New palaeoceanographic constraints on the Eocene-Oligocene Transition in the Pacific (abstract of paper presented at AGU Fall Meeting, San Francisco, 6-10 Dec 2002)

The Eocene-Oligocene (E/O) transition represents perhaps the most pivotal phase in the shift from Cenozoic greenhouse to icehouse and is marked by the most pronounced shift in the calcite compensation depth (CCD) over the last 100 Myr. Yet detailed palaeoceanographic records for these important events are rare because of the lack of well-dated, expanded deep-sea sedimentary sections containing well-preserved calcareous microfossils. Recently, during Ocean Drilling Program Leg 199, we recovered a series of high-quality E/O sections across a latitudinal and depth transect in the central tropical Pacific Ocean. These sections provide an excellent opportunity to improve our understanding of the palaeoceanographic chain of events that took place across this important interval in the region of the world where the CCD perturbation is believed to be most extreme and in the largest ocean basin. Here, we report new high-resolution records of bulk sediment d13C, d18O and percent carbonate from ODP Sites 1217 through 1220. Our results show the following: (i) Bulk records from the central tropical Pacific have the potential to provide a remarkably clean and detailed chemostratigraphy for the E/O transition. (ii) CCD deepening occurred remarkably rapidly (initial depression <50 ka) and, in the most expanded section, at the shallowest end of the transect (Site 1218), as a two-step shift. (iii) The form of this two-step shift is strikingly similar to the bulk d18O record on the build up to Oi-1. (iv) The intermediate plateau that occurs between the two steps in the d18O series fits very well with the main ~100-120 ky eccentricity cycles observed in multi-sensor track data and their amplitude modulation (plateau = one cycle). (v) The interval of maximum CCD as defined by high carbonate sediment content (≥60% CO3) at the deeper end of the transect (Site 1220) correlates with the onset of Oi-1 and lasts for ~250 ka. (vi) Hitherto unrecorded extreme perturbations to low d18O and d13C values occur in the uppermost Eocene at Site 1218. (vii) d18O and d13C records from this site show significantly more structure within Oi-1 than published records (characteristic features of obliquity control, with a small imprint of precession)

Integrated Ocean Drilling Program Expedition 317/319 Scientific Prospectus: Pacific Equatorial Age Transect

