Reversible water induced phase changes of cobalt oxide nanoparticles

Cobalt oxides have been identified as highly active catalysts for the electrochemical water splitting and oxygen evolution reaction. Using near ambient pressure resonant photoelectron spectroscopy, we studied changes in the metal amp; 8722;oxygen coordination of size selected core amp; 8722;shell CoOx nanoparticles induced by liquid water. Indry conditions, the nanoparticles exhibit an octahedrally coordinated Co2 core and a tetrahedrally coordinated Co2 shell. In the presence of liquid water, we observe a reversible phase change of the nanoparticle shell into octahedrally coordinated Co2 as well as partially oxidized octahedrally coordinated Co3 . This is in contrast to previous findings, suggesting an irreversible phase change of tetrahedrally coordinated Co2 after the oxygen evolution reaction conditioning. Our results demonstrate the appearance of water induced structural changes different from voltage induced changes and help us to understand the atomic scale interaction of CoOx nanoparticles with water in electrochemical processe

Ghost Condensation and a Consistent Infrared Modification of Gravity

We propose a theoretically consistent modification of gravity in the infrared, which is compatible with all current experimental observations. This is an analog of Higgs mechanism in general relativity, and can be thought of as arising from ghost condensation--a background where a scalar field \phi has a constant velocity, = M^2. The ghost condensate is a new kind of fluid that can fill the universe, which has the same equation of state, \rho = -p, as a cosmological constant, and can hence drive de Sitter expansion of the universe. However, unlike a cosmological constant, it is a physical fluid with a physical scalar excitation, which can be described by a systematic effective field theory at low energies. The excitation has an unusual low-energy dispersion relation \omega^2 \sim k^4 / M^2. If coupled to matter directly, it gives rise to small Lorentz-violating effects and a new long-range 1/r^2 spin dependent force. In the ghost condensate, the energy that gravitates is not the same as the particle physics energy, leading to the possibility of both sources that can gravitate and antigravitate. The Newtonian potential is modified with an oscillatory behavior starting at the distance scale M_{Pl}/M^2 and the time scale M_{Pl}^2/M^3. This theory opens up a number of new avenues for attacking cosmological problems, including inflation, dark matter and dark energy.Comment: 42 pages, LaTeX 2

Three-spined stickleback armour predicted by body size, minimum winter temperature and pH

Similar phenotypes evolve under equivalent environmental conditions through parallel evolution. Because they have repeatedly invaded and adapted to new freshwater environments, the three-spined stickleback (Gasterosteus aculeatus) offers a powerful system for understanding the agents of selection in nature that drive parallel evolution. Here we examine the ecological and environmental variables responsible for morphological variation in three-spined stickleback populations across its European range. We collected fish from 85 populations, encompassing much of the European latitudinal range of the species and including lowland rivers and lakes, coastal lagoons, and moorland ponds. We measured biotic and environmental variables at all sites along with morphological traits for 2,358 individuals. Using an information theory approach, we identified body size, minimum average winter temperature and pH as primary predictors of stickleback armour evolution, challenging current hypotheses for stickleback morphological diversification and demonstrating the fundamental role played by body size and scaling in mediating responses to selection. Stickleback lateral plate phenotype represents a potentially powerful tool for monitoring change in climate variables across the northern temperate region

Reconstruction of Longitudinal Profiles of Ultra-High Energy Cosmic Ray Showers from Fluorescence and Cherenkov Light Measurements

We present a new method for the reconstruction of the longitudinal profile of extensive air showers induced by ultra-high energy cosmic rays. In contrast to the typically considered shower size profile, this method employs directly the ionization energy deposit of the shower particles in the atmosphere. Due to universality of the energy spectra of electrons and positrons, both fluorescence and Cherenkov light can be used simultaneously as signal to infer the shower profile from the detected light. The method is based on an analytic least-square solution for the estimation of the shower profile from the observed light signal. Furthermore, the extrapolation of the observed part of the profile with a Gaisser-Hillas function is discussed and the total statistical uncertainty of shower parameters like total energy and shower maximum is calculated.Comment: accepted by NIM

Quantum coherence in a degenerate two-level atomic ensemble: for a transition Fe=0↔Fg=1F_e=0\leftrightarrow F_g=1

For a transition $F_e=0\leftrightarrow F_g=1$ driven by a linearly polarized light and probed by a circularly light, quantum coherence effects are investigated. Due to the coherence between the drive Rabi frequency and Zeeman splitting, electromagnetically induced transparency, electromagnetically induced absorption, and the transition from positive to negative dispersion are obtained, as well as the populations coherently oscillating in a wide spectral region. At the zero pump-probe detuning, the subluminal and superluminal light propagation is predicted. Finally, coherent population trapping states are not highly sensitive to the refraction and absorption in such ensemble.Comment: 9 pages, 6 figure

