Sliding friction of polyethylene on ice: tribometer measurements

: It is well known that the low kinetic friction experienced when sliding on snow and ice is due to water films generated through frictional heating. There is, however, uncertainty concerning the thickness and the distribution of these water films. Since direct observation of the water films is difficult, tribometer studies coupled with temperature measurements have been carried out on a large-scale, pin-on-disc tribometer (diameter 1.80m). IR sensors were used to measure the temperature of the ice track in front of and behind the contact region. In addition, thermocouples integrated into the polyethylene slider measured the temperature close to the interface. The kinetic friction between polyethylene and ice has been measured as a function of temperature, velocity, load, and apparent contact area. The friction coefficient, as well as the temperature increase of the slider and the ice track, depends on all of these parameters. Interpretation of the results is given on the basis of hydrodynamic lubrication, taking into account the generation and shearing of thin water films in the contact region

Surface reactivity of tributyl thiophosphate: effects of temperature and mechanical stress

The surface reactivity of tributyl thiophosphate on iron surfaces has been studied in situ by attenuated total reflection Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy and temperature-programmed reaction and desorption spectroscopies. The results show that at temperatures lower than 373K the molecule forms a physisorbed layer on the iron substrate. At 373K a reaction takes place with the formation of an organic layer, together with iron polyphosphate and sulfate. At higher temperatures temperature-programmed desorption results suggest that the mechanism involves P-O bond scission to yield butoxy groups. This could be preceded by P=S bond scission to give tributyl phosphite, which then, in turn, undergoes P-O bond scission to produce butoxy groups. The results obtained following tribological testing are in agreement with those of thermal tests: evidence of polyphosphate and sulfate formation is foun

Self-healing behavior of a polyelectrolyte-based lubricant additive for aqueous lubrication of oxide materials

We report on the self-healing behavior of a polyelectrolyte-based aqueous lubricant additive, poly(l-lysine)-graft-poly(ethylene glycol) (PLL-g-PEG), during aqueous lubrication of an oxide-based tribosystem. Combined pin-on-disk tribometry and fluorescence microscopy experiments have shown that stable lubricating performance was enabled by means of rapid healing of the worn tribopair surface by polymers dissolved in the adjoining bulk lubricant. This rapid ‘self-healing' of PLL-g-PEG is attributed to electrostatic interactions between the polycationic poly(l-lysine) (PLL) backbone of the polymer and negatively charged oxide surface. In contrast, a similar healing effect was not readily achievable in the case of methoxy-poly(ethylene glycol)-trimethylsilylether (Sil-PEG), a lubricant additive that is covalently bonded to the surface prior to tribological stres

Influence of water on tribolayer growth when lubricating steel with a fluorinated phosphonium dicyanamide ionic liquid

This work aims to elucidate the role of environmental humidity on the tribological behavior of steel surfaces lubricated with an ionic liquid comprised of a fluorinated phosphonium cation-tributyl-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl-phosphonium-and a dicyanamide anion (i.e. N(CN) 2 - ). Ball-on-disk tribotests were carried out at room temperature and at various levels of relative humidity (RH). Water was found to be required to promote the formation of a tribofilm over the contact area. The reaction layer exhibited a patchy morphology, which resembles that observed formed with conventional antiwear additives such as ZnDTP. A surface-chemical analysis of the tribofilm indicated that the tribofilm is composed of fluorides, oxides, and phosphates, pointing to a stress-induced degradation of the ions and corrosion of the sliding counterparts, which is enabled by the presence of water at the sliding interface. © 2019 by the authors

Elastic Chain in a Random Potential: Simulation of the Displacement Function <(u(x)−u(0))2><(u(x)-u(0))^2> and Relaxation

We simulate the low temperature behaviour of an elastic chain in a random potential where the displacements $u(x)$ are confined to the {\it longitudinal} direction ($u(x)$ parallel to $x$) as in a one dimensional charge density wave--type problem. We calculate the displacement correlation function $g(x)=< (u(x)-u(0))^2>$ and the size dependent average square displacement $W(L)=$. We find that $g(x)\sim x^{2\eta}$ with $\eta\simeq3/4$ at short distances and $\eta\simeq3/5$ at intermediate distances. We cannot resolve the asymptotic long distance dependence of $g$ upon $x$. For the system sizes considered we find $g(L/2)\propto W\sim L^{2\chi}$ with $\chi\simeq2/3$. The exponent $\eta\simeq3/5$ is in agreement with the Random Manifold exponent obtained from replica calculations and the exponent $\chi\simeq2/3$ is consistent with an exact solution for the chain with {\it transverse} displacements ($u(x)$ perpendicular to $x$).The distribution of nearest distances between pinning wells and chain-particles is found to develop forbidden regions.Comment: 19 pages of LaTex, 6 postscript figures available on request, submitted to Journal of Physics A, MAJOR CHANGE

Surface activation of polyetheretherketone (PEEK) and formation of calcium phosphate coatings by precipitation

Plasma activation of polyetheretherketone (PEEK) surfaces and the influence on coating formation in a supersaturated calcium phosphate solution was investigated in this study. It was observed that plasma treatment in a N2/O2 plasma had a significant effect on the wettability of the PEEK surface. The contact angle decreased from 85° to 25° after plasma treatment. Cell culture testing with osteoblastic cell lines showed plasma activation not to be disadvantageous to cell viability. X-ray photoelectron spectroscopy (XPS) analysis was performed to characterize the chemical composition of the PEEK surfaces. It was observed that the O1s intensity increased with plasma activation time. At the C1s peak the appearance of a shoulder at higher binding energies was observed. Coating of PEEK was performed in a supersaturated calcium phosphate solution. Coating thicknesses of up to 50 μm were achieved after 24 days of immersion. Plasma activation followed by nucleation in a highly saturated hydroxyapatite solution had a positive effect on the growth rate of the layer on PEEK. Chemical analysis revealed that the coating consists of a carbonate-containing calcium phosphat

Measurement of the polarisation of W bosons produced with large transverse momentum in pp collisions at sqrt(s) = 7 TeV with the ATLAS experiment

This paper describes an analysis of the angular distribution of W->enu and W->munu decays, using data from pp collisions at sqrt(s) = 7 TeV recorded with the ATLAS detector at the LHC in 2010, corresponding to an integrated luminosity of about 35 pb^-1. Using the decay lepton transverse momentum and the missing transverse energy, the W decay angular distribution projected onto the transverse plane is obtained and analysed in terms of helicity fractions f0, fL and fR over two ranges of W transverse momentum (ptw): 35 < ptw < 50 GeV and ptw > 50 GeV. Good agreement is found with theoretical predictions. For ptw > 50 GeV, the values of f0 and fL-fR, averaged over charge and lepton flavour, are measured to be : f0 = 0.127 +/- 0.030 +/- 0.108 and fL-fR = 0.252 +/- 0.017 +/- 0.030, where the first uncertainties are statistical, and the second include all systematic effects.Comment: 19 pages plus author list (34 pages total), 9 figures, 11 tables, revised author list, matches European Journal of Physics C versio