EFFECTS OF HEAT-FLOW AND HYDROTHERMAL FLUIDS FROM VOLCANIC INTRUSIONS ON AUTHIGENIC MINERALIZATION IN SANDSTONE FORMATIONS

Volcanic intrusions and hydrothermal activity have modified the diagenetic minerals. In the Ulster Basin, UK, most of the authigenic mineralization in the Permo-Triassic sandstones pre-dated tertiary volcanic intrusions. The hydrothermal fluids and heat-flow from the volcanic intrusions did not affect quartz and feldspar overgrowths. However, clay mineral-transformation, illite-smectite to illite and chlorite was documented near the volcanic intrusions. Abundant actinolite, illite, chlorite, albite and laumontite cementation of the sand grains were also documented near the volcanic intrusions. The abundance of these cementing minerals decreases away from the volcanic intrusions. In the Hartford Basin, USA, the emplacement of the volcanic intrusions took place simultaneous with sedimentation. The heat-flow from the volcanic intrusions and hydrothermal activity related to the volcanics modified the texture of authigenic minerals. Microcrystalline mosaic albite and quartz developed rather than overgrowths and crystals near the intrusions. Chlorite clumps and masses were also documented with microcrystalline mosaic albite and quartz. These features are localized near the basaltic intrusions. Laumontite is also documented near the volcanic intrusions. The reservoir characteristics of the studied sandstone formations are highly affected by the volcanic and hydrothermal fluids in the Hartford and the Ulster Basin. The porosity dropped from 27.4 to zero percent and permeability from 1350 mD to 1 mD. (Received December 8, 2000; revised April 26, 2002) Bull. Chem. Soc. Ethiop. 2002, 16(1), 37-52

DIAGENESIS AND MASS TRANSFER BETWEEN PERMO-TRIASSIC SANDSTONES AND INTERBEDDED MUDSTONES, ULSTER BASIN

Beds of siltstone, mudstone and shale are interbedded in the Permo-Triassic sandstones of the Ulster Basin, UK, at different stratigraphic levels. The paragenetic sequences of authigenic minerals both in the sandy and fine-grained sediments (mudstones and siltstones) indicate red bed diagenetic trend. Abundant authigenic quartz overgrowths and carbonate crystals observed near the sandstone-siltstone and sandstone-mudstone contacts, indicating that pore water and mass transfer from the fine-grained sediments to sandstone facies. The fine-grained sediments are the main source of ions for the authigenesis of quartz and feldspar overgrowths and carbonate precipitation. Mechanical compaction of fine-grained sediments, influx of gravity-driven acidic meteoric pore water, dehydration water, diffusion and convection are the most important means of mass transfer and pore water circulation. Pore water migration depends upon permeability distribution and pressure difference. (Received December 8, 2000; revised April 26, 2002) Bull. Chem. Soc. Ethiop. 2002, 16(1), 9-35

Geology and combustion perspectives of Pakistani coals from Salt Range and Trans Indus Range

Abundant availability of low rank coals in some developing countries has a great potential for socio-economic development. Pakistan, as a developing country, has taken a number of initiatives some of which are at an advanced stage. Thus, a critical study of regional and local geology of Salt Range and Trans Indus Range coals located in the Kohat–Potwar geologic province is presented in this paper. Permian coal is the oldest coal, which is located in the Western Salt Range in limited quantity while Palaeocene coal is the younger coal and it is mined from the Hangu and Patala formations. The Palaeocene coal is available in abundance and is mined in the Eastern and Central parts of the Salt Range and Trans Indus Range. Additionally, this study presents the thermo-chemical analyses of the coal samples collected from thirty coal mines of Salt Range and Trans Indus Range. The samples were analyzed for ash composition, ash fusion temperatures (AFT), proximate analysis, ultimate analysis and calorific value from two different Labs, i.e. SGS Pakistan and Changsha University of Science and Technology (CUST), China. The average AFT of the samples analyzed is > 1350 °C, which reveals that the coal is non-slagging. On average the coal has low slagging index, medium fouling index, good combustion characteristic parameters and indices. The coal samples have high ash (14–50%), ultra-high sulfur (3.3–11.1%), low moisture (3–10%), high volatile matter (VM, 24–41%), low carbon (23–57%) with low to medium gross calorific value (GCV, 10.2–25.7 MJ/kg). The data gathered from an extensive campaign is compared with the already published data. The study has provided a knowledge on utilization of coal reserves to meet the projected energy demand in Pakistan as well as in other developing countries

<b>Comparison of authigenic minerals in sandstones and interbedded mudstones, siltstones and shales, East Berlin formation, Hartford Basin, USA</b>

The East Berlin formation consists mainly of alternating sequences of fluviatile, lacustrine and playa sediments. Diagenetic sequences reconstruction revealed the same range of authigenic minerals in the studied sandstones and the interbedded fine-grained sediments (mudstones and siltstones). This indicates that the diagenetic processes that took place in the sandy facies also took place in fine-grained sediments. Mechanically infiltrated clays, grain-coating clay/hematite, quartz and feldspar overgrowths, carbonate cements and pore-filling and pore-lining clay minerals that precipitated in the sandy facies also precipitated in the fine-grained sediments. The abundance of authigenic minerals in decreasing order include: sandstone > siltstone > mudstone > shale. Except minor amounts of authigenic illite-smectite and illite, the shaly facies dominated by detrital clay, carbonate, quartz and feldspars framework grains. Authigenic minerals such as quartz, albite and K-feldspar are absent in the shaly facies, possibly related to early destruction of porosity. The lacustrine sandstones, siltstones and mudstones followed marine diagenetic trend, whereas playa and fluviatile sandstones, siltstones and mudstones followed red bed diagenetic trend. Mechanically compacted mudstones, siltstones and shales expelled large volume of mineralized pore water, which might migrated into the sandstone-rich section. Part of the ions for the precipitation of quartz overgrowths and carbonate cements in the sandy facies possibly contributed from the interbedded siltstones, mudstones and shales facies