As the world's largest ocean, the Pacific is intricately linked to major changes in the global climate system. Throughout the Cenozoic, Pacific plate motion has had a northward component. Thus, the Pacific is unique in that the thick sediment bulge of biogenic-rich deposits from the currently narrowly focused zone of equatorial upwelling is slowly moving away from the Equator. Hence, older sections are not deeply buried and can be recovered by drilling. Previous drilling in this area during Ocean Drilling Program (ODP) Legs 138 and 199 was remarkably successful in giving us new insights into the workings of the climate and carbon system, productivity changes across the zone of divergence, time-dependent calcium carbonate dissolution, bio- and magnetostratigraphy, the location of the Intertropical Convergence Zone (ITCZ), and evolutionary patterns for times of climatic change and upheaval. Together with older Deep Sea Drilling Project drilling in the eastern equatorial Pacific, both legs also helped to delineate the position of the paleoequator and variations in sediment thickness from ~150°W to 110°W.The Pacific equatorial age transect (PEAT) science program is based on Integrated Ocean Drilling Program (IODP) Proposal 626 and consists of Expeditions 317 and 319, grouped into one science program. The goal is to recover a continuous Cenozoic record of the equatorial Pacific by drilling at the paleoposition of the Equator at successive crustal ages on the Pacific plate. Records collected from Expeditions 317 and 319 are to be joined with records of previous drilling during ODP Legs 138 and 199 to make a complete equatorial Pacific record from 0 to 55 Ma. Previously, ODP Legs 138 and 199 were designed as transects across the paleoequator in order to study the changing patterns of sediment deposition across equatorial regions at critical time intervals. As we have gained more information about the past movement of plates and when in Earth's history "critical" climate events took place, it becomes possible to drill an age transect ("flow-line") along the position of the Pacific paleoequator. The goal of this transect is to target important time slices where calcareous sediments have been best preserved and the sedimentary archive will allow us to reconstruct past climatic and tectonic conditions. Leg 199 enhanced our understanding of extreme changes of the calcium carbonate compensation depth (CCD) across major geological boundaries during the last 55 m.y. A very shallow CCD during most of the Paleogene makes it difficult to obtain well-preserved sediments during these stratigraphic intervals, but the strategy of site locations for the current two expeditions is designed to occupy the most promising sites and to obtain a unique sedimentary biogenic sediment archive for time periods just after the Paleocene/Eocene boundary event, Eocene cooling, the Eocene–Oligocene transition, the "one cold pole" Oligocene, the Oligocene–Miocene transition, and the Miocene. These new cores and data will significantly contribute to the objectives of the IODP Extreme Climates Initiative and will provide material that the previous legs were not able to recover.For logistical reasons, the PEAT science program is composed of two expeditions but is being implemented as a single science program to best achieve the overall objectives of Proposal 626. Participants on both expeditions (as well as approved shore-based scientists) will comprise a single science party with equal access to data and materials from both cruises. Sampling aboard the ship will be minimal, and the bulk of the sampling will be completed postcruise.The operational plan is to occupy eight sites along the age transect with the goal of recovering as complete a sedimentary succession as possible. This will probably require three holes to be cored at each site with wireline logging operations in one hole. Basement will be tagged in at least one of the holes. Expedition 317 will be directed primarily to sample the Neogene sites (proposed Sites PEAT-2C, 6C, and 7C, in priority order). The second expedition (319) will primarily sample the Paleogene sites (proposed Sites PEAT-1C, 3C, 4C, and possibly 5C, in priority order)

Site U1334

Integrated Ocean Drilling Program (IODP) Site U1334 (7°59.998?N, 131°58.408?W; 4799 meters below sea level [mbsl]) (Fig. F1; Table T1) is located ~380 km southeast of previously drilled Ocean Drilling Program (ODP) Site 1218 (~42 Ma crust) in the central area drilled during the Pacific Equatorial Age Transect (PEAT) program (IODP Expedition 320/321). Site U1334 (~38 Ma crust) is situated ~100 km north of the Clipperton Fracture Zone on abyssal hill topography draped with ~280 m sediment (Fig. F2). The fabric of the abyssal hills within the sites is oriented either due north or slightly east of due north.Water depth in the vicinity of Site U1334 ranges between 5.0 and 5.1 km for the depressions between the abyssal hills. The abyssal hills range between 4.70 and 4.85 km water depth and generally show a thicker and more consistent sediment cover than the basins. In fact, a significant amount of the bathymetric difference between hills and basins is controlled by the amount of sediment cover. The comparison of sediment thickness and clarity of seismic sections led us to select a location on the middle elevation of one of the abyssal plateaus.Site U1334 sediments were estimated to have been deposited on top of late middle Eocene crust with an age of ~38 Ma and target the events bracketing the Eocene–Oligocene transition with the specific aim of recovering carbonate-bearing sediments of latest Eocene age prior to a large deepening of the calcium carbonate compensation depth (CCD) that occurred during this greenhouse to icehouse transition (Kennett and Shackleton, 1976; Miller et al., 1991; Zachos et al., 1996; Coxall et al., 2005). The Eocene–Oligocene transition experienced the most dramatic deepening of the Pacific CCD during the Paleogene (van Andel, 1975), which has now been shown by Coxall et al. (2005) to coincide with a rapid stepwise increase in benthic oxygen stable isotope ratios, interpreted to reflect a combination of growth of the Antarctic ice sheet and decrease in deepwater temperatures (DeConto et al., 2008; Liu et al., 2009).<br/

Tracking the Equator Into the Paleogene (abstract of paper presented at AGU Fall Meeting, San Francisco, 8-12 Dec 2003)