Measurement of the D+ and Ds+ decays into K+K-K+

We present the first clear observation of the doubly Cabibbo suppressed decay D+ --> K-K+K+ and the first observation of the singly Cabibbo suppressed decay Ds+ --> K-K+K+. These signals have been obtained by analyzing the high statistics sample of photoproduced charm particles of the FOCUS(E831) experiment at Fermilab. We measure the following relative branching ratios: Gamma(D+ --> K-K+K+)/Gamma(D+ --> K-pi+pi+) = (9.49 +/- 2.17(statistical) +/- 0.22(systematic))x10^-4 and Gamma(Ds+ --> K-K+K+)/Gamma(Ds+ --> K-K+pi+) = (8.95 +/- 2.12(statistical) +2.24(syst.) -2.31(syst.))x10^-3.Comment: 10 pages, 8 figure

The exposure of the hybrid detector of the Pierre Auger Observatory

The Pierre Auger Observatory is a detector for ultra-high energy cosmic rays. It consists of a surface array to measure secondary particles at ground level and a fluorescence detector to measure the development of air showers in the atmosphere above the array. The "hybrid" detection mode combines the information from the two subsystems. We describe the determination of the hybrid exposure for events observed by the fluorescence telescopes in coincidence with at least one water-Cherenkov detector of the surface array. A detailed knowledge of the time dependence of the detection operations is crucial for an accurate evaluation of the exposure. We discuss the relevance of monitoring data collected during operations, such as the status of the fluorescence detector, background light and atmospheric conditions, that are used in both simulation and reconstruction.Comment: Paper accepted by Astroparticle Physic

Anisotropy studies around the galactic centre at EeV energies with the Auger Observatory

Data from the Pierre Auger Observatory are analyzed to search for anisotropies near the direction of the Galactic Centre at EeV energies. The exposure of the surface array in this part of the sky is already significantly larger than that of the fore-runner experiments. Our results do not support previous findings of localized excesses in the AGASA and SUGAR data. We set an upper bound on a point-like flux of cosmic rays arriving from the Galactic Centre which excludes several scenarios predicting sources of EeV neutrons from Sagittarius $A$. Also the events detected simultaneously by the surface and fluorescence detectors (the `hybrid' data set), which have better pointing accuracy but are less numerous than those of the surface array alone, do not show any significant localized excess from this direction.Comment: Matches published versio

Evidence for a mixed mass composition at the `ankle' in the cosmic-ray spectrum

We report a first measurement for ultra-high energy cosmic rays of the correlation between the depth of shower maximum and the signal in the water Cherenkov stations of air-showers registered simultaneously by the fluorescence and the surface detectors of the Pierre Auger Observatory. Such a correlation measurement is a unique feature of a hybrid air-shower observatory with sensitivity to both the electromagnetic and muonic components. It allows an accurate determination of the spread of primary masses in the cosmic-ray flux. Up till now, constraints on the spread of primary masses have been dominated by systematic uncertainties. The present correlation measurement is not affected by systematics in the measurement of the depth of shower maximum or the signal in the water Cherenkov stations. The analysis relies on general characteristics of air showers and is thus robust also with respect to uncertainties in hadronic event generators. The observed correlation in the energy range around the `ankle' at $\lg(E/{\rm eV})=18.5-19.0$ differs significantly from expectations for pure primary cosmic-ray compositions. A light composition made up of proton and helium only is equally inconsistent with observations. The data are explained well by a mixed composition including nuclei with mass $A > 4$. Scenarios such as the proton dip model, with almost pure compositions, are thus disfavoured as the sole explanation of the ultrahigh-energy cosmic-ray flux at Earth.Comment: Published version. Added journal reference and DOI. Added Report Numbe

\pi^0 \pi^0 Production in Proton-Proton Collisions at Tp=1.4 GeV

The reaction pp->pppi0pi0 has been investigated at a beam energy of 1.4 GeV using the WASA-at-COSY facility. The total cross section is found to be (324 +- 21_systematic +- 58_normalization) mub. In order to to study the production mechanism, differential kinematical distributions have been evaluated. The differential distributions indicate that both initial state protons are excited into intermediate Delta(1232) resonances, each decaying into a proton and a single pion, thereby producing the pion pair in the final state. No significant contribution of the Roper resonance N*(1440) via its decay into a proton and two pions is foundComment: Submitted to PL