursts are capable of revealing much fresher, less contaminated H2O ice that is preserved with consolidated cometary material, as observed on exposed patches resting on boulders. This is corroborated by our albedo calculations that attribute higher albedos for bright features with formations related to outbursts

Acceleration of individual, decimetre-sized aggregates in the lower coma of comet 67P/Churyumov-Gerasimenko

We present observations of decimetre-sized, likely ice-containing aggregates ejected from a confined region on the surface of comet 67P/Churyumov-Gerasimenko. The images were obtained with the narrow angle camera of the Optical, Spectroscopic, and Infrared Remote Imaging System on board the Rosetta spacecraft in 2016 January when the comet was at 2 au from the Sun outbound from perihelion.We measure the acceleration of individual aggregates through a 2 h image series. Approximately 50 per cent of the aggregates are accelerated away from the nucleus, and 50 per cent towards it, and likewise towards either horizontal direction. The accelerations are up to one order of magnitude stronger than local gravity, and are most simply explained by the combined effect of gas drag accelerating all aggregates upwards, and the recoil force from asymmetric outgassing, either from rotating aggregates with randomly oriented spin axes and sufficient thermal inertia to shift the temperature maximum away from an aggregate's subsolar region, or from aggregates with variable ice content. At least 10 per cent of the aggregates will escape the gravity field of the nucleus and feed the comet's debris trail, while others may fall back to the surface and contribute to the deposits covering parts of the Northern hemisphere. The rocket force plays a crucial role in pushing these aggregates back towards the surface. Our observations show the future back fall material in the process of ejection, and provide the first direct measurement of the acceleration of aggregates in the innermost coma (&lt;2 km) of a comet, where gas drag is still significant

Constraints on cometary surface evolution derived from a statistical analysis of 67P's topography

We present a statistical analysis of the distribution of large-scale topographic features on comet 67P/Churyumov-Gerasimenko.We observe that the cumulative cliff height distribution across the surface follows a power law with a slope equal to -1.69 ± 0.02. When this distribution is studied independently for each region, we find a good correlation between the slope of the power law and the orbital erosion rate of the surface. For instance, the Northern hemisphere topography is dominated by structures on the 100 m scale, while the Southern hemisphere topography, illuminated at perihelion, is dominated by 10 m scale terrain features. Our study suggests that the current size of a cliff is controlled not only by material cohesion but also by the dominant erosional process in each region. This observation can be generalized to other comets, where we argue that primitive nuclei are characterized by the presence of large cliffs with a cumulative height-power index equal to or above -1.5, while older, eroded cometary surfaces have a power index equal to or below -2.3. In effect, our model shows that a measure of the topography provides a quantitative assessment of a comet's erosional history, that is, its evolutionary age. © 2017 The Authors Published by Oxford University Press on behalf of the Royal Astronomical Society

Geomorphological and spectrophotometric analysis of Seth's circular niches on comet 67P/Churyumov-Gerasimenko using OSIRIS images

We provide a detailed geomorphological and spectrophotometric analysis of the circular niches located on the Seth region of 67P using OSIRIS images. The features can be related to landslide events that occurred on 67P and shaped its surface, as the recent Aswan cliff collapse detected in the same region. We therefore provide an analysis of the area pre- and post-perihelion suggesting that no specific changes have been observed. To assess this, after performing a geomorphological map of the area that allows us to identify different terrain units, we computed the boulders cumulative size frequency distribution (SFD) of the niches, before and after the perihelion passage. The niches SFDs are characterized by a similar trend with two different power-law indices within the same deposit: lower power-law value (between -2.3 and -2.7) for boulders smaller than 5 m and steeper power-law value (between -4.7 and -5.0) for boulders larger than 5 m. These trends suggest that smaller boulders have evolved and progressively have been depleted (lower power-law index), while bigger boulders are more representative of the event that generated the deposit and are less degraded. Then, we perform the spectrophotometric analysis of this region comparing pre- and post-perihelion results. We found colour changes within the area, in particular brighter patches related to the presence of exposed water ice mixed to the refractory materials have been detected in the post-perihelion images

Characterization of dust aggregates in the vicinity of the Rosetta spacecraft

In a Rosetta/OSIRIS imaging activity in 2015 June, we have observed the dynamic motion of particles close to the spacecraft. Due to the focal setting of the OSIRIS wide angle camera, these particles were blurred, which can be used to measure their distances to the spacecraft. We detected 109 dust aggregates over a 130 min long sequence, and find that their sizes are around a millimetre and their distances cluster between 2 and 40 m from the spacecraft. Their number densities are about a factor 10 higher than expected for the overall coma and highly fluctuating. Their velocities are small compared to the spacecraft orbital motion and directed away from the spacecraft, towards the comet. From this we conclude that they have interacted with the spacecraft and assess three possible scenarios. In the likeliest of the three scenarios, centimetre-sized aggregates collide with the spacecraft and we would observe the fragments. Ablation of a dust layer on the spacecraft's z panel (remote instrument viewing direction) when rotated towards the Sun is a reasonable alternative. We could also measure an acceleration for a subset of 18 aggregates, which is directed away from the Sun and can be explain by a rocket effect, which requires a minimum ice fraction of the order of 0.1 per cent

Thermal modelling of water activity on comet 67P/Churyumov-Gerasimenko with global dust mantle and plural dust-to-ice ratio

We perform a thermo-physical analysis on water activity of comet 67P/Churyumov- Gerasimenko (67P). The sublimation of water is assumed to occur from beneath a global, desiccated dust mantle over the irregular-shaped nucleus. The concept of two thermal models, the recipe of model formulation and the strategy of application to comet 67P are described. For an accurate and efficient evaluation of energy input by insolation and self-heating over the nucleus, a Landscape data base is devised based on polyhedral shape models of the nucleus. We apply the thermal models to investigate the impact of certain parameters of nucleus properties on water production. It is found that the measured water production of 67P can be overall attributed to sublimation of water ice with a mass abundance of a few to 10 per cent beneath a uniform dust mantle of several millimetres to one centimetre in thickness. Insofar as 67P is concerned, we argue against the necessity to invoke assumptions on localized water activity, or on the distinction of active/dormant surface areas