<b>Fossil fuel energy resources of Ethiopia</b>

Inter-Trappean coal and oil shale-bearing sediments are widely distributed in the Delbi-Moye, Lalo-Sapo, Yayu, Sola, Chida, Chilga, Mush Valley, Wuchale and Nejo Basins. Coal and oil shale-bearing sediments were deposited in fluvio-lacustrine and paludal depositional environments. The Ethiopian oil shales reach a maximum thickness of 60 m, and contain mixtures of algal, herbaceous and higher plant taxa. Type II and I kerogen dominated the studied oil shales. Pyrolysis data revealed that the Ethiopian oil shales are good to excellent source rocks types up to 34.5 % TOC values and up to 130 HC g/kg S₂. A total of about 653,000,000 - 1,000,000,000 tones of oil shale reserve registered in the country. The coal and coal-bearing sediments attain a maximum thickness of 4 m and 278 m, respectively. Proximate analysis and calorific value data show that the Ethiopian coals fall under the soft coal series (lignite to bituminous coal), and genetically classified under humic, sapropelic and mixed coals. A total of about 297,000,000 tones of coal reserve registered in the country. The Permian Bokh Shale, Oxfordian-Bathonian Hamanlei Limestones, Kimmeridgian Urandab Shale are potential organic-rich source rocks. The Permian Calub sandstone, Triassic-Liassic Adigrat sandstone and Oxfordian-Bathonian Hamanlei carbonates are reservoirs in the Ogaden and Blue Nile Basins. 2.7 TCF (76 x 10⁹ m³) sulfur-free gas and 1817 x 10⁶ tons condensate reserves are estimated in the Calub field. About 1.3 TCF gas deposit is also encountered in Hilala field. The Blue Nile Basin is one of the potential basins for hydrocarbon exploration. The presence of mature source rocks and oil seepage in the Blue Nile Basin is clue for the generation of hydrocarbon in the basin. The Gambella Basin is the southern extension of the petroliferous Sudan Interior Basins, and could be one of the potential basins for oil and gas deposits

<b>Contrast in clay mineralogy and their effect on reservoir properties in sandstone formations</b>

Adigrat sandstone formation in the Blue Nile Basin is dominated by quartz arenite and subarkosicarenite, and cemented by carbonate, clay minerals and quartz overgrowths. Clay minerals in the Adigratsandstone formation are dominated by kaolinite, illite and chlorite. Illite is the common grain-coating claymineral. The common pore-filling minerals are kaolinite, illite and chlorite. The formation reaches a depth of 3km, which facilitated the change of kaolinite to illite. Clay minerals are the major reducer of porosity andpermeability in the Adigrat sandstone formation.The Permo-Triassic sandstones in the Ulster Basin were deposited in NE-SW trending fault-boundedasymmetrical graben. The Permo-Triassic sandstones reaches a burial depth of 1/2 km in the marginal areas and4.5 km in the basin center. The basin underwent multiple episodes of uplift and erosion in the Upper Jurassic, andMid-Cretaceous, and uplift and inversion in the Upper Tertiary. The difference of the clay mineralogy in thePermo-Triassic in the Ulster Basin depends upon the depositional environments, source area geology and burialhistory of the basin. Illite-smectite is grain coating, whereas smectite, illite-smectite, smectite-chlorite, chlorite,illite and kaolinite are the common pore-filling clay minerals in the Permo-Triassic sandstones in the Ulster Basin.Clay minerals reduced the porosity and permeability of the Permo-Triassic sandstones

<b>Effects of heat-flow and hydrothermal fluids from volcanic intrusions on authigenic mineralization in sandstone formations</b>

Volcanic intrusions and hydrothermal activity have modified the diagenetic minerals. In the Ulster Basin, UK, most of the authigenic mineralization in the Permo-Triassic sandstones pre-dated tertiary volcanic intrusions. The hydrothermal fluids and heat-flow from the volcanic intrusions did not affect quartz and feldspar overgrowths. However, clay mineral-transformation, illite-smectite to illite and chlorite was documented near the volcanic intrusions. Abundant actinolite, illite, chlorite, albite and laumontite cementation of the sand grains were also documented near the volcanic intrusions. The abundance of these cementing minerals decreases away from the volcanic intrusions.In the Hartford Basin, USA, the emplacement of the volcanic intrusions took place simultaneous with sedimentation. The heat-flow from the volcanic intrusions and hydrothermal activity related to the volcanics modified the texture of authigenic minerals. Microcrystalline mosaic albite and quartz developed rather than overgrowths and crystals near the intrusions. Chlorite clumps and masses were also documented with microcrystalline mosaic albite and quartz. These features are localized near the basaltic intrusions. Laumontite is also documented near the volcanic intrusions. The reservoir characteristics of the studied sandstone formations are highly affected by the volcanic and hydrothermal fluids in the Hartford and the Ulster Basin. The porosity dropped from 27.4 to zero percent and permeability from 1350 mD to 1 mD