Stratigraphy has been compiled for 63 tropical Pacific drill sites that sample lower Neogene and Paleogene sediments. These Sites derive from drilling on DSDP Leg 5 through ODP Leg 199. All Sites have been put on the biostratigraphic and paleomagnetic timescale refined by Leg 199 scientists. Sediment accumulation rates have been calculated for ten intervals ranging in age from 10 Ma to 56 Ma. A simple fixed hotspot model was used for Pacific lithospheric plate rotation in reconstructing the position of the selected sites for each of these ten intervals. The reconstruction of all intervals show the development of a tongue of relatively high accumulation rates associated with the oceanographic divergence at the geographic equator. The estimated position of the geographic equator based on these reconstructions lies consistently south of the position of the equator based on the rotation model used. However, the southward displacement is generally 2 degrees of latitude or less. We believe that this relatively small disagreement between the two estimates of equatorial position back to 56 Ma indicates: 1) Whatever hotspot movement that may have occurred in the interval between 40 and 56 Ma did not affect the motion of the Pacific plate; its motion after 40 Ma appears to have been approximately the same as before 40 Ma. 2) The estimated rate of true polar wander during the interval of 40 - 56 Ma must be very small (~0.125$\deg$/m.y.) and is probably not significant (i.e., well within the error of these reconstructions)

La2010: A new orbital solution for the long term motion of the Earth

We present here a new solution for the astronomical computation of the orbital motion of the Earth spanning from 0 to -250 Myr. The main improvement with respect to the previous numerical solution La2004 (Laskar et al. 2004) is an improved adjustment of the parameters and initial conditions through a fit over 1 Myr to a special version of the high accurate numerical ephemeris INPOP08 (Fienga et al. 2009). The precession equations have also been entirely revised and are no longer averaged over the orbital motion of the Earth and Moon. This new orbital solution is now valid over more than 50 Myr in the past or in the future with proper phases of the eccentricity variations. Due to chaotic behavior, the precision of the solution decreases rapidly beyond this time span, and we discuss the behavior of various solutions beyond 50 Myr. For paleoclimate calibrations, we provide several different solutions that are all compatible with the most precise planetary ephemeris. We have thus reached the time where geological data are now required to discriminate among planetary orbital solutions beyond 50 Myr.Comment: 17 pages, 14 figure

IODP Proposal 626: "Cenozoic Equatorial Age Transect – Following the Palaeo-equator"

As the largest ocean, the Pacific is intricately linked to major changes in the global climate system that took place during the Cenozoic. Throughout the Cenozoic the Pacific plate has had a northward component. Thus, the Pacific is unique, in that the thick sediment bulge of biogenic rich deposits from the currently narrowly focused zone of equatorial upwelling is slowly moving away from the equator. Hence, older sections are not deeply buried and can be recovered by drilling. Previous ODP Legs 138 and 199 were designed as transects across the paleo-equator in order to study the changing patterns of sediment deposition across equatorial regions, while this proposal aims to recover an orthogonal “age-transect” along the paleo-equator. Both previous legs were remarkably successful in giving us new insights into the workings of the climate and carbon system, productivity changes across the zone of divergence, time dependent calcium carbonate dissolution, bio- and magnetostratigraphy, the location of the ITCZ, and evolutionary patterns for times of climatic change and upheaval. Together with older DSDP drilling in the eastern equatorial Pacific, both Legs also helped to delineate the position of the paleo-equator and variations in sediment thickness from approximately 150°W to 110°W. As we have gained more information about the past movement of plates, and where in time “critical” climate events are located, we now propose to drill an age-transect (“flow-line”) along the position of the paleo-equator in the Pacific, targeting selected time-slices of interest where calcareous sediments have been preserved best. Leg 199 enhanced our understanding of extreme changes of the calcium carbonate compensation depth across major geological boundaries during the last 55 million years. A very shallow CCD during most of the Paleogene makes it difficult to obtain well preserved sediments, but we believe our siting strategy will allow us to drill the most promising sites and to obtain a unique sedimentary biogenic carbonate archive for time periods just after the Paleocene- Eocene boundary event, the Eocene cooling, the Eocene/Oligocene transition, the “one cold pole” Oligocene, the Oligocene-Miocene transition, and the Miocene, contributing to the objectives of the IODP Extreme Climates Initiative, and providing material that the previous legs were not able to recover

Organic Carbon Burial following the Middle Eocene Climatic Optimum (MECO) in the central - western Tethys

We present trace metal geochemistry and stable isotope records for the middle Eocene Alano di Piave section, NE Italy, deposited during magnetochron C18n in the marginal Tethys Ocean. We identify a $\sim$ 500 kyr long carbon isotope perturbation event we infer to be the middle Eocene Climatic Optimum (MECO) confirming the northern hemisphere expression and global occurrence of MECO. Interpreted peak climatic conditions are followed by the rapid deposition of two organic rich intervals ($\le$3\% TOC) and contemporaneous positive $\delta^{13}$C excursions. These two intervals are associated with increases in the concentration of sulphur and redox-sensitive trace metals, and low concentrations of Mn, as well as coupled with the occurrence of pyrite. Together these changes imply low, possibly dysoxic, bottom water O$_{2}$ conditions promoting increased organic carbon burial. We hypothesize that this rapid burial of organic carbon lowered global {\it p}CO$_{2}$ following the peak warming and returned the climate system to the general Eocene cooling trend

Astronomically paced changes in overturning circulation in the Western North Atlantic during the middle Eocene

North Atlantic Deep Water (NADW) currently redistributes heat and salt between Earth’s ocean basins, and plays a vital role in the ocean-atmosphere CO2 exchange. Despite its crucial role in today’s climate system, vigorous debate remains as to when deep-water formation in the North Atlantic started. Here, we present datasets from carbonate-rich middle Eocene sediments from the Newfoundland Ridge, revealing a unique archive of paleoceanographic change from the progressively cooling climate of the middle Eocene. Well-defined lithologic alternations between calcareous ooze and clay-rich intervals occur at the ∼41-kyr beat of axial obliquity. Hence, we identify obliquity as the driver of middle Eocene (43.5–46 Ma) Northern Component Water (NCW, the predecessor of modern NADW) variability. High-resolution benthic foraminiferal δ18O and δ13C suggest that obliquity minima correspond to cold, nutrient-depleted, western North Atlantic deep waters. We thus link stronger NCW formation with obliquity minima. In contrast, during obliquity maxima, Deep Western Boundary Currents were weaker and warmer, while abyssal nutrients were more abundant. These aspects reflect a more sluggish NCW formation. This obliquity-paced paleoceanographic regime is in excellent agreement with results from an Earth system model, in which obliquity minima configurations enhance NCW formation

Insensitivity of alkenone carbon isotopes to atmospheric CO₂ at low to moderate CO₂ levels

Atmospheric pCO2 is a critical component of the global carbon system and is considered to be the major control of Earth’s past, present and future climate. Accurate and precise reconstructions of its concentration through geological time are, therefore, crucial to our understanding of the Earth system. Ice core records document pCO2 for the past 800 kyrs, but at no point during this interval were CO2 levels higher than today. Interpretation of older pCO2 has been hampered by discrepancies during some time intervals between two of the main ocean-based proxy methods used to reconstruct pCO2: the carbon isotope fractionation that occurs during photosynthesis as recorded by haptophyte biomarkers (alkenones) and the boron isotope composition (δ11B) of foraminifer shells. Here we present alkenone and δ11B-based pCO2 reconstructions generated from the same samples from the Plio-Pleistocene at ODP Site 999 across a glacial-interglacial cycle. We find a muted response to pCO2 in the alkenone record compared to contemporaneous ice core and δ11B records, suggesting caution in the interpretation of alkenone-based records at low pCO2 levels. This is possibly caused by the physiology of CO2 uptake in the haptophytes. Our new understanding resolves some of the inconsistencies between the proxies and highlights that caution may be required when interpreting alkenone-based reconstructions of pCO2